indium(1+);hydroxide | 32365-64-3

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 后过渡金属氧阴离子化合物
• 英文名称: indium(1+);hydroxide
• CAS: 32365-64-3
• 化学式: HInO
• 分子量: 131.827
• InChiKey: XPHWZABCPRKTIK-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.56
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  indium(III) oxide 在 hydrogen 作用下， 以 gaseous matrix 为溶剂， 生成 indium(1+);hydroxide
  参考文献：
  名称：

  The identification of InOH in the gas phase and determination of its geometric structure

  摘要：

  The first gas phase observation of the species InOH is reported through the detection of its electronic spectrum in the near ultraviolet region, between 345 and 377 nm. The molecule was generated by the high temperature reaction between H2O and In metal or between H2 and In2O3, and cooled in a free jet expansion. Two separate electronic transitions have been identified and are tentatively assigned as α1A′←X̃1A′ and β1A″←X̃1A′. Values for the vibrational wavenumbers ν2 (bending vibration) and ν3 (In–O stretching vibration) have been determined for InOH and InOD in all three electronic states involved. There is evidence that the molecule is quasilinear in its ground electronic state which somewhat complicates the values determined for ν2 in this state. Rotational structure was easily resolved at the lowest temperature achieved in this work (Trot≊12 K). Analysis of this structure shows that the molecule is bent in all of the electronic states studied, with a bond angle of about 132° in the X̃ state and about 105° in the α and β states.

  DOI：

  10.1063/1.466756

文献信息

• Matrix-isolation studies by electronic spectroscopy of group IIIA metal–water photochemistry
  作者：Monte A. Douglas、Robert H. Hauge、John L. Margrave

  DOI：10.1039/f19837901533

  日期：——

  This paper reports an investigation of the electronic structures of the Group IIIA metal atom hydration reaction intermediates (M⋯OH2adducts) and their subsequent photolysis products (HMOH, MOH and MO) where M = Al, Ga and In. The metal–water interaction in the adduct is sufficiently strong to perturb the electronic structure of the metal atom; consequently, one observes a unique band structure for

  本文报告了IIIA组金属原子水合反应中间体（M⋯OH 2加合物）及其后续光解产物（HMOH，MOH和MO）的电子结构的研究，其中M = Al，Ga和In。加合物中的金属与水的相互作用足够强，足以扰乱金属原子的电子结构。因此，人们观察到加合物具有独特的能带结构，该加合物从金属的原子共振跃迁中发生了红移。提出了分子轨道和电子状态间的相关性。
• Infrared matrix-isolation studies of the interactions and reactions of Group 3A metal atoms with water
  作者：R. H. Hauge、J. W. Kauffman、J. L. Margrave

  DOI：10.1021/ja00539a005

  日期：1980.9
• The identification of InOH in the gas phase and determination of its geometric structure
  作者：Nicholas M. Lakin、John M. Brown、Ian R. Beattie、Peter J. Jones

  DOI：10.1063/1.466756

  日期：1994.6

  The first gas phase observation of the species InOH is reported through the detection of its electronic spectrum in the near ultraviolet region, between 345 and 377 nm. The molecule was generated by the high temperature reaction between H2O and In metal or between H2 and In2O3, and cooled in a free jet expansion. Two separate electronic transitions have been identified and are tentatively assigned as α1A′←X̃1A′ and β1A″←X̃1A′. Values for the vibrational wavenumbers ν2 (bending vibration) and ν3 (In–O stretching vibration) have been determined for InOH and InOD in all three electronic states involved. There is evidence that the molecule is quasilinear in its ground electronic state which somewhat complicates the values determined for ν2 in this state. Rotational structure was easily resolved at the lowest temperature achieved in this work (Trot≊12 K). Analysis of this structure shows that the molecule is bent in all of the electronic states studied, with a bond angle of about 132° in the X̃ state and about 105° in the α and β states.