magnesium amide | 935289-03-5

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 各种混合金属/非金属
• 英文名称: magnesium amide
• CAS: 935289-03-5
• 化学式: H₄MgN₂
• 分子量: 60.3184
• InChiKey: PKMBLJNMKINMSK-JBISRTOLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.56
• 重原子数：
  3.0
• 可旋转键数：
  2.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  52.04
• 氢给体数：
  2.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  magnesium amide 以 neat (no solvent, solid phase) 为溶剂， 生成 magnesium imide
  参考文献：
  名称：

  Magnesium Imide: Synthesis and Structure Determination of an Unconventional Alkaline Earth Imide from Decomposition of Magnesium Amide

  摘要：

  Magnesium imide (MgNH) was produced by monitoring the decomposition process of magnesium amide with in situ neutron diffraction. Significant changes in the structure of magnesium amide are detected during heat treatment and eventually result in the formation of crystalline MgNH. A model for the crystal structure of magnesium imide (MgNH) is presented for the first time. Remarkably, magnesium imide offers unique structural features similar to the cyclosilicate class and can be described as a porous solid formed by a sequence of linked chains of face sharing Mg(6)N(6) hexagonal prism clusters.

  DOI：

  10.1021/ic1023778
• 作为产物：
  描述：

  magnesium dihydride 、 氨-d3 以 neat (no solvent, solid phase) 为溶剂， 生成 magnesium amide
  参考文献：
  名称：

  Magnesium Imide: Synthesis and Structure Determination of an Unconventional Alkaline Earth Imide from Decomposition of Magnesium Amide

  摘要：

  Magnesium imide (MgNH) was produced by monitoring the decomposition process of magnesium amide with in situ neutron diffraction. Significant changes in the structure of magnesium amide are detected during heat treatment and eventually result in the formation of crystalline MgNH. A model for the crystal structure of magnesium imide (MgNH) is presented for the first time. Remarkably, magnesium imide offers unique structural features similar to the cyclosilicate class and can be described as a porous solid formed by a sequence of linked chains of face sharing Mg(6)N(6) hexagonal prism clusters.

  DOI：

  10.1021/ic1023778