磷酸二(2-氯苯基)苯基酯 | 597-80-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 中文名称: 磷酸二(2-氯苯基)苯基酯
• 英文名称: Di-(o-chlorphenyl)-phenylphosphat
• 英文别名: phosphoric acid bis-(2-chloro-phenyl ester)-phenyl ester；Phosphorsaeure-bis-(2-chlor-phenylester)-phenylester；Phenyl-bis-(2-chlor-phenyl)-phosphat；2,2'-dichlorotriphenyl phosphate；Bis(o-chlorophenyl) phenyl phosphate；bis(2-chlorophenyl) phenyl phosphate
• CAS: 597-80-8
• 化学式: C₁₈H₁₃Cl₂O₄P
• 分子量: 395.179
• InChiKey: QGJHPPKJOSJFIV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  25
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  苯酚 在 magnesium chloride 、 三氯氧磷 作用下， 生成 磷酸二(2-氯苯基)苯基酯
  参考文献：
  名称：

  Organic phosphates

  摘要：

  公开号：

  US02033916A1

文献信息

• Light-sensitive silver halide color photographic material
  申请人：KONICA CORPORATION

  公开号：EP0193397A2

  公开（公告）日：1986-09-03

  @ A light-sensitive silver halide color photographic material having photographic constituent layers including a blue-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer and a red-sensitive silver halide emulsion layer on a support wherein the content of silver bromide of the silver halides in the green-sensitive silver halide emulsion layer and red-sensitive silver halide emulsion layer is 5 to 65 mole %, and the green-sensitive silver halide emulsion layer contains at least one of the compounds represented by the formula [I] shown below: wherein X represents a halogen atom or a monovalent organic group eliminable through coupling reaction with an oxidized product of a developing agent; R, to R3, which may be either identical or different, each represent a hydrogen atom, a halogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, a cycloalkenyl group, an alkynyl group, an aryl group, a heterocyclic group, an acyl group, a sulfonyl group, a sulfinyl group, a phosphonyl group, a carbamoyl group, a sulfamoyl group, a cyano group, a spiro compound residue, a bridged hydrocarbon compound residue, an alkoxy group, an aryloxy group, a heterocycloxy group, a siloxy group, an acyloxy group, a carbamoyloxy group, an amino group, an acylamino group, a sulfonamide group, an imide group, a ureido group, a sulfamoylamino group, an alkoxycarbonylamino group, an aryloxycarbonylamino group, an alkoxycarbonyl group, an aryloxycarboynyl group, an alkylthio group, an arylthio group or a heterocyclic thio group, with proviso that at least two of R, to R3 are not hydrogen atoms; R4 represents a hydrogen atom, an alkyl group, an aryl group, a heterocyclic group, an acylamino group, an alkylamino group, an anilino group, an alkoxycarbonyl group or an alkylthio group. According to the light-sensitive silver halide color photographic material of this invention, rapid developing processing is possible with improvement of processing stability in the rapid developing processing, and yet saving of silver is possible, simultaneously with inhibition of generation of fog, and moreover color image with good light resistance can be obtained.

  @一种感光卤化银彩色感光材料，其感光成分层包括位于支撑物上的感蓝卤化银乳剂层、感绿卤化银乳剂层和感红卤化银乳剂层，其中感绿卤化银乳剂层和感红卤化银乳剂层中卤化银中溴化银的含量为5至65摩尔%，感绿卤化银乳剂层含有下式[I]所代表的至少一种化合物： 其中 X 代表卤素原子或可通过与显影剂的氧化产物发生偶联反应而消除的一价有机基团；R,至R3可以相同或不同，各自代表氢原子、卤素原子、烷基、环烷基、烯基、环烯基、炔基、芳基、杂环基、酰基、磺酰基、亚磺酰基、膦酰基、氨基甲酰基、氨基磺酰基、氰基、螺环化合物残基、桥接烃化合物残基、烷氧基、芳氧基、烯氧基、炔氧基、炔烃基、炔烃基、炔烃基、炔烃基、炔烃基、炔烃基、炔烃基、炔烃基、炔烃基、炔烃基、炔烃基、炔烃基、炔烃基、炔烃基、炔烃基、炔烃基、芳氧基、杂环氧基、硅氧基、酰氧基、氨基、酰氨基、磺酰胺基、酰亚胺基、 脲基、磺酰胺基、烷氧基羰基氨基、烷氧基羰基氨基、烷氧基羰基、芳氧基羰基、烷硫基、芳硫基或杂环硫基，但 R 至 R3 中至少有两个不是氢原子；R4 代表氢原子、烷基、芳基、杂环基、酰氨基、烷氨基、苯胺基、烷氧羰基或烷硫基。 根据本发明的感光卤化银彩色感光材料，可以进行快速显影处理，并在快速显影处理中提高处理稳定性，还可以节省银，同时抑制雾的产生，此外还可以获得耐光性良好的彩色图像。
• Analytical element for determination of hydrogen peroxide and analytical method using the same
  申请人：KONICA CORPORATION

  公开号：EP0268167A2

  公开（公告）日：1988-05-25

  Disclosed is an analytical element for determination of hydrogen peroxide, which comprises using an analytical element containing a substance having the action of peroxidation, a compound represented by Formula (I) shown below, and an aromatic primary amine compound, or a salt thereof, capable of forming a dye through the coupling reaction with the compound represented by Formula (I) shown below: wherein Z represents a group of nonmetallic atoms necessary for forming a nitrogen-containing heterocyclic ring, which ring formed by Z may have a substituent; X represents a hydrogen atom or a group capable of being split off through the reaction with an oxidized product of the aromatic primary amine compound; and R represents a hydrogen atom or a substituent. Disclosed is also an analytical method for determination of hydrogen peroxide by use of the above analytical element. As described in the foregoing, the analytical element of this invention can exhibit the remarkable effect that the determination sensitivity can be greatly improved.

  本发明公开了一种测定过氧化氢的分析元件，它包括使用一种含有具有过氧化作用的物质的分析元件、下图所示式(I)代表的化合物和一种芳香族伯胺化合物或其盐，该芳香族伯胺化合物或其盐能够通过与下图所示式(I)代表的化合物发生偶联反应形成一种染料： 其中 Z 代表形成含氮杂环所必需的非金属原子团，由 Z 形成的环可以具有取代基；X 代表氢原子或能够通过与芳香族伯胺化合物的氧化产物反应而分离的基团；R 代表氢原子或取代基。 还公开了一种利用上述分析元件测定过氧化氢的分析方法。 如上所述，本发明的分析元件可以表现出显著的效果，即测定灵敏度可以大大提高。
• Liquid substituted 2H-benzotriazole mixtures
  申请人：CIBA-GEIGY AG

  公开号：EP0337942A1

  公开（公告）日：1989-10-18

  Liquid substituted 2H-benzotriazole mixtures are prepared by alkylation with concomitant dealkylation, fragmentation and/or realkylation of 2-(2-hydroxy-5-alkylphenyl)-2H-benzotriazoles or of 2-(2-hydroxy-3,5-dialkylphenyl)-2H-benzotriazoles with straight or branched alkenes of 8 to 40 carbon atoms in the presence of an acid catalyst at 100 - 200°C. The liquid mixtures exhibit outstanding efficacy in protecting organic substrates from light induced deterioration as well as good resistance to loss by volatilization or exudation during the processing of stabilized compositions at elevated temperatures.

  液态取代的 2H 苯并三唑混合物是在 100 - 200°C 下，在酸催化剂存在下，通过 2-(2-羟基-5-烷基苯基)-2H-苯并三唑或 2-(2-羟基-3,5-二烷基苯基)-2H-苯并三唑与 8 - 40 个碳原子的直链或支链烯烃进行烷基化并同时进行脱烷基化、破碎和/或再烷基化而制备的。这种液态混合物在保护有机基质免受光引起的劣化方面表现出卓越的功效，并且在高温下加工稳定组合物时，具有良好的抗挥发或抗渗出性。
• Flüssige 2-(2-Hydroxy-3-höherverzweigtalkyl-5-methylphenyl)-2H-benztriazolgemische, Verfahren zu deren Herstellung und diese enthaltende stabilisierte Zusammensetzungen
  申请人：CIBA-GEIGY AG

  公开号：EP0189374B1

  公开（公告）日：1992-03-18
• 3-Aminoallylidenemalononitrile uv-absorbing compounds and photographic elements containing them
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0210409B1

  公开（公告）日：1992-08-19