2-[4-[Hydroxy-[4-[2-(2-methylprop-2-enoyloxy)ethyl]phenoxy]phosphoryl]oxyphenyl]ethyl 2-methylprop-2-enoate | 367516-39-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: 2-[4-[Hydroxy-[4-[2-(2-methylprop-2-enoyloxy)ethyl]phenoxy]phosphoryl]oxyphenyl]ethyl 2-methylprop-2-enoate
• CAS: 367516-39-0
• 化学式: C₂₄H₂₇O₈P
• 分子量: 474.447
• InChiKey: DATUTDLGSCVXFM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  33
• 可旋转键数：
  14
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  108
• 氢给体数：
  1
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  4-(2-methacryloyloxyethyl)phenol 在 吡啶 、 三氯氧磷 、 水 作用下， 以 甲苯 、 吡啶 为溶剂， 反应 12.5h， 生成 2-(4-Phosphonooxyphenyl)ethyl 2-methylprop-2-enoate 、 2-[4-[Hydroxy-[4-[2-(2-methylprop-2-enoyloxy)ethyl]phenoxy]phosphoryl]oxyphenyl]ethyl 2-methylprop-2-enoate
  参考文献：
  名称：

  Building Material

  摘要：

  一种建筑材料由特定组成成分形成，该组成成分包含以下化学式(8)-c和(8)-d所代表的磷酸酯化合物和铜离子，在树脂板中。

  公开号：

  US20040204600A1

文献信息

• DENTAL ADHESIVE COMPOSITION
  申请人：Matsushige Koji

  公开号：US20120238658A1

  公开（公告）日：2012-09-20

  [Problems] To provide a liquid dental adhesive composition which contains a phosphoric acid-type compound having a hydrogenphosphoric diester group as an acidic group-containing polymerizable monomer and, further, contains polyvalent metal ions, effectively preventing not only the gelation but also the formation of precipitates (cloudiness) during the storage. [Means for Solution] A dental adhesive composition which is acidic and contains an acidic group-containing polymerizable monomer (A), polyvalent metal ions (B), water (C), a water-soluble organic solvent (D) and fluoride ions (E), wherein at least 35% by mole of the acidic group-containing polymerizable monomer (A) is a phosphoric acid-type compound having a hydrogenphosphoric diester group, and the contents of the fluoride ions (E) and the polyvalent metal ions (B) are so set that a valence number ratio (R F ) defined by the following formula (1): R F =V F /TV P (1) wherein V F is a valence number of the fluoride ions (E) contained in the composition, and TV P is a total valence number of the polyvalent metal ions (B) contained in the composition, satisfies a range of 0.2 to 2.0.

  提供一种液体牙科粘合剂组合物，其中包含具有氢磷酸二酯基团作为酸性基团的聚合可单体的磷酸型化合物，并且进一步含有多价金属离子，有效地防止在储存期间不仅凝胶化，还防止沉淀（混浊）的形成。解决方案是一种含有酸性和含有酸性基团的聚合可单体（A）、多价金属离子（B）、水（C）、水溶性有机溶剂（D）和氟离子（E）的牙科粘合剂组合物，其中至少35%的含有酸性基团的聚合可单体（A）是具有氢磷酸二酯基团的磷酸型化合物，并且氟离子（E）和多价金属离子（B）的含量设置得使得以下公式（1）定义的价数比率（RF）满足0.2至2.0的范围：RF=VF/TVP（1）其中VF是组合物中含有的氟离子（E）的价数，而TVP是组合物中含有的多价金属离子（B）的总价数。
• Adhesive composition
  申请人：TOKUYAMA SODA KABUSHIKI KAISHA

  公开号：EP0335645A2

  公开（公告）日：1989-10-04

  Disclosed is an adhesive composition comprising (a) 100 parts by weight of a monomer mixture comprising a vinyl monomer having an acidic group in the molecule and a vinyl monomer copolymerizable with said vinyl monomer, (b) 10 to 500 parts by weight of a filler, (c) 0.01 to 10 parts by weight of a polymerization initiator and (d) 0.01 to 10 parts by weight of ascorbic acid or a derivative thereof. This adhesive composition has a high bonding force and an excellent durability even in a severe environment, for example, in the environment in the oral cavity. Accordingly, this adhesive composition is especially valuable used as a dental adhesive.

  本发明公开了一种粘合剂组合物，该组合物包括：(a) 100 份（按重量计）单体混合物，该混合物由分子中含有酸性基团的乙烯基单体和可与所述乙烯基单体共聚的乙烯基单体组成；(b) 10 至 500 份（按重量计）填料；(c) 0.01 至 10 份（按重量计）聚合引发剂；(d) 0.01 至 10 份（按重量计）抗坏血酸或其衍生物。 这种粘合剂组合物具有很高的粘合力和极好的耐久性，即使在恶劣的环境中，例如在口腔环境中也是如此。因此，这种粘合剂组合物特别适合用作牙科粘合剂。
• ANTIMICROBIAL COMPOSITION
  申请人：Kuraray Co., Ltd.

  公开号：EP1285947A1

  公开（公告）日：2003-02-26

  An antibacterial composition comprising (a) an antibacterial salt compound, (b) an acid group-having polymerizable monomer, (c) a hydrophilic polymerizable monomer, (d) water, and (e) a basic compound selected from alkali metal hydroxides, strong basic acid salts not having an aromatic group, and aliphatic amines has good antibacterial properties, and, in addition, the composition discolors little and its adhesiveness lowers little even when stored or heated for a long period of time.

  由以下成分组成的抗菌组合物具有良好的抗菌性能：(a) 抗菌盐化合物；(b) 带有酸性基团的可聚合单体；(c) 亲水性可聚合单体；(d) 水；(e) 选自碱金属氢氧化物、不带芳香基团的强碱性酸盐和脂肪族胺的碱性化合物。
• Dental adhesive composition
  申请人：GC Corporation

  公开号：EP1287805A1

  公开（公告）日：2003-03-05

  A one-pack type dental adhesive composition-that does not require a pre-treatment such as an etching treatment and a priming treatment and can surely adhere a dental restoration material to a tooth structure and keep an adhesive effect over a long period of time, comprised of a polymerizable composition containing (a) 1 ∼ 5 % by weight of a polymerizable monomer containing a phosphoric acid group, (b) 10 ∼ 40 % by weight of a polymerizable monomer containing a plurality of carboxyl groups in one molecule, or being readily reactive with water to generate a plurality of carboxyl groups in one molecule, (c) 20 ∼ 40 % by weight of an acid group-free polymerizable monomer or a mixture of two or more acid group-free polymerizable monomers, both having a solubility of water at 25 °C of 25 % by weight or less, and (d) 15 ∼ 50 % by weight of water, with (e) 0.1 ∼ 5.0 parts by weight, based on 100 parts by weight of the polymerizable composition, of a photo-polymerization initiator and (f) a viscosity modifier having a mean particle size of 0.01 ∼ 0.05 µm, the dental adhesive composition having a viscosity of 0.1 ∼ 1 Pa·s.

  一种单组分型牙科粘合剂组合物--它不需要蚀刻处理和打底处理等预处理，就能将牙科修复材料牢固地粘合在牙齿结构上，并能长期保持粘合效果，它由可聚合组合物组成，该组合物含有(a)1∼5%（重量百分比）含有磷酸基团的可聚合单体、(b) 10 ∼ 40 %（重量百分比）的可聚合单体，该单体在一个分子中含有多个羧基， 或容易与水反应在一个分子中生成多个羧基、(c) 20 ∼ 40 %（重量百分比）的不含酸性基团的可聚合单体或两种或两种以上不含酸性基团的可聚合单体的混合物，这两种单体在 25 °C 时的水溶解度均为 25 %（重量百分比）或更低，以及 (d) 15 ∼ 50 %（重量百分比）的水，其中 (e) 0.1 ∼ 5.0 重量份（以 100 重量份的可聚合组合物为基准）的光聚合引发剂和 (f) 平均粒径为 0.01 ∼ 0.05 µm 的粘度调节剂，牙科粘合剂组合物的粘度为 0.1 ∼ 1 Pa-s。
• ADHESIVES FOR DENTAL USE
  申请人：TOKUYAMA CORPORATION

  公开号：EP1459726A1

  公开（公告）日：2004-09-22

  A dental adhesive containing an acidic group-containing radically polymerizable monomer, a non-acidic radically polymerizable monomer, a chemical polymerization initiator and a filler, as well as a 2,4-diphenyl-4-methyl-1-pentene. When the dental adhesive is used for adhering a crown restorative to the tooth, an excess of cement swelling from the surface of adhesion can be favorably removed, the curing time can be suitably adjusted without decreasing the strength of adhesion to the tooth, and a change in the color tone of the cured body can be effectively suppressed.

  一种牙科粘合剂，含有含酸性基团的可辐射聚合单体、非酸性可辐射聚合单体、化学聚合引发剂和填料，以及 2,4-二苯基-4-甲基-1-戊烯。当牙科粘合剂用于将牙冠修复体粘合到牙齿上时，可以有效地去除粘合表面过量的水泥膨胀，适当调整固化时间而不会降低与牙齿的粘合强度，并能有效抑制固化体色调的变化。