phosphoric acid-(6-methyl-heptyl ester)-diphenyl ester | 29319-57-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: phosphoric acid-(6-methyl-heptyl ester)-diphenyl ester
• 英文别名: Phosphorsaeure-(6-methyl-heptylester)-diphenylester；Isooctyl-O-diphenyl-phosphorsaeure-ester；Phosphoric acid, isooctyl diphenyl ester；6-methylheptyl diphenyl phosphate
• CAS: 29319-57-1
• 化学式: C₂₀H₂₇O₄P
• 分子量: 362.406
• InChiKey: RCRYBQKHEDNBDN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  25
• 可旋转键数：
  11
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  C7-9-烷基醇 在 三氯氧磷 作用下， 生成 phosphoric acid-(6-methyl-heptyl ester)-diphenyl ester
  参考文献：
  名称：

  烷基芳基磷酸盐的化学和物理性质

  摘要：

  DOI：

  10.1021/ie50529a062

文献信息

• Mineral filled polyphenylene ether compositions having improved properties
  申请人：GENERAL ELECTRIC COMPANY

  公开号：EP0054845A2

  公开（公告）日：1982-06-30

  There are provided compositions comprising a poly. phenylene ether resin, a high impact rubber modified polystyrene, a mineral filler other than iron oxide and an effective amount of a plasticizer. Such compositions possess surprisingly improved impact strength in comparison with corresponding compositions in which the plasticizer is not present. In addition, there are provided compositions comprising a polyphenylene ether resin, an impact modifier other than a rubber modified polystyrene, iron oxide and an effective amount of a plasticizer. Such compositions possess improved modulus in comparison with corresponding compositions in which the iron oxide is not present, with good retention of ductility which is unexpected.

  所提供的组合物包含聚苯醚树脂、高抗冲橡胶改性聚苯乙烯、氧化铁以外的矿物填料和有效量的增塑剂。与不含增塑剂的相应组合物相比，这种组合物的抗冲击强度有惊人的提高。此外，还提供了包含聚苯醚树脂、橡胶改性聚苯乙烯以外的抗冲改性剂、氧化铁和有效量增塑剂的组合物。与不含氧化铁的相应组合物相比，这些组合物具有更好的模量，并能保持意想不到的良好延展性。
• Polyethers containing 2,2,6,6-tetramethyl piperidinyl carboxylic acid ester groups and synthetic resin compositions
  申请人：ADEKA ARGUS CHEMICAL CO., Ltd.

  公开号：EP0118578A1

  公开（公告）日：1984-09-19

  Polyethers containing 2,2,6,6-tetramethyl piperidinyl carboxylic acid ester or ether groups are provided, comprising polymeric units having the structure. wherein X is selected from the group consisting of: R1 is selected from the group consisting of hydrogen, -0, alkyl, hydroxy alkyl and epoxyalkyl having from one to about eighteen carbon atoms, acyl having from one to about eighteen carbon atoms, cycloalkyl having from three to about eighteen carbon atoms; phenyl; phenalkyl and alkylphenyl having from seven to about twenty-four carbon atoms; R2 is hydrogen or hydroxy; n1 is 0 or 1; R3 is lower alkyl having from one to about six carbon atoms; and n is the average number of such units in the polymer; as well as stabilized synthetic resin compositions comprising such polyethers.

  提供了含有 2,2,6,6-四甲基哌啶基羧酸酯或醚基团的聚醚，该聚醚由具有以下结构的聚合物单元组成。 其中 X 选自以下组成的组 R1 选自氢、-0、具有 1 至约 18 个碳原子的烷基、羟基烷基和环氧烷基、具有 1 至约 18 个碳原子的酰基、具有 3 至约 18 个碳原子的环烷基、具有 7 至约 24 个碳原子的苯基、苯基和烷基苯基； R2 是氢或羟基 n1 是 0 或 1； R3 是具有 1 至约 6 个碳原子的低级烷基；以及 n 是聚合物中此类单元的平均数量；以及包含此类聚醚的稳定合成树脂组合物。
• Polyphenylene ether resin blends reinforced with finely divided particulate clay of narrow size distribution
  申请人：GENERAL ELECTRIC COMPANY

  公开号：EP0151261A1

  公开（公告）日：1985-08-14

  Blends of a polyphenylene ether resin, optionally containing an impact modifier, are filled with finely divided particulate clay which is characterized by a very narrow size distribution, 98 percent or more of the particles being less than 2 microns in diameter, and a very small particle size, with the particles having mean equivalent spherical diameter of from 0.2 to 0.4 microns. This particular clay filler provides rigidity and stiffness, as expected, but with better retention of other physical properties which are normally adversely affected by other mineral fillers, such as larger particle size clay and titanium dioxide. Adhesion between this clay and the polymer, which is already good, is further enhanced by pre-cleaning the clay particles to remove surface dirt, chemicals and salts.

  聚苯醚树脂的混合物（可选择含有抗冲改性剂）中填充了细小的颗粒粘土，这种粘土的特点是粒度分布非常窄，98%或更多的颗粒直径小于 2 微米，而且粒度非常小，颗粒的平均等效球形直径为 0.2 至 0.4 微米。这种特殊的粘土填料具有预期的刚性和刚度，但能更好地保持其他物理特性，而这些特性通常会受到其他矿物填料（如粒径较大的粘土和二氧化钛）的不利影响。这种粘土与聚合物之间的粘附性本来就很好，通过预先清洁粘土颗粒以去除表面污垢、化学物质和盐分，粘土与聚合物之间的粘附性进一步增强。
• CARBONIC DIESTER, AROMATIC POLYCARBONATE, PRODUCTION APPARATUS, AND PROCESS FOR PRODUCTION
  申请人：TEIJIN LIMITED

  公开号：EP0992522A1

  公开（公告）日：2000-04-12

  Aromatic polycarbonate having a reduced discoloration and improved heat stability, hue, etc. is provided by keeping a pressure in a raw material melting vessel and the linear velocity of a gas in a transporting piping in a specific range, keeping the concentration of a nitrogen-containing basic compound in a specific range, recycling a byproduct containing specific amounts of impurities, suppressing the amounts of a nitrogen-containing basic compound, metallic elements and a silicic acid derivative in the carbonic acid diester at specific values or less, prescribing the material quality of the reaction facilities, and/or forming an oxide layer at the inner wall surfaces of the reaction facilities.

  通过将原料熔化容器中的压力和输送管道中的气体线速度保持在特定范围内，将含氮碱性化合物的浓度保持在特定范围内，循环使用含氮碱性化合物，从而提供了变色减少、热稳定性和色调等性能均得到改善的芳香族聚碳酸酯。将原料熔化容器中的压力和输送管道中气体的线速度保持在特定范围内，将含氮碱性化合物的浓度保持在特定范围内，回收含有特定数量杂质的副产品，将碳酸二酯中的含氮碱性化合物、金属元素和硅酸衍生物的数量控制在特定值或更低，规定反应设备的材料质量，和/或在反应设备的内壁表面形成氧化层，从而提供具有减少变色和提高热稳定性等特性的芳香族聚碳酸酯。
• Flame retardant radiation curable compositions
  申请人：Cytec Surface Specialties, S.A.

  公开号：EP2154191A1

  公开（公告）日：2010-02-17

  The invention relates to a flame retardant composition comprising at least one polymer precursor, at least one flame retardant (A) selected from cyclic phosphonate esters responding to formula (I) and at least one flame retardant (B) selected from phosphorus derivatives different from the cyclic phosphonates of formula (I) and their use to make fire resistant glass laminates.

  本发明涉及一种阻燃剂组合物，该组合物包含至少一种聚合物前体、至少一种选自符合式 (I) 的环状膦酸酯的阻燃剂 (A) 和至少一种选自不同于式（I）环状膦酸酯的磷衍生物的阻燃剂（B），以及它们在制造防火玻璃层压板中的用途。