Phosphorsaeure-phenylester-p-tolylester | 79227-89-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: Phosphorsaeure-phenylester-p-tolylester
• 英文别名: phosphoric acid monophenyl ester-mono-p-tolyl ester; brucine salt；Phosphorsaeure-monophenylester-mono-p-tolylester; Brucin-Salz；Phosphorsaeure-monophenylester-mono-p-tolylester; Strychnin-Salz；Phosphorsaeure-monophenylester-mono-p-tolylester；Phosphorsaeure-phenylester-p-tolylester；Monophenyl-mono-p-tolyl-phosphat；(4-Methylphenyl) phenyl hydrogen phosphate
• CAS: 79227-89-7
• 化学式: C₁₃H₁₃O₄P
• 分子量: 264.218
• InChiKey: QLJCXHUYOMXRQL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  55.8
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  4-methylphenyl phenyl chlorophosphate 在 sodium hydroxide 作用下， 生成 Phosphorsaeure-phenylester-p-tolylester
  参考文献：
  名称：

  Luff; Kipping, Journal of the Chemical Society, 1909, vol. 95, p. 2003

  摘要：

  DOI：

文献信息

• MELT TENSION IMPROVER FOR POLYOLEFIN RESINS AND PROCESS FOR PRODUCING THE SAME
  申请人：——

  公开号：US20010016627A1

  公开（公告）日：2001-08-23

  A melt tension enhancer for polyolefin resins that contains polytetrafluoroethylene and a polymer of an alkyl (meth)acrylate of 5-30 carbon atoms, and a process for its production. Its addition to polyolefin resins enhances the melt tension of the polyolefin resins without impairing the surface appearance of their molds.

  一种用于聚烯烃树脂的熔融张力增强剂，包含聚四氟乙烯和碳链为5-30的烷基（甲基）丙烯酸酯聚合物，并提供其生产方法。将其添加到聚烯烃树脂中，可以增强聚烯烃树脂的熔融张力，而不会损害模具表面的外观。
• Stretched cellulose ester film, hard coat film, antireflective film, and optical compensation film, and polarizing plate, and display device using them
  申请人：Takagi Takahiro

  公开号：US20060182901A1

  公开（公告）日：2006-08-17

  In a stretched cellulose ester film containing a plasticizer, the plasticizer includes at least an aromatic terminal ester type plasticizer expressed by the following general formula (1): and stretched cellulose ester film includes a cellulose ester having a total acyl substitution degree of 2.4 to 2.9, a number average molecular weight (Mn) of 30000 to 200000, and a value of a weight-average molecular weight (Mw)/a number average molecular weight (Mn) being 1.4 to 3.0, B-(G-A)n-G-B  General formula (1) where B represents a benzenemonocarboxylic acid residue, G represents an alkylene glycol residue having a carbon number of 2 through 12 or an oxyalkylene glycol residue having a carbon number of 4 through 12, A represents an alkylene dicarboxylic acid residue having a carbon number of 4 to 12, and n indicates an integer of 0 or more.

  在一个含有可塑剂的拉伸纤维素酯薄膜中，该可塑剂包括至少一种芳香末端酯类型可塑剂，其由以下通式（1）表示：B-(G-A)n-G-B，其中B表示苯甲酸残基，G表示碳数为2至12的烷基二醇残基或碳数为4至12的氧烷基二醇残基，A表示碳数为4至12的烷基二羧酸残基，n表示大于或等于0的整数。而拉伸纤维素酯薄膜则包括具有总酰基取代度为2.4至2.9、数均分子量（Mn）为30000至200000以及重均分子量（Mw）/数均分子量（Mn）为1.4至3.0的纤维素酯。
• Polarizing plate and liquid crystal display apparatus using the same
  申请人：Takebe Takashi

  公开号：US20070048459A1

  公开（公告）日：2007-03-01

  A polarizing plate includes two transparent supports A and B; and a polarizer sandwiched between the two transparent supports A and B; wherein (i) the transparent support A is a stretched cellulose ester film (a) which contains a non-phosphoric acid ester plasticizer and substantially does not contain a phosphoric acid ester plasticizer, and wherein (ii) the transparent support B is a stretched cellulose ester film (b) which has a retardation value R 0 of from 0 nm to 10 nm and a retardation value R t of from −30 nm to 20 nm, and the retardation value R 0 and the retardation value R t are defined by the following formulas (I) and (II): Ro =( nx−ny )× d Formula (I): Rt =( nx+ny )/2− nz}×d. Formula (II):

  一个偏振板包括两个透明支撑体A和B；以及夹在两个透明支撑体A和B之间的偏振器；其中(i)透明支撑体A是一种拉伸纤维素酯薄膜(a)，它包含一种非磷酸酯增塑剂，且基本不含磷酸酯增塑剂；而(ii)透明支撑体B是一种拉伸纤维素酯薄膜(b)，其具有从0纳米到10纳米的延迟值R0和从-30纳米到20纳米的延迟值Rt，其中延迟值R0和延迟值Rt由以下公式(I)和(II)定义：Ro=(nx-ny)×d公式(I)：Rt=(nx+ny)/2-nz}×d。公式(II)：
• Manufacturing Method of Polarizing Plate Protective Film, Polarizing Plate Protective Film, Polarizing Plate, and Liquid Crystal Display Device
  申请人：Kasahara Kenzo

  公开号：US20100239787A1

  公开（公告）日：2010-09-23

  A process for producing a cellulose-ester-resin-containing protective film for polarizers through film formation by melt casting. The protective film diminishes long-period optical unevenness and suffers no unevenness even after long-term storage. Also provided are a protective film for polarizers, a polarizer employing the film, and a liquid-crystal display. The process for producing a protective film for polarizers is a process for producing by the melt casting method a polarizer-protective film containing a cellulose ester resin. The process for producing a protective film for polarizers is characterized in that the protective film contains at least one compound selected among compounds represented by the following general formula (I) and compounds having an acrylate or methacrylate group and a phenolic hydroxy group in the same molecule and that the protective film extruded from a casting die at a draw ratio of 10-30 during film formation by melt casting is transferred while holding/pressing it between a touch roll having an elastic surface and a cooling roll.

  一种通过熔融铸造进行膜形成的生产含有纤维素酯树脂的偏光片保护膜的方法。该保护膜减少了长周期光学不均匀性，并且即使长期存储后也不会出现不均匀性。还提供了用于偏光片的保护膜，使用该膜的偏光器和液晶显示器。生产偏光片保护膜的方法是通过熔融铸造法生产含有纤维素酯树脂的偏光片保护膜的方法。生产偏光片保护膜的方法的特点在于，保护膜包含以下通式（I）所代表的化合物中选择的至少一种化合物和在同一分子中具有丙烯酸酯或甲基丙烯酸酯基和酚羟基的化合物，并且在熔融铸造过程中，通过保持/压制保护膜在具有弹性表面的触摸辊和冷却辊之间转移，以拉伸比为10-30的方式挤出保护膜。
• METHOD FOR RECOVERING POLYCARBONATE RESIN FROM DISCARDED OPTICAL DISC AND/OR RECOVERED OPTICAL DISC, FLAME-RETARDANT POLYCARBONATE RESIN COMPOSITION, INJECTION MOLDED BODY, AND MOLDED ARTICLE FOR OPTICAL USE
  申请人：Isozaki Toshio

  公开号：US20130018115A1

  公开（公告）日：2013-01-17

  Provided is a method for recovering a polycarbonate resin from a discarded optical disk and/or a recovered optical disk, which has a polycarbonate resin substrate. The following process steps (I) and (II) are applied to a chemically treated product, which is obtained by crushing a discarded optical disk and/or a recovered optical disk, and chemically treating the resulting crushed product. Process step (I): a step containing (a) removing a magnetic metal foreign matter with a magnet, and (b) identifying a colored foreign matter with an optical camera, and removing the colored foreign matter. Process step (II): a step containing detecting the presence of a metal foreign matter with a metal foreign matter detector, and removing a resin containing the metal foreign matter.

  提供了一种从废弃的光盘和/或回收的光盘中回收聚碳酸酯树脂的方法，该光盘具有聚碳酸酯树脂基板。将以下工艺步骤（I）和（II）应用于化学处理过的产品，该产品是通过粉碎废弃的光盘和/或回收的光盘，并对所得到的碎片进行化学处理得到的。工艺步骤（I）：包含（a）使用磁铁去除磁性金属异物，和（b）使用光学相机识别有色异物并去除有色异物。工艺步骤（II）：包含使用金属异物检测器检测金属异物的存在，并去除含有金属异物的树脂。