(2-heptylundecyl) diphenyl phosphate | 183810-88-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: (2-heptylundecyl) diphenyl phosphate
• 英文别名: 2-Heptylundecyl diphenyl phosphate
• CAS: 183810-88-0
• 化学式: C₃₀H₄₇O₄P
• 分子量: 502.675
• InChiKey: XAULERQIGBCQTE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.7
• 重原子数：
  35
• 可旋转键数：
  21
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  dimethylamino pyridine triethylamine 、 2-庚基-1-十一烷醇 、 二苯基次膦酰氯 生成 (2-heptylundecyl) diphenyl phosphate
  参考文献：
  名称：

  摘要：

  DOI：

文献信息

• Process to prepare alkyl phenyl phosphates
  申请人：Akzo Nobel N.V.

  公开号：EP1526137A1

  公开（公告）日：2005-04-27

  The present invention relates to a process to prepare dialkyl monophenyl phosphate, monoalkyl diphenyl phosphate or mixtures thereof wherein dichloromonophenyl phosphate and/or monochlorodiphenyl phosphate is reacted with an aliphatic alcohol in the presence of a Lewis acid catalyst and in the absence of solvent at a temperature of 40 to 200°C and a pressure of 0 to 1 bar. The present invention further relates to mixtures of monoalkyl diphenyl phosphates and dialkyl monophenyl phosphates obtainable from the above process and the use of such mixtures as a plasticiser and/or a flame retardant.

  本发明涉及一种制备二烷基单苯酸酯、单烷基二苯酸酯或其混合物的方法，其中在无溶剂存在的情况下，以路易斯酸催化剂为催化剂，在40至200°C温度和0至1巴压力下，将二氯单苯酸酯和/或单氯二苯酸酯与脂肪族醇反应。本发明还涉及从上述方法获得的单烷基二苯酸酯和二烷基单苯酸酯的混合物以及将这种混合物用作增塑剂和/或阻燃剂的用途。
• PROCESS TO PREPARE ALKYL PHENYL PHOSPHATES
  申请人：Akzo Nobel N.V.

  公开号：EP1685141A1

  公开（公告）日：2006-08-02
• Durable Flame Retardant Finish for Cellulosic Materials
  申请人：De Kleine A. Lambertus

  公开号：US20070270616A1

  公开（公告）日：2007-11-22

  A process is provided for reacting dichloromonophenyl phosphate and monochlorodiphenyl phosphate with aliphatic alcohol in the presence of a Lewis acid catalyst and absence of solvent, at a temperature above 60 to 200° C. and pressure of 0.001 to 1.1 bara, and sparging the reaction mixture with an inert carrier gas if the pressure is above 0.67 bars. Mixtures of monoalkyl biphenyl phosphates and dialkyl monophenyl phosphates and use of such mixtures as a plasticizer and/or flame retardant, are also provided.
• US6299887B1
  申请人：——

  公开号：US6299887B1

  公开（公告）日：2001-10-09
• US7700807B2
  申请人：——

  公开号：US7700807B2

  公开（公告）日：2010-04-20