Trineopentylphosphat | 14540-59-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: Trineopentylphosphat
• 英文别名: 1-Propanol, 2,2-dimethyl-, phosphate (3:1)；tris(2,2-dimethylpropyl) phosphate
• CAS: 14540-59-1
• 化学式: C₁₅H₃₃O₄P
• 分子量: 308.398
• InChiKey: GQCAYQSZLDQITO-UHFFFAOYSA-N

物化性质

• 熔点：
  80 °C
• 沸点：
  149-152 °C(Press: 14 Torr)
• 密度：
  0.965±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  20
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  新戊醇 在 吡啶 、 乙醚 、 三氯氧磷 作用下， 生成 Trineopentylphosphat
  参考文献：
  名称：

  Gerrard; Nechvatal; Wilson, Journal of the Chemical Society, 1950, p. 2090

  摘要：

  DOI：

文献信息

• Method for Producing Quaternary Ammonium Compounds
  申请人：Szarvas Laszlo

  公开号：US20070254822A1

  公开（公告）日：2007-11-01

  The present invention relates to a process for preparing quaternary ammonium compounds, which comprises reacting compounds comprising an sp 3 -hybridized nitrogen atom with a dialkyl sulfate or trialkyl phosphate and subjecting the resulting ammonium compound to an anion exchange.

  本发明涉及一种制备季铵盐化合物的方法，包括将含有sp3杂化氮原子的化合物与二烷基硫酸盐或三烷基磷酸酯反应，并将所得的铵盐化合物进行阴离子交换。
• Hydrocarbon and phosphate triester formation during homolytic hydrolysis of organophosphonium ions: an alternate model for organophosphonate biodegradation
  作者：L. Z. Avila、P. A. Bishop、J. W. Frost

  DOI：10.1021/ja00006a049

  日期：1991.3.1

  trifluoromethanesulfonates with base and organic peroxides results in carbon to phosphorus (C-P) bond cleavage. The products of the homolytic hydrolysis are hydrocarbons and trineopentyl phosphate. Reaction of the organophosphonium ions with only base leads to oxygen to phosphorus (O-P) bond cleavage with a complete absence of C-P bond cleavage. The likely intermediacy of a pentacovalent phosphonyl radical during

  用碱和有机过氧化物处理有机三五氧鏻三氟甲磺酸盐会导致碳磷 (CP) 键断裂。均裂水解的产物是碳氢化合物和磷酸三新戊酯。有机鏻离子仅与碱反应导致氧至磷 (OP) 键断裂，而完全没有 CP 键断裂。在均裂水解过程中五共价膦酰基自由基的可能中间体为在有机膦酸盐生物降解过程中观察到的 CP 键裂解的替代机械配方提供了基础。该配方的独特之处在于它预测无机磷酸盐是微生物介导的 CP 键裂解的直接含磷产物
• VAPOR PRESSURE DEPRESSANT AND USE THEREOF
  申请人：Daihachi Chemical Industry Co., Ltd.

  公开号：EP1561793A1

  公开（公告）日：2005-08-10

  A vapor pressure reducing agent for polyurethane foam, comprising at least one compound represented by the following formula (1): wherein R1, R2 and R3 represent a straight-chain alkyl group or branched-chain alkyl group having 2 to 5 carbon atoms, R1, R2 and R3 may be the same or different, with the proviso that the compound wherein R1, R2 and R3 are all ethyl groups is excluded, the compound having a total acid content of 650 mg KOH or less as measured in accordance with MIL H-19457; and a premix composition for producing polyurethane foam, comprising a polyol, a curing catalyst, 1,1,1,3,3-pentafluoropropane, a foaming stabilizer, and the vapor pressure reducing agent described above.

  一种用于聚氨酯泡沫塑料的蒸汽减压器，由至少一种下式(1)代表的化合物组成： 其中 R1、R2 和 R3 代表具有 2 至 5 个碳原子的直链烷基或支链烷基，R1、R2 和 R3 可以相同或不同，但不包括 R1、R2 和 R3 全为乙基的化合物，根据 MIL H-19457 测量，该化合物的总酸含量为 650 毫克 KOH 或更少；一种用于生产聚氨酯泡沫塑料的预混组合物，包括多元醇、固化催化剂、1,1,1,3,3-五氟丙烷、发泡稳定剂和上述蒸汽减压器。
• POLYOLEFIN RESIN PRE-EXPANDED PARTICLES AND POLYOLEFIN RESIN IN-MOLD EXPANSION-MOLDED ARTICLE COMPRISING POLYOLEFIN RESIN PRE-EXPANDED PARTICLES
  申请人：Kaneka Corporation

  公开号：EP2420533A1

  公开（公告）日：2012-02-22

  Polyolefin-based resin pre-expanded particles include a polyolefin-based resin composition including a polyolefin-based resin, a sterically hindered amine ether flame retardant expressed by the general formula (1): R1NHCH2CH2CH2NR2CH2CH2NR3CH2CH2CH2NHR4 (1), and a phosphoric ester. The polyolefin-based resin pre-expanded particles are flame retardant polyolefin-based resin pre-expanded particles that can have good in-mold expansion moldability and exhibit excellent flame resistance compared to the conventional pre-expanded particles even when molded into a sample having a higher density or a larger thickness without using a halogen flame retardant, and that do not generate harmful gas during burning.

  聚烯烃基树脂预膨胀颗粒包括一种聚烯烃基树脂组合物，其中包括聚烯烃基树脂、通式(1)表示的立体受阻胺醚阻燃剂： R1NHCH2CH2CH2NR2CH2CH2NR3CH2CH2CH2NHR4 (1) 和磷酸酯。这种聚烯烃基树脂预膨化粒子是一种阻燃性聚烯烃基树脂预膨化粒子，与传统的预膨化粒子相比，即使在不使用卤素阻燃剂的情况下，将其模塑成密度更大或厚度更大的样品，也能具有良好的模内膨胀成型性和优异的阻燃性，并且在燃烧时不会产生有害气体。
• RESIN COMPOSITION AND LAMINATE IN WHICH SAME IS USED
  申请人：Riken Technos Corporation

  公开号：EP3508528A1

  公开（公告）日：2019-07-10

  Problem: To provide a resin composition that has excellent adhesiveness to bare copper, is capable of retaining adhesiveness to bare copper even when exposed to a hot and humid environment for a long period of time, and enables compliance to standards for high rated temperatures or accreditation to the standards to be achieved without involving a cross-linking step, and to provide a laminate that can be suitably used as a covering material for flexible flat cables in which the resin composition is used. Solution: A resin composition for an adhesive layer of a laminate, the resin composition, containing: (A) 55 to 85 mass% of an acid modified polypropylene-based resin; and (B) 45 to 15 mass% of a copolymer of ethylene and one or more comonomers selected from the group consisting of vinyl acetate, an alkyl methacrylate, and an alkyl acrylate; in which the total of the component (A) and the component (B) is 100 mass%; and in which an acid modified amount of the component (A) is 0.5 to 10 mol%.

  问题：提供一种树脂组合物，该树脂组合物对裸铜具有极佳的粘附性，即使长时间暴露在湿热环境中也能保持对裸铜的粘附性，并且无需交联步骤即可达到高额定温度标准或通过标准认证，还提供一种层压材料，该层压材料可适当用作使用该树脂组合物的柔性扁平电缆的覆盖材料。 解决方案一种用于层压板粘合层的树脂组合物，该树脂组合物含有：(A)55-85 质量％的酸改性聚丙烯基树脂；和(B)45-15 质量％的乙烯与一种或多种选自乙酸乙烯酯、甲基丙烯酸烷基酯和丙烯酸烷基酯组的共聚单体的共聚物；其中组分(A)和组分(B)的总量为 100 质量％；组分(A)的酸改性量为 0.5-10 摩尔％。