3,3,8,8,10,10-hexamethyl-9-[1-(4-oxiranylmethoxy-phenyl)-ethoxy]-1,5-dioxa-9-aza-spiro[5.5]undecan | 434898-80-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氮杂螺癸烷衍生物
• 英文名称: 3,3,8,8,10,10-hexamethyl-9-[1-(4-oxiranylmethoxy-phenyl)-ethoxy]-1,5-dioxa-9-aza-spiro[5.5]undecan
• 英文别名: 1,5-Dioxa-9-azaspiro(5.5)undecane, 3,3,8,8,10,10-hexamethyl-9-(1-(4-(oxiranylmethoxy)phenyl)ethoxy)-；3,3,8,8,10,10-hexamethyl-9-[1-[4-(oxiran-2-ylmethoxy)phenyl]ethoxy]-1,5-dioxa-9-azaspiro[5.5]undecane
• CAS: 434898-80-3
• 化学式: C₂₅H₃₉NO₅
• 分子量: 433.588
• InChiKey: BZDPHNAHPCCTIC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  31
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.76
• 拓扑面积：
  52.7
• 氢给体数：
  0
• 氢受体数：
  6

文献信息

• N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, with glycidyl or alkylcarbonyl groups as functional initiators for controlled radical polymerization
  申请人：——

  公开号：US20040049043A1

  公开（公告）日：2004-03-11

  The present invention relates to selected glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polaylkyl-piperidine compounds forming an open chain or cyclic ketal structure, a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) a glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polyalkyl-piperidine nitroxide initiator compound. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers and the use of glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polyalkyl-piperidine nitroxide initiators for radical polymerization.

  本发明涉及选择的含有环氧基或羰基基团的N-烷氧基-4,4-二氧-聚烯烃-哌啶化合物，形成开链或环状的酮缩结构，一种聚合物组合物，包括a)至少一种乙烯基不饱和单体和b)含有环氧基或羰基基团的N-烷氧基-4,4-二氧-聚烯烃-哌啶自由基引发剂化合物。本发明的进一步方面包括聚合乙烯基不饱和单体的方法以及使用含有环氧基或羰基基团的N-烷氧基-4,4-二氧-聚烯烃-哌啶自由基引发剂进行自由基聚合的方法。
• N-alkoxy-4, 4-dioxy-polyalkyl-piperidine compounds, with glycidyl or alkylcarbonyl groups as functional initiators for controlled radical polymerization
  申请人：Fuso Francesco

  公开号：US20070173570A1

  公开（公告）日：2007-07-26

  The present invention relates to selected glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds forming an open chain or cyclic ketal structure, a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) a glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polyalkyl-piperidine nitroxide initiator compound. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers and the use of glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polyalkyl-piperidine nitroxide initiators for radical polymerization.

  本发明涉及选择的含有环氧基或酮基的N-烷氧基-4,4-二氧基-聚烷基哌啶化合物，形成开链或环状的环缩酮结构，以及包括a) 至少一种乙烯基不饱和单体和b) 含有环氧基或酮基的N-烷氧基-4,4-二氧基-聚烷基哌啶亚硝酰化合物的可聚合组合物。本发明的其他方面包括聚合乙烯基不饱和单体的方法以及使用含有环氧基或酮基的N-烷氧基-4,4-二氧基-聚烷基哌啶亚硝酰化合物进行自由基聚合的方法。
• Stable free radical polymers
  申请人：Firestone Polymers, LLC

  公开号：EP1473312A2

  公开（公告）日：2004-11-03

  A functional polymer having at least one substituent capable of forming a stable free radical is formed by polymerizing a diene monomer, such as butadiene, to form a first polymer block of the functional polymer. The first polymer block has a weight average molecular weight of less than 150,000. A vinyl aromatic monomer, such as styrene, is polymerized to form at least a second polymer block of the functional polymer. The copolymer is contacted with a stable free radical providing compound to form the functional polymer. By adding sufficient vinyl aromatic monomer, a low molecular weight functional rubber polymer can be rendered processable at ambient temperatures, while maintaining a solution viscosity which is suited to subsequent free radical catalyzation of vinyl aromatic monomers.

  通过聚合二烯单体（如丁二烯）形成功能聚合物的第一聚合物嵌段，从而形成具有至少一个能够形成稳定自由基的取代基的功能聚合物。第一聚合物嵌段的重量平均分子量小于 15 万。聚合乙烯基芳香族单体（如苯乙烯），至少形成功能聚合物的第二聚合物嵌段。将共聚物与提供稳定自由基的化合物接触，形成官能聚合物。通过添加足够的乙烯基芳香族单体，可使低分子量的功能性橡胶聚合物在环境温度下进行加工，同时保持溶液粘度，以适合乙烯基芳香族单体的后续自由基催化。
• Colour photographic recording material
  申请人：Biry Stephane

  公开号：US20050079455A1

  公开（公告）日：2005-04-14

  A colour photographic material which contains on a support at least one blue-sensitive silver halide emulsion layer containing at least one yellow coupler, at least one green-sensitive silver halide emulsion layer containing at least one magenta coupler, at least one red-sensitive silver halide emulsion layer containing at least one cyan coupler, together with customary non-light-sensitive layers, characterized in that at least one layer contains a compound of formula (I) or (II) wherein the R 1 -radicals and R 2 -radicals are preferably methyl; and wherein the compounds of formula (II) are preferably (III) R 3 is a radical —H(CH 3 )—X-D, wherein X is phenylene. D is a group (IV) or a group —C(O)—C 1 -C 18 alkyl or a group —O—CH 2 —CH(OH)—CH 2 —NR 12 R 13 , with R 12 and R 13 being C 1 -C 18 alkyl or together form a 4 to 8 membered ring as defined in claim 1, or D is a group —O—CH 2 —CH(OH)—CH 2 —N(R 12 )—CH 2 CHOH—CH 2 —O— or —O—CH 2 —CH(OH)—CH 2 —W—CH 2 —CHOH—CH 2 —O— with W being a divalent amino group (—N(C 1 -C 18 alkyl)-), a polyamine residue, a polyethyleneimine residue or a polyoxyalkyleneamine residue; Z and Z′ are for example C 1 -C 12 alkyl, C 3 -C 12 alkenyl, C 3 -C 12 alkinyl, C 5 -C 8 cycloalkyl, or Z and Z′ together bivalent groups such as —CH 2 —CH 2 — or —CH 2 —C(R 18 )(R 19 )—CH(R 20 )—.

  一种彩色感光材料，在支撑体上含有至少一个含有至少一个黄色耦合剂的蓝色感光卤化银乳剂层、至少一个含有至少一个品红色耦合剂的绿色感光卤化银乳剂层、至少一个含有至少一个青色耦合剂的红色感光卤化银乳剂层，以及惯用的非感光层，其特征在于至少有一层含有式(I)或(II)化合物，其中R 1 -自由基和 R 2 -自由基最好是甲基；式 (II) 的化合物最好是 (III) R 3 是基团-H(CH 3 )-X-D，其中 X 是亚苯基。D 是基团 (IV) 或基团 -C(O)-C 1 -C 18 烷基或基团 -O-CH 2 -CH（OH）-CH 2 -NR 12 R 13 ，其中 R 12 和 R 13 为 C 1 -C 18 或 D 是一个基团 -O-CH 2 -CH（OH）-CH 2 -N（R 12 )-CH 2 CHOH-CH 2 -O-或-O-CH 2 -CH(OH)-CH 2 -W-CH 2 -CHOH-CH 2 -O-，其中 W 是二价氨基（-N(C 1 -C 18 烷基）、聚胺残基、聚乙烯亚胺残基或聚氧亚烷基胺残基；Z 和 Z′例如是 C 1 -C 12 烷基、C 3 -C 12 烯基，C 3 -C 12 烷基、C 5 -C 8 环烷基，或 Z 和 Z′共同组成的二价基团，如 -CH 2 -CH 2 - 或 -CH 2 -C(R 18 )(R 19 )-CH(R 20 )-.
• High gloss rubber modified monovinylidene aromatic polymers produced by a mass polymerization process
  申请人：Vanspeybroeck S Rony

  公开号：US20060122331A1

  公开（公告）日：2006-06-08

  The present invention relates to a mass polymerized rubber-modified polymeric composition comprising a continuous matrix phase of a polymer of a monovinylidene aromatic monomer, and optionally, an ethylenically unsaturated nitrile monomer, and rubber particles produced from a functionalized diene rubber.

  本发明涉及一种大规模聚合的橡胶改性聚合物组合物，该组合物包含由单亚乙烯基芳香族单体和乙烯基不饱和丁腈单体聚合物组成的连续基相，以及由官能化二烯橡胶制成的橡胶颗粒。