Bi2Pd, β

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 各种混合金属/非金属
• 英文名称: Bi2Pd, β
• 化学式: Bi₂Pd
• 分子量: 524.381
• InChiKey: QMOOSEFDIDVKET-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -2.37
• 重原子数：
  3.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  tin 、 Bi2Pd, β 、 溴化铋 以 neat (no solvent, solid phase) 为溶剂， 生成
  参考文献：
  名称：

  嵌入盐基质中的一维金属：{}^1_\infty[PdBi6][(Bi,Sn)1-δBr5-δ'] 的合成、调制晶体结构、导电性和化学键合

  摘要：

  富金属化合物 (1)(无穷大)[PdBi6][(Bi,Sn)(1-delta)Br5-delta,] delta(1) = 2/13, delta(1)' = 5/26,或 delta(2) = delta(2)' = 2/12 由 Bi2Pd、BiBr3 和 Sn 在 300 摄氏度合成。晶体结构包含金属间棒 (1)(无穷大)[Pd@Bi2/1Bi8/2] (2.5+) 嵌入类盐基质中，由溴化铋 (III)-锡酸盐 (II) 八面体 [(Bi,Sn)(n)Br4n+2](m-) (n = 2, 3) 和分离的溴离子。结晶金属盐混合物中两个子系统的计量不相容性导致与复杂上层结构相关的盐盘的非化学计量。平均结构在正交空间群 Pmmm 中描述，a 近似于 408 pm，b 近似于 2263 pm，c 近似于 849 pm。它假装连接八面体的空位和取向紊乱的统计分布。通过选择调制矢量 q(i) =

  DOI：

  10.1002/zaac.200900191
• 作为产物：
  描述：

  Bi4[tetrakis(diphenylmethylphosphine)palladium] dibromodiphenylbismuthide 以 甲苯 为溶剂， 以33%的产率得到Bi2Pd, β
  参考文献：
  名称：

  Different Ways To Distort a Tetracapped Tetrahedron on Route to Forming an E₄M₄ Cubane:  The Case of [E₄(Pd(PPh₂Me)₂)₄][Ph₂EX₂]₂ (E = Sb, X = Cl; E = Bi, X = Br)

  摘要：

  Tetrakis(diphenylmethylphosphine)palladium reacts with diphenylantimony chloride or diphenyl-bismuth bromide to give [E-4(PdL2)(4)][Ph2EX2](2) (L = PPh2Me, 1: E = Sb, X = Cl; 2: E = Pi, X = Br) which have been characterized spectroscopically and by single-crystal X-ray diffraction for [Sb-4(PdL2)(4)][Ph2SbCl2](2). 0.5THF and [Bi-4(PdL2)(4)][Ph2BiBr2](2). These compounds are electron-rich based on electron counting formalisms. The additional cluster electrons can be rationalized by the ability of group 15 elements to show hypervalency, particularly those elements such as Sb and Pi which show more metal character. The electronic structure of the compounds and of related species has been examined by EHT and DFT calculations. Relationships to other cubane-derived structures are derived, and the stability of structurally related M4E4 hypothetical clusters is discussed. Compounds 1 and 2 decompose thermally to give Bi2Pd and SbPd.

  DOI：

  10.1021/ja982902u

文献信息

• Influence of Pb doping on superconductivity of α-BiPd and β-Bi2Pd alloys
  作者：Miao Wang、Suyuan Zeng、Baichuan Zhu、Dake Wang、Dan Lin、Yi Ren、Lulu Tang、Kaibin Tang

  DOI：10.1016/j.materresbull.2018.12.032

  日期：2019.4

  systematically examined by the magnetic susceptibility and resistivity measurements. Both alloy systems have shown bulk superconductivity and metallic conductivity in normal state. Furthermore, the superconducting onset temperature (Tc) gradually decreased with higher Pb content for both systems. The Tc dropped from 3.7 K for BiPd to 2.7 K for Bi0.8Pb0.2Pd, whereas the Tc dropped from 5.3 K for Bi2Pd to

  摘要 采用简便的固相反应法合成了一系列掺铅铋基合金α-Bi1-xPbxPd (0 ≤ x ≤ 0.5) 和β-Bi2-xPbxPd (0 ≤ x ≤ 0.6)。粉末X射线衍射证实，Pb掺杂后样品的晶体结构保持不变，随着Pb含量的增加，晶胞体积减小。已通过磁化率和电阻率测量系统地研究了 Pb 掺杂效应对 BiPd 和 Bi2Pd 合金超导性的影响。两种合金系统在正常状态下都显示出体超导性和金属导电性。此外，两种系统的超导起始温度（Tc）随着铅含量的增加而逐渐降低。Tc 从 BiPd 的 3.7 K 下降到 Bi0.8Pb0.2Pd 的 2.7 K，而 Bi2Pd 的 Tc 从 5.3 K 下降到 Bi1.5Pb0.5Pd 的 2.4 K。
• Low-temperature thermal expansion of the topological material candidates <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline" id="d1e853" altimg="si70.svg"><mml:mi>β</mml:mi></mml:math>-PtBi<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline" id="d1e858" altimg="si71.svg"><mml:msub><mml:mrow /><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:math> and <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline" id="d1e866" altimg="si70.svg"><mml:mi>β</mml:mi></mml:math>-PdBi<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline" id="d1e872" altimg="si71.svg"><mml:msub><mml:mrow /><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:math>
  作者：V.F. Correa、P. Pedrazzini、D.G. Franco、A.J. Rosa、B. Rubrecht、N. Haberkorn

  DOI：10.1016/j.physb.2022.414102

  日期：2022.9

  We report on the low-temperature (T< 120 K) thermal expansion of the bismuth-based topological semimetal β-PtBi2 and topological superconductor β-PdBi2 candidates. The linear thermal-expansion coefficient of tetragonal β-PdBi2 shows a pronounced anisotropy between the a- and c-axis while the volume thermal-expansion coefficient αV (β-PdBi2) is considerable larger than αV (β-PtBi2). The coefficient

  我们报告低温（吨<120 K) 铋基拓扑半金属的热膨胀β-铂铋2和拓扑超导体β-PdBi2候选人。四方的线性热膨胀系数β-PdBi2显示出明显的各向异性一个- 和C-轴而体积热膨胀系数α五 (β-PdBi2) 明显大于α五 (β-铂铋2）。系数α五 (β-铂铋2) 几乎与实验比热相匹配，从中得出德拜温度θD=199获得 K。另一方面，α五 (β-PdBi2) 合理地拟合德拜模型θD=138K，从低温比热中提取。一个几乎恒定的 Grüneisen 参数Γ≈两种化合物均获得 2。在这两种化合物中都没有观察到磁致伸缩μ0H=16T. 我们将我们的结果与其他基于 Bi 的拓扑材料进行比较。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Bi: MVol., 32, page 81 - 83
  作者：

  DOI：——

  日期：——
• Different Ways To Distort a Tetracapped Tetrahedron on Route to Forming an E₄M₄ Cubane:  The Case of [E₄(Pd(PPh₂Me)₂)₄][Ph₂EX₂]₂ (E = Sb, X = Cl; E = Bi, X = Br)
  作者：Joseph L. Stark、Brian Harms、Ilse Guzman-Jimenez、Kenton H. Whitmire、Régis Gautier、Jean-François Halet、Jean-Yves Saillard

  DOI：10.1021/ja982902u

  日期：1999.5.1

  Tetrakis(diphenylmethylphosphine)palladium reacts with diphenylantimony chloride or diphenyl-bismuth bromide to give [E-4(PdL2)(4)][Ph2EX2](2) (L = PPh2Me, 1: E = Sb, X = Cl; 2: E = Pi, X = Br) which have been characterized spectroscopically and by single-crystal X-ray diffraction for [Sb-4(PdL2)(4)][Ph2SbCl2](2). 0.5THF and [Bi-4(PdL2)(4)][Ph2BiBr2](2). These compounds are electron-rich based on electron counting formalisms. The additional cluster electrons can be rationalized by the ability of group 15 elements to show hypervalency, particularly those elements such as Sb and Pi which show more metal character. The electronic structure of the compounds and of related species has been examined by EHT and DFT calculations. Relationships to other cubane-derived structures are derived, and the stability of structurally related M4E4 hypothetical clusters is discussed. Compounds 1 and 2 decompose thermally to give Bi2Pd and SbPd.
• Roessler, Zeitschrift fur anorganische Chemie, 1895, vol. 9, p. 68 - 68
  作者：Roessler

  DOI：——

  日期：——