摩熵化学
数据库官网
小程序
打开微信扫一扫
首页 分子通 化学资讯 化学百科 反应查询 关于我们
请输入关键词

sodium dizirconium triphosphate

中文名称
——
中文别名
——
英文名称
sodium dizirconium triphosphate
英文别名
sodium dizirconium tris(phosphate);sodium dizirconium tris(orthophosphate);sodium dizirconium orthophosphate;sodium zirconate-phosphate;sodium zirconium orthophosphate;sodium zirconium phosphate;zirconium sodium phosphate;Sodium;zirconium(4+);phosphate
sodium dizirconium triphosphate化学式
CAS
——
化学式
Na*3O4P*2Zr
mdl
——
分子量
490.352
InChiKey
YHKRPJOUGGFYNB-UHFFFAOYSA-K
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

计算性质

  • 辛醇/水分配系数(LogP):
    -5.82
  • 重原子数:
    7
  • 可旋转键数:
    0
  • 环数:
    0.0
  • sp3杂化的碳原子比例:
    0.0
  • 拓扑面积:
    86.2
  • 氢给体数:
    0
  • 氢受体数:
    4

反应信息

  • 作为反应物:
    描述:
    sodium silicate 、 sodium dizirconium triphosphatesodium hydroxide 作用下, 以 为溶剂, 生成 Sodium;zirconium(4+);silicate
    参考文献:
    名称:
    一种制备Na 4 Zr 2(SiO 4)3的水热新途径
    摘要:
    Na 4 Zr 2(SiO 4)3是由NaZr 2(PO 4)3与Na 2 SiO 3在比以前使用的更低的温度和压力结晶条件下水热制备的,并通过X射线粉末衍射鉴定, Raman和29 Si MAS NMR光谱。
    DOI:
    10.1039/c39900001166
  • 作为产物:
    描述:
    zirconyl nitrate 在 磷酸 、 sodium carbonate 作用下, 以 为溶剂, 生成 sodium dizirconium triphosphate
    参考文献:
    名称:
    NASICON系统Na 1 + 4 y Zr 2- y(PO 4)3的31 P MAS NMR研究
    摘要:
    多达四个固定共振在标题系统独立于组合物的观察:纳兹尔2(PO 4)3(Ý ≲0.5),钠3的Zr 1.5(PO 4)3(Ý 0),钠4 P 2 ö 7(y 0)和第四行,到目前为止我们还无法用结构术语来解释。Na 3 Zr 1.5(PO 4)3的31 P化学位移参数为:δ= -11.9±0.3ppm,Δσ= 64±2ppm和η= 0.52±0.05。
    DOI:
    10.1016/0009-2614(88)87237-3
点击查看最新优质反应信息

文献信息

  • The Phases Formed by the Dehydration of Disodium Zirconium(IV) Bis(orthophosphate) Trihydrate and Their Ion-exchange Behavior
    作者:Yasushi Inoue、Yoshimune Yamada
    DOI:10.1246/bcsj.55.792
    日期:1982.3
    The phase transformation of Na2Zr(PO4)2·3H2O which had been obtained from zirconium(IV) bis(hydrogenphosphate) monohydrate(α-zirconium phosphate), prepared by the direct precipitation method, was studied by means of gravimetry, X-ray analysis, and acid-base titration. When the material was heated for 2 d, it was transformed to a monohydrate at 80 °C and then successively to three anhydrous phases,
    以直接沉淀法制备的一水合二磷酸氢锆(α-磷酸锆)为原料,采用重量法、X射线分析法研究了Na2Zr(PO4)2·3H2O的相变, 酸碱滴定。当该材料加热 2 天时,它在 80 °C 下转变为一水合物,然后根据温度依次转变为三个无水相。一水合物也是通过让三水合物在室温下在 P2O5 上放置超过两周而形成的。通过对再水合行为的检查,确认这些过程是不可逆的,由此确定了五种变体二正磷酸锆 (IV) 的储存条件。令人特别感兴趣的是,当它在室温下在空气中或干燥器中静置时,第二个无水相回复到第一个无水相。回复率随热处理温度和...
  • Zirconium Phosphate Supported MOF Nanoplatelets
    作者:Yuwei Kan、Abraham Clearfield
    DOI:10.1021/acs.inorgchem.6b00710
    日期:2016.6.6
    nanoplatelets through a step-by-step seeding procedure. Sodium ion exchanged zirconium phosphate, NaZrP, nanoplatelets were judiciously selected as support for layer-by-layer (LBL) assembly of Cu(II) and benzene-1,3,5-tricarboxylic acid (H3BTC) linkers. The first layer of Cu(II) is attached to the surface of zirconium phosphate through covalent interaction. The successive LBL growth of HKUST-1 film is
    我们报告了通过分步播种程序制备HKUST-1金属-有机骨架纳米片的罕见例子。明智地选择了钠离子交换的磷酸锆NaZrP纳米片作为Cu(II)和苯-1,3,5-三羧酸(H 3 BTC)接头的逐层(LBL)组装的载体。Cu(II)的第一层通过共价相互作用连接到磷酸锆的表面。然后通过将NaZrP纳米片浸入乙酸铜和H 3的乙醇溶液中,实现HKUST-1膜的连续LBL生长。BTC,分别。可以通过改变生长周期的数量来容易地控制HKUST-1的组装数量,这可以通过粉末X射线衍射和气体吸附分析来表征。HKUST-1在NaZrP上的成功构建还受到其对环己烯氧化的催化性能的支持。
  • Antibacterial compositions and antibacterial products
    申请人:Ono Yasuharu
    公开号:US20060182812A1
    公开(公告)日:2006-08-17
    The present invention has an object of improving the processing suitability of an antimicrobial product such as fiber or a film to which is added an antimicrobial composition that includes a silver-based antimicrobial agent such as silver ion-containing tetravalent metal phosphate-based antimicrobial particles. The present invention is an antimicrobial composition that includes tetravalent metal phosphate-based antimicrobial particles represented by Formula (1) and inorganic compound particles having a Mohs hardness of equal to or less than 6, and the maximum particle size of the antimicrobial particles and the inorganic compound particles is substantially equal to or less than 10 μm. Ag a Q b M 2 (PO 4 ) 3 .n H 2 O  (1) In the formula, Q denotes at least one type of ion selected from the group consisting of an alkali metal ion, an alkaline earth metal ion, ammonium ion, and hydrogen ion, M is a tetravalent metal ion, n is a number satisfying 0≦n≦6, a and b are both positive numbers, m is the valence of Q, and a+mb=1. Furthermore, the present invention is an antimicrobial product that contains the antimicrobial composition.
    本发明的目的是改善抗菌产品(如添加了银离子含量四价金属磷酸盐基抗菌颗粒等抗菌成分的纤维或薄膜)的加工适用性。本发明是一种包括由式(1)表示的四价金属磷酸盐基抗菌颗粒和硬度不大于6的无机化合物颗粒的抗菌组合物,其中抗菌颗粒和无机化合物颗粒的最大粒径基本相等或小于10微米。AgaQbM2(PO4)3.nH2O  (1)在该式中,Q表示从碱金属离子、碱土金属离子、铵离子和氢离子组成的离子群中选择的至少一种离子类型,M是四价金属离子,n是满足0≦n≦6的数字,a和b均为正数,m是Q的价数,且a+mb=1。此外,本发明是包含上述抗菌组合物的抗菌产品。
  • NASICON solid electrolytes part III: Sodium conductivity enhancement along domain and grain boundaries
    作者:K.D. Kreuer、H. Kohler、U. Warhus、H. Schulz
    DOI:10.1016/0025-5408(86)90201-1
    日期:1986.2
    Abstract Bulk, grain and domain boundary sodium ion conductivity data are presented for NASICON single crystals and ceramics of composition Na 1+x+4y Zr 2−y Si x P 3−x O 12 (x=0–3, y=0−0.2). For silicate rich compositions the “crystals” are built out of domains and the conductance of the resulting domain boundaries are shown to determine the macroscopically observed conductivity. Grain boundaries in
    摘要 提供了组成为 Na 1+x+4y Zr 2−y Si x P 3−x O 12 (x=0–3, y=0−) 的 NASICON 单晶和陶瓷的体、晶界和畴界钠离子电导率数据0.2)。对于富含硅酸盐的组合物,“晶体”由域构建而成,并且显示所得域边界的电导以确定宏观观察到的电导率。陶瓷中的晶界以类似的方式表现。建议对观察到的现象进行结构性解释。
  • Low thermal expansion of alkali-zirconium phosphates
    作者:G.E. Lenain、H.A. McKinstry、S.Y. Limaye、A. Woodward
    DOI:10.1016/0025-5408(84)90258-7
    日期:1984.11
    Abstract The thermal expansion of all the alkali members of the [NZP] family has been studied using high-temperature x-ray measurements at the back diffraction angles and dilatometry. The discrepancy between the results obtained with both methods is discussed. Some of the phases studied showed very low thermal expansion coefficients (
    摘要 [NZP] 族的所有碱金属成员的热膨胀已经使用高温 X 射线测量在背衍射角和膨胀法进行了研究。讨论了使用两种方法获得的结果之间的差异。研究的一些相显示出非常低的热膨胀系数(
查看更多