4-(2,4-dimethylphenyl)thiomorpholine 1,1-dioxide

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 噻嗪类
• 英文名称: 4-(2,4-dimethylphenyl)thiomorpholine 1,1-dioxide
• 英文别名: 4-(2,4-Dimethylphenyl)-1,4-thiazinane 1,1-dioxide
• 化学式: C₁₂H₁₇NO₂S
• 分子量: 239.338
• InChiKey: QWZSJRDWGDJYAR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  16
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  45.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  二乙烯基砜 、 2,4-二甲基苯胺 在 三氯化铝 作用下， 以 氯苯 为溶剂， 反应 1.0h， 以92%的产率得到4-(2,4-dimethylphenyl)thiomorpholine 1,1-dioxide
  参考文献：
  名称：

  Catalyzed double Michael addition of anilines to vinyl sulfone

  摘要：

  Substituted anilines and vinyl sulfone undergo a facile double Michael addition to form substituted phenylthiomorpholine dioxide, catalyzed with AlCl3 or H3PO4. Scope and conditions were explored. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(03)00702-0

文献信息

• GAS SEPARATION COMPOSITE MEMBRANE, AND GAS SEPARATING MODULE, GAS SEPARATION APPARATUS AND GAS SEPARATION METHOD USING THE SAME
  申请人：FUJIFILM Corporation

  公开号：US20140130669A1

  公开（公告）日：2014-05-15

  A gas separation composite membrane, containing a gas-permeable supporting layer and a gas separating layer containing a crosslinked polyimide resin over the gas-permeable supporting layer, in which the crosslinked polyimide resin has structure in which a polyimide compound is crosslinked and linked, and the polyimide compound is a copolymer having at least an imide group-containing monomer component and a monomer component having a specific polar group; and a module, a gas separation apparatus and a gas separation method using the same.
• US9272248B2
  申请人：——

  公开号：US9272248B2

  公开（公告）日：2016-03-01