Precise conductimetric studies on aqueous solutions of 2 : 2 electrolytes. Part 3.—Detailed study of individual electrolytes
作者:Alan D. Pethybridge、Shahab Soltani Taba
DOI:10.1039/f19827801331
日期:——
This paper reports precise conductance values for dilute (< 4 × 10–3 mol dm–3) aqueous solutions of twenty-three 2:2 salts at 25 °C. Alkaline earth metal sulphates, thiosulphates, dithionates, tetrathionates, ethyl-, n-propyl-, n-butyl-disulphonates and acetylenedicarboxylates were studied. The results are analysed by means of the Lee–Wheaton conductance equation in terms of the limiting molar conductivity
本文报告了25°C下23种2:2盐的稀(<4×10 –3 mol dm –3)水溶液的精确电导值。研究了碱土金属硫酸盐,硫代硫酸盐,二硫酸盐,四硫酸盐,乙基,正丙基,二丁基二磺酸盐和炔二羧酸盐。该结果由利惠顿电导方程的装置在限制摩尔电导率计分析,Λ 0,缔合常数,ķ甲,以及所述关联的距离,- [R 。讨论了这些参数的解释,并将这些值与这些和类似系统上的先前工作进行了比较。