六氟锆酸镁 | 30868-50-9

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 碱土金属盐
• 中文名称: 六氟锆酸镁
• 英文名称: magnesium hexafluorozirconate
• 英文别名: Magnesium hexafluorozirconate(2-)；magnesium;hexafluorozirconium(2-)
• CAS: 30868-50-9
• 化学式: F₆Zr*Mg
• 分子量: 229.519
• InChiKey: WNOUKUPJLOSHGV-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  2.14
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  六氟锆酸镁 、 水 以 neat (no solvent) 为溶剂， 生成 magnesium hexafluorozirconate dihydrate
  参考文献：
  名称：

  Synthesis and studies of magnesium hexafluorozirconates MgZrF6 · nH2O (n = 5, 2, 0)

  摘要：

  Crystalline magnesium hexafluorozirconate MgZrF6 center dot 5H(2)O isostructural to MnZrF6 center dot 5H(2)O, and having a chain-like structure, was synthesized and studied. According to thermogravimetry, the compound undergoes stepwise dehydration in the temperature range of 50-420 degrees C to give the stable phase MgZrF6 center dot 2H(2)O and the final product MgZrF6 isostructural to the cubic modification of MZrF6 (M = Cu, Fe). The vibrational spectra of the initial compound and the dehydration products are analyzed and the structures of the compounds are considered.

  DOI：

  10.1134/s0036023610090020
• 作为产物：
  描述：

  magnesium hexafluorozirconate * ammonium fluoride 以 neat (no solvent) 为溶剂， 生成 六氟锆酸镁
  参考文献：
  名称：

  Krysenko, G. F.; Epov, D. G.; Mel'nichenko, E. I., Russian Journal of Inorganic Chemistry, 1989, vol. 34, p. 1375 - 1377

  摘要：

  DOI：

文献信息

• Effects of coordination environment on the Zr–F symmetric stretching frequency of fluorozirconate glasses, crystals, and melts
  作者：Carol C. Phifer、David J. Gosztola、John Kieffer、C. Austen Angell

  DOI：10.1063/1.459766

  日期：1991.3

  A treatment based on Badger’s rule is used to estimate symmetric stretching frequencies νs of the nonbridging fluorides of various ZrFn groups in the presence of divalent and monovalent countercations. New vibrational spectra of MgZrF6, Ba2ZrF8, and β-BaZr2F10 are presented and incorporated into the method. The factors affecting νs are outlined and discussed in detail. Compilations of estimated frequencies are used to deduce the probable local structure around Zr ions in binary barium fluorozirconate glasses and in fluorozirconate melts containing lithium and sodium ions. It is concluded that the results of Raman spectroscopy indicate the presence of seven- and eight-coordinate Zr in some barium fluorozirconate glasses.