双(4-甲氧基苯基)磷酸酯 | 29138-97-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 中文名称: 双(4-甲氧基苯基)磷酸酯
• 英文名称: bis(4-methoxyphenyl) phosphate
• 英文别名: bis(4-methoxyphenyl) hydrogen phosphate；Phosphorsaeure-di-p-anisylester；Bis-p-methoxyphenylhydrogenphosphat；Di-p-methoxyphenylhydrogenphosphat；phosphoric acid bis-(4-methoxy-phenyl ester)；Phosphorsaeure-bis-(4-methoxy-phenylester)
• CAS: 29138-97-4
• 化学式: C₁₄H₁₅O₆P
• 分子量: 310.243
• InChiKey: XYHQLVGVKWUEOV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  21
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  74.2
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  双(4-甲氧基苯基)磷酸酯 、 异丙醇 在 1,3-二对甲苯基碳二酰亚胺 作用下， 生成 phosphoric acid isopropyl ester bis-(4-methoxy-phenyl) ester
  参考文献：
  名称：

  辐照磷酸二芳基酯。用于制备磷酸单烷基酯的潜在有用的新反应

  摘要：

  一系列简单的二茴香基烷基磷酸的紫外线照射以优异的产率提供了相应的单烷基磷酸。

  DOI：

  10.1039/c3975000928b
• 作为产物：
  描述：

  bis(4-methoxyphenyl) chlorophosphate 在 水 作用下， 反应 8.0h， 以63%的产率得到双(4-甲氧基苯基)磷酸酯
  参考文献：
  名称：

  Hydrogen phosphates: Self initiated organocatalysts for the controlled ring-opening polymerization of cyclic esters

  摘要：

  A series of arylhydrogenphosphates and aryldihydrogenphosphates was synthesized and characterized using spectroscopic methods and single crystal X-ray diffraction. These compounds were assessed as catalysts towards the ring-opening polymerization and proved to be potent organocatalysts for the ring-opening polymerization of cyclic esters. The bulk polymerizations were performed in the absence of external initiator. The polymerization proceeds in a controlled fashion which leads to well defined polyesters with narrow molecular weight distributions. In the post polymerization experiments, kinetics, mechanism and monomer concentration effects were investigated. The kinetic results have confirmed the pseudo-living character of the polymerizations and mechanistic studies suggest that the polymerization operates through a cationic mechanism. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2013.02.006

文献信息

• Noncovalent Modification Strategy with Achiral Phosphoric Acid Diesters for Designing a Chiral Brønsted Base Organocatalyst
  作者：Momoko Hara、Aya Ogawa、Keiji Minagawa、Yasushi Imada、Yukihiro Arakawa

  DOI：10.1246/bcsj.20210462

  日期：2022.4.15

  A strategy for designing chiral Brønsted base organocatalysts through noncovalent modification of a chiral dibasic molecule with an achiral phosphoric acid diester is introduced for the first time. Such a molecular modification concept utilizing acid-base interactions may facilitate the on-demand design of asymmetric organocatalysts, as preliminarily demonstrated in this work.

  首次介绍了一种通过用非手性磷酸二酯对手性二元分子进行非共价修饰来设计手性 Brønsted 碱有机催化剂的策略。这种利用酸碱相互作用的分子修饰概念可以促进不对称有机催化剂的按需设计，正如这项工作中初步证明的那样。
• ONE-PACK TYPE ADHESIVE COMPOSITION FOR DENTAL USE
  申请人：Kuraray Medical Inc.

  公开号：EP1695685A1

  公开（公告）日：2006-08-30

  A hydrophobic acidic group-containing polymeric monomer (a); a water-soluble polymeric monomer (b); water (c); a photopolymerization initiator (d); an aromatic tertiary amine (e) having an electron-withdrawing group; a cross-linkable polymeric monomer (f); and a basic compound (g) for producing a water-soluble salt through a reaction with a part of the hydrophobic acidic group-containing polymeric monomer (a) are included as essential compounding ingredients. A one-part dental adhesive composition that exhibits high adhesive strength and high storage stability in adhesion between a teeth, and more particularly enamel or dentine, and a dental repairing material, and more particularly a resin material, is provided. Since the adhesive composition is one-part type, there is no need to mix in an adhering operation, and in addition, it exhibits high adhesive strength without performing preprocessing (etching processing and priming processing), it is suitably used as a one-step type dental adhesive composition for performing an adhering operation in a teeth repairing treatment in one processing.

  作为重要的复配成分，包括一种含疏水酸性基团的聚合单体（a）；一种水溶性聚合单体（b）；水（c）；一种光聚合引发剂（d）；一种具有抽电子基团的芳香族叔胺（e）；一种可交联聚合单体（f）；以及一种通过与部分含疏水酸性基团的聚合单体（a）反应生成水溶性盐的碱性化合物（g）。 本发明提供了一种单组分牙科粘合剂组合物，该组合物在牙齿（尤其是牙釉质或牙本质）与牙科修复材料（尤其是树脂材料）之间的粘合中具有高粘合强度和高储存稳定性。由于该粘合剂组合物是单组分型的，因此在粘合操作中无需混合，此外，它无需进行预处理（蚀刻处理和打底处理）即可表现出高粘合强度，因此适合用作一步式牙科粘合剂组合物，在牙齿修复治疗中一次处理即可完成粘合操作。
• DENTAL POLYMERIZABLE COMPOSITION
  申请人：Kuraray Medical Inc.

  公开号：EP1787623A1

  公开（公告）日：2007-05-23

  A dental polymerizable composition comprising (a) a fluorine compound comprising a chain polymer having a main chain comprising a monomer unit having a hydrophilic group, and terminal groups comprising a fluoroalkyl group at each of both ends of the main chain; (b) a polymerizable monomer; and (c) a polymerization initiator. The dental polymerizable composition can be suitably used, for example, for dental composite resins, such as dental composite filler materials, crowning materials, and bonding materials; dental adhesive agents, such as teeth-straightening adhesive agents, cavity-coating adhesive agents, and tooth fissure sealing materials; denture base materials, denture base mucosal adjusting materials, fissure sealants, coating agents applied to tooth surface or dental prosthetic, surface glazes, and the like, and especially for various coating applications, for example, a fissure sealant, a coating agent to tooth surface or dental prosthetic, surface stains or a surface glaze, a hypersensitive inhibitor, a dental manicure, or the like.

  一种牙科可聚合组合物，包括(a)氟化合物，其链聚合物的主链由具有亲水基团的单体单元组成，末端基团包括位于主链两端的氟烷基；(b)可聚合单体；以及(c)聚合引发剂。牙科可聚合组合物可适当用于牙科复合树脂，例如牙科复合填充材料、牙冠材料和粘接材料；牙科粘接剂，例如牙齿矫正粘接剂、龋齿涂层粘接剂和牙缝密封材料；义齿基托材料、义齿基托粘膜调节材料、窝沟封闭剂、涂在牙齿表面或义齿上的涂层剂、表面釉料等，特别是用于各种涂层应用，例如窝沟封闭剂、涂在牙齿表面或义齿上的涂层剂、表面染色剂或表面釉料、超敏抑制剂、牙齿修整剂等。
• Phosphorus electrolytic solution containing magnesium ions
  申请人：FUJIFILM Wako Pure Chemical Corporation

  公开号：US10862169B2

  公开（公告）日：2020-12-08

  The present invention relates to an electrolytic solution for a magnesium battery, formed by mixing a compound represented by the following general formula (I), a Lewis acid or a compound represented by the following general formula (A), and a solvent; and the like. In the formula, m represents 0 or 2, n represents 2 in a case of m=0 and represents 0 or 1 in a case of m=2, X1 represents a chlorine atom or a bromine atom, and two R1's each independently represent a magnesium chloride oxy group; a magnesium bromide oxy group; an alkyl group which may have a halogeno group or the like as a substituent; an alkoxy group; an aryl group which may have an alkoxy group or the like as a substituent; an aryloxy group which may have an alkoxy group or the like as a substituent; or a group represented by the following general formula (1), and two R1's may also form the following general formula (2).} (In the formula, four R10's each independently represent an alkyl group, a perfluoroalkyl group, a phenyl group, or a perfluorophenyl group.)

  本发明涉及一种用于镁电池的电解溶液，该溶液由以下通式（I）代表的化合物、路易斯酸或以下通式（A）代表的化合物和溶剂等混合而成。 在式中，m 代表 0 或 2，n 在 m=0 的情况下代表 2，在 m=2 的情况下代表 0 或 1，X1 代表氯原子或溴原子，两个 R1 各自独立地代表氯化镁氧基；溴化镁氧基；烷基，其取代基可以是卤代基或类似物；烷氧基；可具有烷氧基或类似基团作为取代基的芳基；可具有烷氧基或类似基团作为取代基的芳氧基；或由以下通式(1)表示的基团，两个 R1 还可组成以下通式(2)。} (式中，四个 R10 各自独立地代表一个烷基、一个全氟烷基、一个苯基或一个全氟苯基）。
• Dental adhesive composition, preparation and use thereof
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US11160733B2

  公开（公告）日：2021-11-02

  The invention relates to a dental adhesive composition comprising ethylenically unsaturated component(s) with acidic moiety, ethylenically unsaturated component(s) without acidic moiety, water, sensitizing agent(s), reducing agent(s), a silane composition comprising (meth)acrylate functional silane(s) and amino functional silane(s). This composition is in particular useful for adhesively fixing dental restorations based on lithium disilicate and other glass ceramic materials to dental surfaces.

  本发明涉及一种牙科粘合剂组合物，该组合物包括具有酸性分子的乙烯基不饱和组分、不具有酸性分子的乙烯基不饱和组分、水、敏化剂、还原剂、由（甲基）丙烯酸酯官能团硅烷和氨基官能团硅烷组成的硅烷组合物。这种组合物特别适用于将基于二硅酸锂和其他玻璃陶瓷材料的牙齿修复体粘合固定在牙齿表面。