1-甲基丁基磷酸二氢酯 | 84196-06-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 中文名称: 1-甲基丁基磷酸二氢酯
• 英文名称: phosphoric acid (1,3-dimethylbutyl) ester
• 英文别名: (1,3-dimethylbutyl)phosphoric acid；2-Pentanol, 4-methyl-, phosphate；4-methylpentan-2-yl dihydrogen phosphate
• CAS: 84196-06-5
• 化学式: C₆H₁₅O₄P
• 分子量: 182.156
• InChiKey: OYKHBMFBSZKYLC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  11
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  66.8
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  Phosphoric acid 1,3-dimethyl-butyl ester 2-hydroxy-phenyl ester 在 碘苯二乙酸 、 水 作用下， 以 乙腈 为溶剂， 反应 1.0h， 以72%的产率得到1-甲基丁基磷酸二氢酯
  参考文献：
  名称：

  Oxidative Cleavage ofo-Hydroxyphenyl Phosphate by Iodobenzene Diacetate

  摘要：

  AbstractThe protecting o‐hydroxyphenyl group in the synthesis of mono‐ or dialkyl phosphates (6 or 8) could be removed by oxidative cleavage of mono‐ or dialkyl o‐hydroxyphenyl phosphates (3 or 7) using iodobenzene diacetate.

  DOI：

  10.1002/jccs.199900133

文献信息

• Lubricant composition containing an antiwear agent
  申请人：The Lubrizol Corporation

  公开号：US11072758B2

  公开（公告）日：2021-07-27

  The invention provides a lubricant composition comprising an oil of lubricating viscosity and a protic acid salt of an N-hydrocarbyl-substituted gamma-(γ-) or delta-amino(thio)ester. The invention further relates to a method of lubricating a mechanical device with the lubricant composition.

  本发明提供了一种润滑剂组合物，该组合物由具有润滑粘度的油和 N-氢羰基取代的γ-（γ-）或δ-氨基（硫）酯的原酸盐组成。本发明还涉及一种用润滑剂组合物润滑机械装置的方法。
• LUBRICANT COMPOSITION CONTAINING AN ANTIWEAR AGENT
  申请人：The Lubrizol Corporation

  公开号：EP3371286A1

  公开（公告）日：2018-09-12
• Lubricant Composition Containing an Antiwear Agent
  申请人：The Lubrizol Corporation

  公开号：US20180327686A1

  公开（公告）日：2018-11-15

  The invention provides a lubricant composition comprising an oil of lubricating viscosity and a (thio)phosphoric acid salt of an N-hydrocarbyl-substituted gamma- (γ-) or delta- (δ-)amino(thio)ester. The invention further relates to a method of lubricating a mechanical device with the lubricant composition.
• [EN] LUBRICANT COMPOSITION CONTAINING AN ANTIWEAR AGENT<br/>[FR] COMPOSITION LUBRIFIANTE CONTENANT UN AGENT ANTI-USURE
  申请人：LUBRIZOL CORP

  公开号：WO2017079575A1

  公开（公告）日：2017-05-11

  The invention provides a lubricant composition comprising an oil of lubricating viscosity and a protic acid salt of an N-hydrocarbyl-substituted gamma- (γ-) or delta- amino(thio)ester. The invention further relates to a method of lubricating a mechanical device with the lubricant composition.
• Oxidative Cleavage of<i>o</i>-Hydroxyphenyl Phosphate by Iodobenzene Diacetate
  作者：Pei-Lin Wu、Jhy-Hong Chen、Ded-Shih Huang

  DOI：10.1002/jccs.199900133

  日期：1999.12

  AbstractThe protecting o‐hydroxyphenyl group in the synthesis of mono‐ or dialkyl phosphates (6 or 8) could be removed by oxidative cleavage of mono‐ or dialkyl o‐hydroxyphenyl phosphates (3 or 7) using iodobenzene diacetate.