2,2-二氯乙烯基甲基磷酸酯钙盐 | 13445-62-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 中文名称: 2,2-二氯乙烯基甲基磷酸酯钙盐
• 英文名称: Desmethyldichlorvos
• 英文别名: dichlorovinylmethyl phosphoric acid；2,2-Dichlorvinylmethylphosphorsaeure；Methyl 2,2-dichlorovinylphosphorsaeure；Methyl-2,2-dichlorvinylphosphat；phosphoric acid 2,2-dichloro-vinyl ester methyl ester；2,2-Dichlorovinyl-methylphosphorsaeure；2,2-Dichlorovinyl methyl phosphate；2,2-dichloroethenyl methyl hydrogen phosphate
• CAS: 13445-62-0
• 化学式: C₃H₅Cl₂O₄P
• 分子量: 206.95
• InChiKey: PFCDFSJUWNKQQI-UHFFFAOYSA-N

物化性质

• 沸点：
  216.6±50.0 °C(Predicted)
• 密度：
  1.609±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  10
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  55.8
• 氢给体数：
  1
• 氢受体数：
  4

安全信息

• 海关编码：
  2919900090

反应信息

• 作为反应物：
  描述：

  2,2-二氯乙烯基甲基磷酸酯钙盐 在 氯化亚砜 作用下， 生成 diphosphoric acid 1,2-bis-(2,2-dichloro-vinyl) ester 1,2-dimethyl ester
  参考文献：
  名称：

  新型磷酸盐驱虫药。1.烷基2，2-二氯乙烯基甲基磷酸酯和敌敌畏的相关烷氧基烷基和环烷基类似物。

  摘要：

  DOI：

  10.1021/jm00282a006
• 作为产物：
  描述：

  敌敌畏 在 sodium iodide 作用下， 以 丁酮 为溶剂， 生成 2,2-二氯乙烯基甲基磷酸酯钙盐
  参考文献：
  名称：

  Schneider,P.; Fischer,G.W., Journal fur praktische Chemie (Leipzig 1954), 1977, vol. 319, p. 391 - 398

  摘要：

  DOI：

文献信息

• Enantiopure Water-Soluble [Fe₄L₆] Cages: Host-Guest Chemistry and Catalytic Activity
  作者：Jeanne L. Bolliger、Ana M. Belenguer、Jonathan R. Nitschke

  DOI：10.1002/anie.201302136

  日期：2013.7.29

  Inside information: The new enantiopure cage molecule ΔΔΔΔ‐Fe4L6 (and its enantiomer, ΛΛΛΛ‐Fe4L6) was prepared by subcomponent self‐assembly. It binds a range of organic guests (A, see scheme) in its cavity and distinguishes between the enantiomers of a chiral organic guest. Host ΔΔΔΔ‐Fe4L6 is also a catalyst for the hydrolysis (giving B and C) of the neurotoxic organophosphate dichlorvos.

  内部信息：新对映体纯笼分子ΔΔΔΔ -铁4大号6（及其对映体，ΛΛΛΛ -铁4大号6）通过副成分制备自组装。它在其腔中结合了一系列有机客体（A，参见方案），并区分了手性有机客体的对映异构体。主机ΔΔΔΔ -铁4大号6也用于水解（给人一种催化剂乙和Ç神经毒性的有机磷敌敌畏）。
• Reduction of Dichlorvos and Omethoate Residues by O₂ Plasma Treatment
  作者：Yanhong Bai、Jierong Chen、Hui Mu、Chunhong Zhang、Baoping Li

  DOI：10.1021/jf900995d

  日期：2009.7.22

  A practical, inexpensive, and green chemical process is greatly needed for degrading pesticides in food and environmental water. In this work, the impact of O-2 plasma treatment on reduction of dichlorvos (DDVP) and omethoate in maize was determined by gas chromatography (GC). The main plasma-induced degradation mechanisms were investigated through identification of intermediates or products during O-2 plasma treatment for DDVP and omethoate on solid surfaces by gas chromatography/mass spectrometry (GC/MS). The results clearly demonstrate that O-2 plasma treatment is significantly effective in the degradation of original DDVP and omethoate, and the degradation efficiency mainly depends upon related operating parameters and chemical structures of pesticides. Moreover, GUMS analyses show that DDVP and omethoate molecules are degraded into less-toxic compounds, and the plasma degradation mechanisms for pesticides can be dominated by a free-radical reaction. It is concluded that O-2 plasma has the potential to reduce pesticide residues in agricultural products.
• Krutikov, V. I.; Naidenov, A. V.; Palagina, T. V., Journal of general chemistry of the USSR, 1988, vol. 58, # 9, p. 1839 - 1841
  作者：Krutikov, V. I.、Naidenov, A. V.、Palagina, T. V.、Lebedev, V. B.、Lavrent'ev, A. N.

  DOI：——

  日期：——
• Scheybal, Achim; Gabrio, Thomas; Kirst, Eberhard, Zeitschrift fur Chemie, 1980, vol. 20, # 6, p. 226 - 227
  作者：Scheybal, Achim、Gabrio, Thomas、Kirst, Eberhard

  DOI：——

  日期：——
• Polychlorinated ketones. III. Formation by acid-catalyzed cleavage of vinyl phosphates and phosphonates
  作者：Kurt Pilgram、Franz Goergen、Helmut Ohse

  DOI：10.1021/jo01263a072

  日期：1969.11