Butyl dioctyl phosphate | 64031-59-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: Butyl dioctyl phosphate
• CAS: 64031-59-0
• 化学式: C₂₀H₄₃O₄P
• 分子量: 378.5
• InChiKey: COPHVUDURPSYBO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.6
• 重原子数：
  25
• 可旋转键数：
  20
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• Silver halide color photographic light-sensitive material
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0117511A2

  公开（公告）日：1984-09-05

  A silver halide color photographic light-sensitive material comprising a support having thereon a silver halide emulsion layer and a compound represented by the following general formula (I): wherein COUP represents a coupler residue capable of being subjected to a coupling reaction with an oxidation product of an aromatic primary amine developing agent; TIME represents a timing group which is released upon the coupling reaction and subsequently releases Z represents a monocyclic or condensed heterocyclic ring consisting of a nitrogen atom and a carbon atom; L represents a divalent linking group; R represents a hydrogen atom or an alkoxycarbonyl group; R2 represents a hydrogen atom, an alkyl group, an aryl group, a heterocyclic group, an acyl group, a sulfonyl group, an alkoxycarbonyl group, a carbamoyl group, a sulfamoyl group, a thioacyl group or a thiocarbamoyl group; R3 represents a hydrogen atom; R2 and R3 may be bonded each other to form a hydrazone structure; a part of L and R1 may be bonded each other to form a hydrazone structure; and n represents 0 or 1. The silver halide color photographic light-sensitive material containing the compound capable of imagewise releasing a fogging agent represented by the general formula (I) is improved in stability during preservation and has a high contrast and sensitivity. A method of forming a color image using the silver halide color photographic light-sensitive material is also disclosed.

  一种卤化银彩色感光照相材料，它包括在其上具有卤化银乳剂层的支持物和由以下通式(I)表示的化合物： 其中 COUP 代表能与芳香族伯胺显影剂的氧化产物发生偶联反应的偶联剂残留物；TIME 代表在偶联反应时释放并随后释放的定时基团；TIME 代表在偶联反应时释放并随后释放的定时基团；TIME 代表在偶联反应时释放并随后释放的定时基团；TIME 代表在偶联反应时释放并随后释放的定时基团。 Z 代表由氮原子和碳原子组成的单环或缩合杂环； L 代表二价连接基团； R 代表氢原子或烷氧基羰基；R2代表氢原子、烷基、芳基、杂环基、酰基、磺酰基、烷氧羰基、氨基甲酰基、氨基磺酰基、硫代酰基或硫代氨基甲酰基；R3代表氢原子；R2和R3可以相互键合形成腙结构；L和R1的一部分可以相互键合形成腙结构；n代表0或1。 含有通式(I)所代表的化合物的卤化银彩色感光材料能够在图像上释放雾化剂，在保存过程中提高了稳定性，并具有高对比度和高灵敏度。此外，还公开了一种使用该卤化银彩色感光材料形成彩色图像的方法。
• Color photographic light-sensitive material
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0127162A2

  公开（公告）日：1984-12-05

  A silver halide color photographic light-sensitive material comprising a support having coated thereon at least one silver halide emulsion layer, the color photographic light-sensitive material having at least one layer containing at least one 2-equivalent magenta coupler of the 5-pyrazolone type represented by the following general formula (I): wherein W represents a phenyl group substituted with at least one substituent selected from the group consisting of a halogen atom, an alkyl group, an alkoxy group, an alkoxycarbonyl group and a cyano group; Y represents an acylamino group or an anilino group; and Z represents a group capable of being released upon coupling, and at least one compound represented by the following general formula (II): wherein R' and RZ, which may be the same or different, each represents a hydrogen atom, an alkyl group or an aryl group, provided that both R' and R' do not represent hydrogen atoms atthe same time; Z' represents a methine group, a substituted methine group orthe group-N=; and Q represents an atomic group which contains a nitrogen atom, a sulfur atom or an oxygen atom and is necessary to form a 5-membered ora 6-membered heterocyclic ring together with the group-C=Z1-. The silver halide color photographic light-sensitive material can provide an excellent magenta color image without the occurrence of stain, even when the color photographic material is processed in a processing solution under the running condition.

  一种卤化银彩色感光材料，包括一个支撑体，该支撑体上涂覆有至少一层卤化银乳剂层，该彩色感光材料至少有一层含有至少一种由以下通式(I)表示的5-吡唑酮型2当量品红耦合剂： 其中 W 代表至少一个被选自卤素原子、烷基、烷氧基、烷氧羰基和氰基的取代基取代的苯基；Y 代表酰氨基或苯胺基；Z 代表在偶联时能被释放的基团，以及至少一种由下式通式（II）代表的化合物： 其中 R' 和 RZ 可以相同或不同，各自代表氢原子、烷基或芳基，但 R' 和 R' 不能同时代表氢原子；Z' 代表甲基、取代的甲基或基团-N=；Q 代表含有氮原子、硫原子或氧原子的原子团，必须与基团-C=Z1-一起形成 5 元或 6 元杂环。 这种卤化银彩色感光材料可以提供极佳的品红色图像，即使在运行状态下用冲洗液冲洗彩色感光材料，也不会出现染色现象。
• Silver halide photographic light-sensitive material
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0147765A2

  公开（公告）日：1985-07-10

  A silver halide photographic light-sensitive material comprising a support and at least one silver halide emulsion layer wherein the silver halide photographic light-sensitive material contains at least one compound represented by the following general formula (I): wherein COUP represents a coupler residue capable of undergoing a coupling reaction with an oxidation product of an aromatic primary amine developing agent; TIME represents a timing group which is released from COUP the coupling reaction and subsequently releases represents a group capable of being released from COUP by the coupling reaction when n is 0, or a group capable of being released from TIME after TIME which has been released from COUP when n is 1, AD being adsorptive to silver halide particles; R represents an alkyl group, an aryl group or a heterocyclic group; R' and R", which may be the same or different, each represents a hydrogen atom or a substitutent; and -NHNHCOR may be directly connected to AD when AD is combined with the benzene ring to form a condensed ring system. The'silver halide photographic light-sensitive material containing the compound represented by general formula (I) is improved in stability during storage and has a high sensitivity.

  一种卤化银感光照相材料，包括一个支撑体和至少一个卤化银乳剂层，其中卤化银感光照相材料含有至少一种由下通式(I)表示的化合物： 其中 COUP 代表能与芳香族伯胺显影剂的氧化产物发生偶联反应的偶联剂残留物； TIME 代表在偶联反应中从 COUP 释放并随后释放的定时基团 R 代表烷基、芳基或杂环基；R'和 R "可以相同或不同，各自代表氢原子或取代基；当 AD 与苯环结合形成缩合环系时，-NHNHCOR 可直接与 AD 连接。 含有通式（I）所代表化合物的'卤化银感光材料'在贮存期间的稳定性得到改善，并具有高灵敏度。
• Silver halide color photo-sensitive material
  申请人：KONICA CORPORATION

  公开号：EP0182617A2

  公开（公告）日：1986-05-28

  A silver halide photo-sensitive material having at least one silver halide emulsion layer on a support the silver halide emulsion layer containing at least one magenta-forming coupler of the 1 H-pyrazolo[3,2-c]-S-triazole type which is substituted by a tertiary alkyl group at the 3-position and, by a releasable group other than a hydrogen atom at the 7-position.

  一种卤化银感光材料，在支架上有至少一层卤化银乳剂层，该卤化银乳剂层含有至少一种 1 H-吡唑并[3,2-c]-S-三唑类型的洋红色形成耦合剂，该耦合剂在 3 位被叔烷基取代，在 7 位被氢原子以外的可释放基团取代。
• Silver halide color photograhic light-sensitive material
  申请人：KONICA CORPORATION

  公开号：EP0304856A2

  公开（公告）日：1989-03-01

  A silver halide photographic light sensitive materail is disclosed, which is contains a novel cyan coupler excellent in spectral absorption, absorption coefficient and fastness. The cyan coupler is represented by the following Formula I; wherein R₁ and R₂ each represent a substituent; R₃ represents a hydrogen atom, an alkyl group, an aryl group, a -COR₄ group, a -COOR₄ group, a group, an -SO₂R₄ or an group in which R₄ represents an alkyl group an aryl group or a heterocyclic group, R₅ represents a hydrogen atom or an alkyl group; X represents a hydrogen atom or a group capable of being split off upon reaction with the oxidized product of a color developing agent; m represent an integer of from 0 to 4; and n represents an integer of from 0 to 5.

  本发明公开了一种卤化银感光材料，它含有一种新型的青色耦合剂，该耦合剂在光谱吸收、吸收系数和牢度方面都非常出色。该青色耦合剂由下式 I 表示； 基团、-SO₂R₄ 或 其中，R₄ 代表烷基、芳基或杂环基，R₅ 代表氢原子或烷基；X 代表氢原子或与显色剂的氧化产物反应后可分离的基团；m 代表 0 至 4 的整数；n 代表 0 至 5 的整数。