phosphoric acid bis-(2-chloro-phenyl ester) | 36400-49-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: phosphoric acid bis-(2-chloro-phenyl ester)
• 英文别名: Phosphorsaeure-bis-(2-chlor-phenylester)；Bis-(2-chlor-phenyl)-hydrogenphosphat；Bis-(2-chlor-phenyl)-phosphat；Bis(2-chlorophenyl) hydrogen phosphate
• CAS: 36400-49-4
• 化学式: C₁₂H₉Cl₂O₄P
• 分子量: 319.081
• InChiKey: IOPCEPCSTBOTEG-UHFFFAOYSA-N

物化性质

• 熔点：
  105-106 °C
• 沸点：
  437.1±55.0 °C(Predicted)
• 密度：
  1.513±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  55.8
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  双(2-氯苯基)磷酰氯 在 水 作用下， 反应 13.0h， 以59%的产率得到phosphoric acid bis-(2-chloro-phenyl ester)
  参考文献：
  名称：

  Hydrogen phosphates: Self initiated organocatalysts for the controlled ring-opening polymerization of cyclic esters

  摘要：

  A series of arylhydrogenphosphates and aryldihydrogenphosphates was synthesized and characterized using spectroscopic methods and single crystal X-ray diffraction. These compounds were assessed as catalysts towards the ring-opening polymerization and proved to be potent organocatalysts for the ring-opening polymerization of cyclic esters. The bulk polymerizations were performed in the absence of external initiator. The polymerization proceeds in a controlled fashion which leads to well defined polyesters with narrow molecular weight distributions. In the post polymerization experiments, kinetics, mechanism and monomer concentration effects were investigated. The kinetic results have confirmed the pseudo-living character of the polymerizations and mechanistic studies suggest that the polymerization operates through a cationic mechanism. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2013.02.006
• 作为试剂：
  描述：

  在 吡啶 、 phosphoric acid bis-(2-chloro-phenyl ester) 作用下， 以 二氯甲烷 为溶剂， 反应 0.08h， 生成
  参考文献：
  名称：

  Reese, Colin B.; Quanlai, Song, Journal of the Chemical Society. Perkin transactions I, 1999, # 11, p. 1477 - 1486

  摘要：

  DOI：

文献信息

• Method for producing meta type polyaniline
  申请人：Honda Giken Kogyo Kabushiki Kaisha

  公开号：EP1090944A2

  公开（公告）日：2001-04-11

  A novel method for producing a meta type polyaniline, comprising polymerizing aniline in at least one organic solvent selected from N-methyl-2-pyrrolidone, N,N-dimethyl sulfoxide, N,N-dimethylacetamide and N,N-dimethylformamide, in the presence of at least one oxidizing agent selected from ammonium peroxodisulfate, iron(III) chloride, manganese dioxide and hydrogen peroxide, at -20°C to 50°C.

  一种生产元型聚苯胺的新方法，包括在至少一种选自 N-甲基-2-吡咯烷酮、N,N-二甲基亚砜、N,N-二甲基乙酰胺和 N,N-二甲基甲酰胺的有机溶剂中，在至少一种选自过氧化二硫酸铵、氯化铁（III）、二氧化锰和过氧化氢的氧化剂存在下，于 -20°C 至 50°C 的温度下聚合苯胺。
• Proton conducting polymer, method for producing the same, solid polymer electrolyte and electrode
  申请人：Honda Giken Kogyo Kabushiki Kaisha

  公开号：EP1085034A1

  公开（公告）日：2001-03-21

  A proton conducting polymer obtained by blending an organic phosphoric acid compound solution with a meta type polyaniline solution; a solid polymer electrolyte for a fuel cell comprising the proton conducting polymer, which is excellent in proton conductivity, methanol barrier property and dopant stability in an aqueous solution of methanol; and an electrode comprising the proton conducting and fine catalyst particles carried on porous particles.

  一种质子传导聚合物，由有机磷酸化合物溶液与元型聚苯胺溶液混合而成；一种燃料电池用固体聚合物电解质，由质子传导聚合物组成，该聚合物在甲醇水溶液中具有优异的质子传导性、甲醇阻隔性和掺杂稳定性；以及一种电极，由质子传导聚合物和多孔颗粒上的细小催化剂颗粒组成。
• Aromatic polymer, method for producing the same and uses thereof
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP1348716A1

  公开（公告）日：2003-10-01

  There is provided a polymer electrolyte which shows excellent characteristics as proton conductive membrane of fuel cells and the like. This polymer electrolyte contains an aromatic polymer which is characterized by having a super strong acid group in a side chain.

  本发明提供了一种聚合物电解质，它作为燃料电池等的质子传导膜具有优异的特性。这种聚合物电解质含有一种芳香族聚合物，其特点是侧链中含有一个超强酸基。
• Flame retardant, additive compositions, and flame retardant polyurethanes
  申请人：Hussain Saadat

  公开号：US20050113495A1

  公开（公告）日：2005-05-26

  Provided are new flame retardants and liquid flame retardant additive compositions of low viscosity for use in flexible polyurethane foams. The new flame retardants are the reaction product of at least one brominated aromatic diester diol with at least one alcohol-reactive agent. Preferred liquid flame retardant additive compositions are capable of minimizing visible scorching of the foam during its production. Flexible flame retardant polyurethane foams and methods for their production are also provided. The flame retardant additive compositions are formed at least from a) at least one reaction product of a brominated aromatic diester diol and an alcohol-reactive agent; b) at least one hindered amine antioxidant; and c) at least one phenolic antioxidant in which the phenolic ring is substituted by an alkanoic acid alkyl ester group in which alkanoic acid moiety has in the range of 2 to about 4 carbon atoms and the alkyl group has in the range of about 6 to about 16 carbon atoms.

  本文提供了用于软质聚氨酯泡沫的新型阻燃剂和低粘度液体阻燃添加剂组合物。新型阻燃剂是至少一种溴化芳香族二酯二醇与至少一种醇反应剂的反应产物。优选的液态阻燃添加剂组合物能够在泡沫生产过程中最大限度地减少可见的焦烧现象。此外，还提供了柔性阻燃聚氨酯泡沫及其生产方法。阻燃添加剂组合物至少由以下物质形成：a) 至少一种溴化芳香族二酯二元醇与醇反应剂的反应产物；b) 至少一种受阻胺抗氧化剂；c) 至少一种酚类抗氧化剂，其中酚环被烷酸烷基酯基团取代，烷酸分子的碳原子数在 2 至约 4 之间，烷基的碳原子数在约 6 至约 16 之间。
• Zetzsche; Nachmann, Helvetica Chimica Acta, 1926, vol. 9, p. 427
  作者：Zetzsche、Nachmann

  DOI：——

  日期：——