[3-[[5-[[3-Bis(3-formylphenoxy)phosphoryloxyphenyl]methylideneamino]naphthalen-1-yl]iminomethyl]phenyl] bis(3-formylphenyl) phosphate | 1426080-56-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: [3-[[5-[[3-Bis(3-formylphenoxy)phosphoryloxyphenyl]methylideneamino]naphthalen-1-yl]iminomethyl]phenyl] bis(3-formylphenyl) phosphate
• 英文别名: [3-[[5-[[3-bis(3-formylphenoxy)phosphoryloxyphenyl]methylideneamino]naphthalen-1-yl]iminomethyl]phenyl] bis(3-formylphenyl) phosphate
• CAS: 1426080-56-9
• 化学式: C₅₂H₃₆N₂O₁₂P₂
• 分子量: 942.812
• InChiKey: XVOJISBMCWEVON-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.7
• 重原子数：
  68
• 可旋转键数：
  20
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  183
• 氢给体数：
  0
• 氢受体数：
  14

反应信息

• 作为反应物：
  描述：

  [3-[[5-[[3-Bis(3-formylphenoxy)phosphoryloxyphenyl]methylideneamino]naphthalen-1-yl]iminomethyl]phenyl] bis(3-formylphenyl) phosphate 、 3-氨基苯酚 以 乙醇 为溶剂， 反应 5.0h， 以65%的产率得到[3-[[5-[[3-Bis[3-[(3-hydroxyphenyl)iminomethyl]phenoxy]phosphoryloxyphenyl]methylideneamino]naphthalen-1-yl]iminomethyl]phenyl] bis[3-[(3-hydroxyphenyl)iminomethyl]phenyl] phosphate
  参考文献：
  名称：

  Synthesis, Characterization, and Thermogravimetric Studies of a Phosphorus-Containing Dendron Built from 1,5-Diaminonaphthalene at the Core

  摘要：

  A facile divergent synthesis of a phosphorus-containing dendron containing 1,5-diaminonaphthalene is described. The phosphorus-containing dendron, functionalized with a 1,5-diaminonaphthalene unit at the core and phenolic OH groups grafted at the periphery, has been accomplished in a versatile, simple fashion, using Schiff's condensation and nucleophilic substitution reactions with POCl3, 3-hydroxy-benzaldehyde, 4-hydroxy-benzaldehyde, and 3-amino-phenol iteratively. The structures of intermediate dendrons were characterized by infrared, NMR (H-1, C-13, and P-31), liquid chromatography-mass spectrometry, and C, H, N analysis. The structure of the final dendron (6) was confirmed by infrared, NMR (H-1, C-13, and P-31), matrix-assisted laser desorption/ionization time-of-flight mass spectrometry, and C, H, N analysis. The thermal stability and degradation of the resulting final dendron was checked by thermal gravitometric analysis/differential thermal analysis.

  DOI：

  10.1080/00397911.2011.628773
• 作为产物：
  描述：

  1,5-萘二胺 在 三乙胺 、 三氯氧磷 作用下， 以 四氢呋喃 、 乙醇 为溶剂， 反应 14.66h， 生成 [3-[[5-[[3-Bis(3-formylphenoxy)phosphoryloxyphenyl]methylideneamino]naphthalen-1-yl]iminomethyl]phenyl] bis(3-formylphenyl) phosphate
  参考文献：
  名称：

  Synthesis, Characterization, and Thermogravimetric Studies of a Phosphorus-Containing Dendron Built from 1,5-Diaminonaphthalene at the Core

  摘要：

  A facile divergent synthesis of a phosphorus-containing dendron containing 1,5-diaminonaphthalene is described. The phosphorus-containing dendron, functionalized with a 1,5-diaminonaphthalene unit at the core and phenolic OH groups grafted at the periphery, has been accomplished in a versatile, simple fashion, using Schiff's condensation and nucleophilic substitution reactions with POCl3, 3-hydroxy-benzaldehyde, 4-hydroxy-benzaldehyde, and 3-amino-phenol iteratively. The structures of intermediate dendrons were characterized by infrared, NMR (H-1, C-13, and P-31), liquid chromatography-mass spectrometry, and C, H, N analysis. The structure of the final dendron (6) was confirmed by infrared, NMR (H-1, C-13, and P-31), matrix-assisted laser desorption/ionization time-of-flight mass spectrometry, and C, H, N analysis. The thermal stability and degradation of the resulting final dendron was checked by thermal gravitometric analysis/differential thermal analysis.

  DOI：

  10.1080/00397911.2011.628773

文献信息

• Synthesis, Characterization, and Thermogravimetric Studies of a Phosphorus-Containing Dendron Built from 1,5-Diaminonaphthalene at the Core
  作者：E. Dadapeer、B. Satheesh Krishna、C. Naga Raju

  DOI：10.1080/00397911.2011.628773

  日期：2013.5.3

  A facile divergent synthesis of a phosphorus-containing dendron containing 1,5-diaminonaphthalene is described. The phosphorus-containing dendron, functionalized with a 1,5-diaminonaphthalene unit at the core and phenolic OH groups grafted at the periphery, has been accomplished in a versatile, simple fashion, using Schiff's condensation and nucleophilic substitution reactions with POCl3, 3-hydroxy-benzaldehyde, 4-hydroxy-benzaldehyde, and 3-amino-phenol iteratively. The structures of intermediate dendrons were characterized by infrared, NMR (H-1, C-13, and P-31), liquid chromatography-mass spectrometry, and C, H, N analysis. The structure of the final dendron (6) was confirmed by infrared, NMR (H-1, C-13, and P-31), matrix-assisted laser desorption/ionization time-of-flight mass spectrometry, and C, H, N analysis. The thermal stability and degradation of the resulting final dendron was checked by thermal gravitometric analysis/differential thermal analysis.