[Cu(ethylene bis(diethyldithiocarbamate))2]n*(ClO4)n | 244036-40-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 二硫代氨基甲酸及其衍生物
• 英文名称: [Cu(ethylene bis(diethyldithiocarbamate))2]n*(ClO4)n
• CAS: 244036-40-6
• 化学式: C₂₄H₄₈CuN₄S₈*ClO₄
• 分子量: 812.197
• InChiKey: WDXFOOGMMKFLQZ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  ethylene bis(diethyldithiocarbamate) 、 copper(II) perchlorate 以 乙醇 为溶剂， 以84.5%的产率得到[Cu(ethylene bis(diethyldithiocarbamate))2]n*(ClO4)n
  参考文献：
  名称：

  Crystal structure and spectroscopic properties of a one-dimensional copper(I) coordination polymer: μ-ethylene bis(diethyldithiocarbamate) copper(I) perchlorate. [Cu(EDTC)2]ClO4[EDTC=ethylene bis(diethyldithiocarbamate)]

  摘要：

  The synthesis and X-ray structure of the one-dimensional polymeric ethylene bis(diethyldithiocarbamate) copper(I) perchlorate complex formulated as [Cu(EDTC)(2)](n) .(ClO4)(n) were reported. The copper ion is tetrahedrally coordinated by four sulfur atoms from four different ligand molecules. Each of the ethylene bis(diethyldithiocarbamate) ligands bridges two copper(I) ions. The shortest Cu-Cu distance is 8.361(3) Angstrom. This bidentate, non-chelating coordination leads to a one-dimensional chain. The structure of the title compound in solution was also studied by electrospray mass spectrometry (ESMS). This study demonstrates that a one-dimensional chain polymer could be retained in solution as the same structure as in solid. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00090-x