Phosphoric acid mono-(2-allyl-phenyl) ester | 141843-96-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: Phosphoric acid mono-(2-allyl-phenyl) ester
• 英文别名: (2-Prop-2-enylphenyl) dihydrogen phosphate
• CAS: 141843-96-1
• 化学式: C₉H₁₁O₄P
• 分子量: 214.158
• InChiKey: UEOGDLLVRRYLMS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  66.8
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  dibenzyl (2-prop-2-enylphenyl) phosphate 在 吡啶 、 三甲基溴硅烷 作用下， 以 二氯甲烷 为溶剂， 以72%的产率得到Phosphoric acid mono-(2-allyl-phenyl) ester
  参考文献：
  名称：

  用溴代三甲基硅烷选择性去除磷酸芳基酯中的苄基保护基团

  摘要：

  摘要 溴代三甲基硅烷 (BTMS) 被证明是一种有效的选择性试剂，可用于二苄基芳基磷酸酯的脱苄基反应生成相应的芳基磷酸，并且不影响分子结构中也存在的其他官能团。

  DOI：

  10.1080/00397919208020856

文献信息

• 3-benzoyl-2,4,5-substituted pyridine derivatives or salts thereof and bactericides containing the same
  申请人：Nishide Hisaya

  公开号：US20060089390A1

  公开（公告）日：2006-04-27

  To provide 3-benzoyl-2,4,5-substituted pyridine derivatives or their salts, fungicides containing them, and intermediates for producing them. By providing a group of compounds comprising specific 3-benzoyl-2,4,5-substituted pyridine derivatives or their salts, or fungicides containing them, which have so-called rainfastness, whereby they are capable of exhibiting excellent effects even when crops have received rainfall after application of the chemicals, it becomes unnecessary to increase the number of applications or the dose of the chemicals by taking into consideration the rainfall after the application of the chemicals. Thus, it is possible to protect crops from disease injuries at a lower cost with less labor.

  提供3-苯甲酰基-2,4,5-取代吡啶衍生物或其盐，含有它们的杀菌剂以及用于生产它们的中间体。通过提供一组化合物，其中包括特定的3-苯甲酰基-2,4,5-取代吡啶衍生物或其盐，或含有它们的杀菌剂，这些化合物具有所谓的雨水稳定性，即使作物在化学品施用后遭受降雨，它们仍能展现出优异的效果，因此不必考虑化学品施用后的降雨增加化学品的施用次数或剂量。因此，可以以更低的成本和更少的劳动力保护作物免受病害的伤害。
• Ink jet ink, method for producing ink jet ink, ink jet recording method and ink cartridge
  申请人：Osumi Koichi

  公开号：US20060139429A1

  公开（公告）日：2006-06-29

  An ink jet ink includes at least a coloring material. The coloring material is composed of at least one selected from the group consisting of C.I. Direct Yellow 86, C.I. Acid Yellow 23, C.I. Direct Yellow 173, C.I. Direct Yellow 132 and C.I. Direct Yellow 59, and a compound represented by the following the general formula (I) or a salt thereof.

  一种喷墨墨水至少包括一种着色物质。该着色物质由以下至少一种选自C.I.直接黄86、C.I.酸性黄23、C.I.直接黄173、C.I.直接黄132和C.I.直接黄59的群组合中的一种，以及以下通式（I）所表示的化合物或其盐组成。
• Fungicidal Composition Containing Acid Amide Derivative
  申请人：Nakamura Yuji

  公开号：US20080318779A1

  公开（公告）日：2008-12-25

  Conventional many fungicidal compositions have had practical problems such that either a preventive effect or a curing effect is inadequate, the residual effect tends to be inadequate, or the controlling effect against plant diseases tends to be inadequate depending upon the application site, and a fungicidal composition to overcome such problems has been desired. The present invention provides a fungicidal composition containing an acid amide derivative of the formula (I) or a salt thereof, as an active ingredient: wherein A is phenyl which may be substituted, benzyl which may be substituted, naphthyl which may be substituted, heterocyclic ring which may be substituted, fused heterocyclic ring which may be substituted, or the like; B is heterocyclic ring which may be substituted, fused heterocyclic ring which may be substituted, or naphthyl which may be substituted; each of R 1 and R 2 which are independent of each other, is alkyl, or the like; R 3 is hydrogen, or the like; each of W 1 and W 2 which are independent of each other, is oxygen or sulfur.

  传统的许多杀菌组合物存在实际问题，例如预防效果或治疗效果不足，残留效果倾向于不足，或者根据应用场所，对植物疾病的控制效果倾向于不足，因此需要一种克服这些问题的杀菌组合物。本发明提供了一种含有式(I)的酸酰胺衍生物或其盐作为活性成分的杀菌组合物：其中，A是苯基，可以是取代的苯基，苄基，可以是取代的苄基，萘基，可以是取代的萘基，杂环环，可以是取代的杂环环，融合的杂环环，可以是取代的融合的杂环环或类似物；B是杂环环，可以是取代的融合的杂环环或取代的萘基；R1和R2各自独立地是烷基或类似物；R3是氢或类似物；W1和W2各自独立地是氧或硫。
• Biphenyl derivative or its salt, and pesticide containing it as an active ingredient
  申请人：Mitani Shigeru

  公开号：US20070135497A1

  公开（公告）日：2007-06-14

  A pesticide having stabilized high pesticidal effects for crop plants infected with plant diseases, is presented. The pesticide contains a biphenyl derivative represented by the formula (I) or its salt, as an active ingredient: wherein X, Y and Z are each independently a halogen atom, a hydroxyl group, a formyl group, an alkyl group which may be substituted, an alkoxy group which may be substituted, an alkylthio group, an alkylsulfonyl group, an alkylsulfinyl group, or the like, A is a carbonyl group, a thiocarbonyl group, an alkylene group, or a single bond, R 1 and R 2 are each independently a hydrogen atom, an alkyl group which may be substituted, an alkenyl group which may be substituted, an alkynyl group which may be substituted, an aryl group which may be substituted, a formyl group, an alkylcarbonyl group, a cyano group, or the like, and m and n are each independently 0, 1, 2, 3 or 4.

  提供了一种稳定高杀虫效果的杀虫剂，用于感染植物病害的作物。该杀虫剂包含一种双苯衍生物，其由式（I）或其盐表示，作为活性成分：其中X、Y和Z各自独立地是卤素原子、羟基、甲酰基、可被取代的烷基、可被取代的烷氧基、烷基硫基、烷基磺酰基、烷基亚磺酰基或类似的基团，A是羰基、硫代羰基、烷基烯基或单键，R1和R2各自独立地是氢原子、可被取代的烷基、可被取代的烯基、可被取代的炔基、可被取代的芳基、甲酰基、烷基羰基、氰基或类似的基团，m和n各自独立地为0、1、2、3或4。
• FUNGICIDAL COMPOSITION CONTAINING CARBOXYLIC ACID AMIDE DERIVATIVE
  申请人：Nakamura Yuji

  公开号：US20100222337A1

  公开（公告）日：2010-09-02

  Conventional fungicidal compositions have had practical problems such that either a preventive effect or a curative effect is inadequate, the residual effect tends to be inadequate, or the controlling effect against plant diseases tends to be inadequate depending upon the application site, and a fungicidal composition to overcome such problems has been desired. The present invention provides a fungicidal composition containing a carboxylic acid amide derivative of the formula (I) or a salt thereof, as an active ingredient: wherein A is phenyl which may be substituted, benzodioxolanyl which may be substituted, or benzodioxanyl which may be substituted; B is 2- or 3-pyridyl which may be substituted; each of R 1 and R 2 is alkyl, or R 1 and R 2 may together form a 3- to 6-membered saturated carbon ring, provided that when B is 3-pyridyl which may be substituted, A is phenyl substituted by at least two substituents.

  传统的杀菌剂组合物存在实际问题，例如预防效果或治疗效果不足，残留效果往往不足，或者根据应用场所，对植物疾病的控制效果往往不足，因此需要一种克服这些问题的杀菌剂组合物。本发明提供了一种含有式(I)的羧酸酰胺衍生物或其盐作为活性成分的杀菌剂组合物：其中A是苯基，可以是取代的苯基，苯并二氧杂环基，可以是取代的苯并二氧杂环基，或苯并二氧杂环基，可以是取代的苯并二氧杂环基；B是2-或3-吡啶基，可以是取代的；R1和R2中的每一个都是烷基，或者R1和R2可以共同形成3-至6-成员的饱和碳环，但是当B是可以被取代的3-吡啶基时，A是至少被两个取代基取代的苯基。