[(Cu3(N-(diisopropoxythiophosphinyl)-N'-phenylthiourea(-1H))3)2] | 1122400-76-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氮杂螺癸烷衍生物
• 英文名称: [(Cu3(N-(diisopropoxythiophosphinyl)-N'-phenylthiourea(-1H))3)2]
• CAS: 1122400-76-3
• 化学式: C₇₈H₁₂₀Cu₆N₁₂O₁₂P₆S₁₂
• 分子量: 2369.79
• InChiKey: QMNPYRGTOLSWRC-UHFFFAOYSA-H

反应信息

• 作为产物：
  描述：

  copper(l) iodide 、 N-(diisopropoxythiophosphinyl)-N'-phenylthiourea 在 KOH 作用下， 以 乙醇 、 水 为溶剂， 以66%的产率得到[(Cu3(N-(diisopropoxythiophosphinyl)-N'-phenylthiourea(-1H))3)2]
  参考文献：
  名称：

  Novel bicyclic hexanuclear copper(I) aggregate: Structure and solid state 31P CPMAS NMR spectra of [(Cu3L3)2] and [Cu(PPh3)2L] complexes of N-(diisopropoxythiophosphinyl)-N′-phenylthiourea (HL)

  摘要：

  A new complex of N-thiophosphorylthiourea PhNHC(S)NHP(S)(OiPr)(2) (HL) of formula [(Cu3L3)(2)] has been synthesized and characterized by single crystal X-ray diffraction, FT-IR, H-1, P-31 NMR in solution and by P-31 CPMAS NMR spectroscopy in the solid state. A comparison of the structure and the spectral parameters of [(Cu3L3)(2)] with those of the mononuclear analogue [Cu(PPh3)(2)L] was performed. In the solid state the aggregate [(Cu3L3)(2)] represents the first example of a spontaneous "side-by-side" association of two neutral cyclic [Cu3L3] moieties using two Cu-S-Cu bridges formed by the sulfur atoms of the PS-groups. The values of the (1)J(P-31-Cu-63,Cu-65) and (2)J(P-31-P-31) coupling constants of the [Cu(PPh3)(2)](+) moiety in the solid state spectra are reported. (C) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.10.010