2-undecyl-7,7,9,9-tetramethyl-1-oxa-3,8-diaza-4-oxo-spiro[4.5]decane | 64337-97-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氮杂螺癸烷衍生物
• 英文名称: 2-undecyl-7,7,9,9-tetramethyl-1-oxa-3,8-diaza-4-oxo-spiro[4.5]decane
• 英文别名: 7,7,9,9-tetramethyl-2-undecyl-1-oxa-3,8-diaza-spiro[4.5]decan-4-one；7,7,9,9-Tetramethyl-2-undecyl-1-oxa-3,8-diazaspiro[4.5]decan-4-one
• CAS: 64337-97-9
• 化学式: C₂₂H₄₂N₂O₂
• 分子量: 366.588
• InChiKey: IPRLZACALWPEGS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  26
• 可旋转键数：
  10
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.95
• 拓扑面积：
  50.4
• 氢给体数：
  2
• 氢受体数：
  3

文献信息

• [EN] USE OF 4-CYANO-NAPHTHALENE-1, 8-DICARBOXIMIDE DERIVATIVES AND RELATED COMPOUNDS TO PROTECT ORGANIC MATERIAL FROM THE DAMAGING EFFECTS OF LIGHT<br/>[FR] UTILISATION DE DERIVES 4-CYANO-NAPHTHALENE-1, 8-DICARBOXIMIDE ET COMPOSES ASSOCIES POUR LA PROTECTION DE MATIERE ORGANIQUE CONTRE LES EFFETS NUISIBLES DE LA LUMIERE
  申请人：BASF AG

  公开号：WO2005047265A1

  公开（公告）日：2005-05-26

  A description is given of the use of naphthalene-1,8-dicarboxylic monoimides of the formula (I), in which R1 is hydrogen, alkyl, alkenyl, cycloalkyl, cycloalkenyl, heterocycloalkyl, aryl or heteroaryl and R2 is a radical containing at least one π electron system containing a carbon atom and at least one further atom selected from carbon, oxygen, and nitrogen, with the proviso that the radical contains at least one atom other than carbon; to protect organic material from the damaging effects of light, of compositions which comprise at least one naphthalene-1,8-dicarboxylic monoimide of the formula (I) in an amount which provides protection from the damaging effects of light, and at least one organic material, and of new naphthalene-1,8-dicarboxylic monoimides (I).

  描述了使用式(I)的萘-1,8-二羧酸单亚胺，其中R1是氢、烷基、烯基、环烷基、环烯基、杂环烷基、芳基或杂芳基，R2是一个含有至少一个π电子体系的基团，其中包含一个碳原子和至少一个来自碳、氧和氮的其他原子，但基团至少包含一个碳以外的原子；用于保护有机材料免受光的破坏作用的组合物的描述，该组合物包括至少一种式(I)的萘-1,8-二羧酸单亚胺，其含量提供了对光的破坏作用的保护，以及至少一种有机材料，以及新的萘-1,8-二羧酸单亚胺(I)。
• Novel red-shifted triazine ultravioletlight absorbers
  申请人：——

  公开号：US20030088098A1

  公开（公告）日：2003-05-08

  The present invention relates to novel red-shifted UV absorbers comprising 1,3,5-triazine structures containing a 2-naphthol-derived substituent. The present invention also relates to a method for stabilizing a material by incorporating into such material, e.g., organic material, the novel red-shifted triazine compounds in an amount effective to stabilize the material against the effects of actinic radiation.

  本发明涉及包含1,3,5-三嗪结构并含有2-萘酚衍生取代基的新型红移紫外吸收剂。本发明还涉及一种通过将这种新型红移三嗪化合物以有效量加入到材料中，例如有机材料，来稳定材料以抵抗光化学辐射的影响的方法。
• Phenyl ether-substituted hydroxyphenyl triazine ultraviolet light absorbers
  申请人：——

  公开号：US20030146412A1

  公开（公告）日：2003-08-07

  This invention relates generally to phenyl ether substituted triazines compounds and compositions containing same and their use to protect against degradation by environmental forces. A method for stabilizing a material by incorporating such triazines is also disclosed.

  这项发明通常涉及苯醚取代的三嗪化合物和含有这些化合物的组合物，以及它们用于抵抗环境力量降解的用途。还公开了一种通过将这些三嗪化合物纳入来稳定材料的方法。
• Oligomeric hindered amine light stabilizers based on multi-functional carbonyl compounds and methods of making same
  申请人：——

  公开号：US20020087000A1

  公开（公告）日：2002-07-04

  Oligomeric compounds and methods of making the compound having the formula: T&Parenopenst;E-F&Parenclosest; i &Parenopenst;E-F′&Parenclosest; j &Parenopenst;E′-F&Parenclosest; k &Parenopenst;E′-F′&Parenclosest; l S  (II) wherein i, j, k, and l are integers from about 0 to 300 and the sum of i, j, k, and l is greater than 2, wherein the units F, F′ and T are derived from one or more multi-functional carbonyl compounds of general structure DO—CO—CR a R b —(—CR c R d —) n —NH—(Y) m —CO—OD  (IV) wherein n is an integer from 1 to 15, m is either 0 or 1; R a , R b , R c , and R d , are each a hydrogen or a hydrocarbyl group; Y is CO—(CR e R f ) p , wherein R e and R f are each a hydrogen or hydrocarbyl group and p is zero or an integer from 1 to 20 or CO—C 6 H 4 —, wherein the substitution pattern on the phenylene group is an ortho, meta, or para substitution pattern, and one or more of the hydrogens of the phenylene group may be substituted by a hydrocarbyl group or a functional group; and D is a hydrocarbyl group and the units E, E′ and S are derived from one or more 1-substituted piperidin-4-ol or 4-aminopiperidines of general structure 1 wherein Z is OH or NHG, wherein G is H or C 1 -C 12 alkyl, R 1 is —(CH 2 ) s —OH, —(CH 2 ) s —NH 2 , C 1 -C 18 hydroxyalkoxy or C 5 -C 12 hydroxycycloalkoxy; wherein s is an integer from 1 to 10; R 2 represents hydrogen, C 1 -C 8 alkyl, or benzyl; R 3 , R 4 , R 5 , and R 6 are each a hydrogen, C 1 -C 8 alkyl, benzyl or phenethyl, or two geminal R moieties, which together with the carbon to which they are attached form a C 5 -C 10 cycloalkyl. The compounds are useful for stabilizing polymer compositions against photo- and thermal degradation.

  含有以下公式的化合物的寡聚体化合物及其制备方法：T&Parenopenst;E-F&Parenclosest;i&Parenopenst;E-F′&Parenclosest;j&Parenopenst;E′-F&Parenclosest;k&Parenopenst;E′-F′&Parenclosest;lS  (II)，其中i、j、k和l为约0至300的整数，且i、j、k和l的总和大于2，其中单位F、F′和T来源于一个或多个具有一般结构DO—CO—CRaRb—(—CRcRd—)n—NH—(Y)m—CO—OD  (IV)的多功能羰基化合物，其中n为1至15的整数，m为0或1；Ra、Rb、Rc和Rd分别为氢或烃基团；Y为CO—(CReRf)p，其中Re和Rf分别为氢或烃基团，p为0或1至20的整数，或CO—C6H4—，苯环基上的取代模式为邻位、间位或对位取代模式，苯环基的一个或多个氢原子可被烃基团或功能基团取代；D为烃基团，单位E、E′和S来源于一个或多个具有一般结构1的1-取代哌啶-4-醇或4-氨基哌啶，其中Z为OH或NHG，G为H或C1-C12烷基，R1为—(CH2)s—OH、—( )s—NH2、C1-C18羟基烷氧基或C5-C12羟基环烷氧基，其中s为1至10的整数；R2代表氢、C1-C8烷基或苄基；R3、R4、R5和R6分别为氢、C1-C8烷基、苄基或苯乙基，或两个伪生R基团，它们与它们附着的碳形成C5-C10环烷基。这些化合物可用于稳定聚合物组合物对光和热降解的作用。
• Hindered amine light stabilizers based on multi-functional carbonyl compounds and methods of making same
  申请人：——

  公开号：US20020099218A1

  公开（公告）日：2002-07-25

  Compounds and methods of preparing compounds of the formula: RZ—CO—CR a R b —(CR c R d ) n —NH—(Y) m —CO—A  (I) wherein n is an integer from 1 to 15, m is either 0 or 1; R a , R b , R c , and R d are each a hydrogen or a hydrocarbyl group; Y is CO—(CR e R f ) p , wherein R e and R f are each a hydrogen or hydrocarbyl group and p is zero or an integer from 1 to 20 or CO—C 6 H 4 —, wherein the substitution pattern on the phenylene group is an ortho, meta, or para substitution pattern and one or more of the hydrogens of the phenylene group may be substituted by a hydrocarbyl group or a functional group; Z is —O— or —NG—, wherein G is H, C 1 -C 12 alkyl or the radical R; wherein R is 1 wherein R 1 is hydrogen, C 1 -C 18 alkyl, O, OH, CH 2 CN, C 1 -C 18 alkoxy, C-C 18 hydroxyalkoxy, C 5 -C 12 cycloalkoxy, C 5 -C 12 hydroxycycloalkoxy, C 3 -C 6 alkenyl, C 1 -C 18 alkynyl, C 7 -C 9 phenylalkyl, unsubstituted or substituted on the phenyl with 1, 2 or 3 C 1 -C 4 alkyls, or an aliphatic C 1 -C 8 acyl; R 2 is hydrogen, C 1 -C 8 alkyl, or benzyl; R 3 , R 4 , R 5 , and R 6 are each a hydrogen, C 1 -C 8 alkyl, benzyl or phenethyl, or two geminal R moieties, which together with the carbon to which they are attached form a C 5 -C 10 cycloalkyl; and A is either ZR or a hydrocarbyl group, which are useful for stabilizing polymer compositions against photo- and thermal degradation.

  该公式的化合物及其制备方法：RZ—CO—CRaRb—(CRcRd)n—NH—(Y)m—CO—A（I）其中n是1到15之间的整数，m为0或1；Ra、Rb、Rc和Rd分别是氢或烃基团；Y是CO—(CReRf)p，其中Re和Rf分别是氢或烃基团，p为0或1到20之间的整数，或CO—C6H4—，其中苯环上的取代模式为邻位、间位或对位取代模式，苯环的一个或多个氢原子可能被烃基团或功能基团取代；Z是—O—或—NG—，其中G是H、C1-C12烷基或基团R；其中R是1其中R1是氢、C1-C18烷基、O、OH、CH2CN、C1-C18甲氧基、C-C18羟基甲氧基、C5-C12环氧基、C5-C12羟基环氧基、C3-C6烯基、C1-C18炔基、C7-C9苯基烷基，苯基上未取代或取代1、2或3个C1-C4烷基，或脂肪族C1-C8酰基；R2是氢、C1-C8烷基或苄基；R3、R4、R5和R6分别是氢、C1-C8烷基、苄基或苯乙基，或两个共轭的R基，与它们附着的碳形成C5-C10环烷基；A是ZR或烃基团，可用于稳定聚合物组合物对光和热降解的影响。