5-azoniaspiro[4.5]decane | 177-38-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氮杂螺癸烷衍生物
• 英文名称: 5-azoniaspiro[4.5]decane
• 英文别名: 5-Azoniaspiro<4.5>decanion；Spiro(piperidin-1,1'-pyrrolidinium)；Spiro-pyrrolidon-1,1'-piperidinium
• CAS: 177-38-8
• 化学式: C₉H₁₈N
• 分子量: 140.249
• InChiKey: XEYHFNNNWRPOHF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  manganese(II) bromide 、 5-azoniaspiro[4.5]decane 以 水 为溶剂， 反应 168.0h， 生成
  参考文献：
  名称：

  螺环衍生物中的氯取代引发非中心对称晶体中的 SHG 响应

  摘要：

  通过对有机结构进行特殊的卤素改性，新型有机-无机杂化化合物的相变温度提高了23 K。结合SHG信号和优异的发光特性，成功获得了多功能材料，对进一步探索卤素具有重要意义替代设计和合成多功能材料。

  DOI：

  10.1002/asia.202200791
• 作为产物：
  描述：

  哌啶 、 1,4-二溴丁烷 在 potassium carbonate 作用下， 以 乙腈 为溶剂， 反应 10.0h， 生成 5-azoniaspiro[4.5]decane
  参考文献：
  名称：

  螺环衍生物中的氯取代引发非中心对称晶体中的 SHG 响应

  摘要：

  通过对有机结构进行特殊的卤素改性，新型有机-无机杂化化合物的相变温度提高了23 K。结合SHG信号和优异的发光特性，成功获得了多功能材料，对进一步探索卤素具有重要意义替代设计和合成多功能材料。

  DOI：

  10.1002/asia.202200791

文献信息

• Method for synthesizing spiro quartenary ammonium systems
  申请人：Siggel Alfred

  公开号：US20070049750A1

  公开（公告）日：2007-03-01

  A method for preparing a spiro quaternary ammonium system and electrolytes containing spiro quaternary ammonium cations, comprising a synthesizing step wherein a spiro ammonium system is formed in a medium that can serve as both the reaction solvent and as an electrolyte solvent.

  一种制备螺环季铵体系和含有螺环季铵阳离子的电解质的方法，包括合成步骤，其中在既可作为反应溶剂又可作为电解质溶剂的介质中形成螺环铵体系。
• Novel perfluoroalkanesulfonamide compounds
  申请人：Umemoto Teruo

  公开号：US20070093678A1

  公开（公告）日：2007-04-26

  The present invention provides compounds represented by the formula Y +− N(SO 2 R f )(CF 3 ). Such a compound can be manufactured through a reaction between M +− N(SO 2 R f )(CF 3 ) and Y +− B. The present invention also provides compounds represented by the formula Y +− N(SO 2 R f )(CN). Such a compound can be manufactured through a reaction between M +− N(SO 2 R f )(CN) and Y +− B. R f in the above formulae is a perfluoroalkyl group. Y + is an organic or inorganic cation. − B is an organic or inorganic anion. M + is an alkali metal cation or a silver cation.

  本发明提供了以下公式表示的化合物Y+−N(SO2Rf)(CF3)。这样的化合物可以通过M+−N(SO2Rf)( )和Y+−B之间的反应制造。本发明还提供了以下公式表示的化合物Y+−N(SO2Rf)(CN)。这样的化合物可以通过M+−N(SO2Rf)(CN)和Y+−B之间的反应制造。上述公式中的Rf是全氟烷基。Y+是有机或无机阳离子。−B是有机或无机阴离子。M+是碱金属阳离子或银阳离子。
• RADICAL POLYMERIZATION INITIATOR, COMPOSITION CONTAINING SAME, CURED PRODUCT OF COMPOSITION, PRODUCTION METHOD FOR CURED PRODUCT, AND COMPOUND
  申请人：ADEKA CORPORATION

  公开号：US20210107887A1

  公开（公告）日：2021-04-15

  Provided are: a radical polymerization initiator which has excellent sensitivity and solubility in water; a composition containing the same; a cured product of the composition; a method of producing the cured product; and a compound. The radical polymerization initiator contains a compound represented by Formula (A) below (wherein Z 1 represents a direct bond or the like; Z 2 represents >CR 102 2 or the like; R 1 to R 8 each represent a hydrogen atom or the like, or a group containing a salt-forming group, which is represented by Formula (B1) below (wherein L 1 represents a direct bond or the like, B represents an acidic group salt or the like, b represents 1 to 10, and the asterisk (*) represents a binding site); at least one of R 1 to R 8 is the group containing a salt-forming group; R 101 and the like each represent a hydrogen atom or the like; one or more hydrogen atoms in the alkyl group and the like used as R 1 to R 8 and the like are optionally substituted with an ethylenically unsaturated group or the like; one or more methylene groups in R 1 to R 8 and the like are optionally substituted with a double bond or the like; adjacent groups such as R 1 and R 2 are optionally bound together to form a ring and optionally form a fused ring with a benzene ring in Formula (A); and R′ represents a hydrogen atom or the like).

  提供了：具有优异灵敏度和水溶性的自由基聚合引发剂；含有该引发剂的组合物；该组合物的固化产物；生产该固化产物的方法；以及一种化合物。自由基聚合引发剂包含以下式（A）所代表的化合物（其中Z1代表直接键或类似物；Z2代表>CR1022或类似物；R1至R8各自代表氢原子或类似物，或者包含盐形成基团的群，该基团由下式（B1）代表（其中L1代表直接键或类似物，B代表酸性基团盐或类似物，b代表1至10，星号（*）代表结合位）；R1至R8中至少有一个是包含盐形成基团的群；R101等各自代表氢原子或类似物；R1至R8等中所用的烷基群等中的一个或多个氢原子可以选择性地被乙烯不饱和基团等替代；R1至R8等中的一个或多个亚甲基群可以选择性地被双键等替代；相邻的群，如R1和R2，可以选择性地结合在一起形成环，并且可以选择性地与式（A）中的苯环形成融合环；R′代表氢原子或类似物）。
• ELECTROLYTE SOLUTION AND ELECTROCHEMICAL DEVICE
  申请人：DAIKIN INDUSTRIES, LTD.

  公开号：US20170309412A1

  公开（公告）日：2017-10-26

  The present invention aims to provide an electrolyte solution containing a quaternary ammonium salt as an electrolyte salt and is capable of providing an electrochemical device having a high capacitance retention and reducing generation of gas. The electrolyte solution of the present invention contains a solvent, a quaternary ammonium salt, and a nitrogen-containing unsaturated cyclic compound. The unsaturated cyclic compound is a nitrogen-containing unsaturated heterocyclic compound. The unsaturated cyclic compound excludes salts of the unsaturated cyclic compound and ionic liquids obtainable from the unsaturated cyclic compound.

  本发明旨在提供一种电解质溶液，其中包含季铵盐作为电解质盐，并能够提供具有高电容保持率并减少气体生成的电化学器件。本发明的电解质溶液包含溶剂、季铵盐和含氮不饱和环状化合物。不饱和环状化合物是一种含氮不饱和杂环化合物。该不饱和环状化合物不包括该化合物的盐和可从该不饱和环状化合物获得的离子液体。
• [EN] SUSTAINABLE SYNTHESIS OF CARBAMATE COMPOUNDS<br/>[FR] SYNTHÈSE DURABLE DE COMPOSÉS DE CARBAMATE
  申请人：COVESTRO DEUTSCHLAND AG

  公开号：WO2017137343A1

  公开（公告）日：2017-08-17

  A method for the production of carbamate compounds comprises the steps of: A) reacting an organic primary amine with an organic halogen compound in the presence of a quaternary organic ammonium carbonate and/or bicarbonate, thereby obtaining a reaction mixture comprising a carbamate compound and a quaternary organic ammonium salt; B) separating the quaternary organic ammonium salt from the reaction mixture obtained after step A); C) contacting the quaternary organic ammonium salt obtained after step B) with a carbonate and/or bicarbonate anion-exchange resin, thereby obtaining a quaternary organic ammonium carbonate and/or bicarbonate; D) repeating step A) at least once, wherein the quaternary organic ammonium carbonate and/or bicarbonate employed in this next step A) is at least partially sourced from the quaternary organic ammonium carbonate and/or bicarbonate obtained from the preceding step C).

  生产碳酸酯化合物的方法包括以下步骤：A）在四元有机铵碳酸盐和/或碳酸氢盐的存在下，将有机初级胺与有机卤素化合物反应，从而获得包含碳酸酯化合物和四元有机铵盐的反应混合物；B）从步骤A）后获得的反应混合物中分离四元有机铵盐；C）将步骤B）后获得的四元有机铵盐与碳酸盐和/或碳酸氢盐离子交换树脂接触，从而获得四元有机铵碳酸盐和/或碳酸氢盐；D）至少重复一次步骤A），其中在下一个步骤A）中使用的四元有机铵碳酸盐和/或碳酸氢盐至少部分来自前一步骤C）中获得的四元有机铵碳酸盐和/或碳酸氢盐。