tri(cyclohex-3-enylmethyl) phosphate | 851475-30-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: tri(cyclohex-3-enylmethyl) phosphate
• 英文别名: Tris(cyclohex-3-en-1-ylmethyl) phosphate
• CAS: 851475-30-4
• 化学式: C₂₁H₃₃O₄P
• 分子量: 380.464
• InChiKey: FYVQQYBGZNHQAU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  26
• 可旋转键数：
  9
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  tri(cyclohex-3-enylmethyl) phosphate 在 oxone 、 18-冠醚-6 、 乙二胺四乙酸 作用下， 以 二氯甲烷 、 水 、 丙酮 为溶剂， 反应 24.0h， 以78%的产率得到tri((3,4-epoxycyclohexyl)methyl) phosphate
  参考文献：
  名称：

  Phosphorus-containing liquid cycloaliphatic epoxy resins for reworkable environment-friendly electronic packaging materials

  摘要：

  Novel thermally reworkable, phosphorus-containing, di- and tri-functional liquid cycloaliphatic epoxy resins were designed and synthesized. Their chemical structures were characterized by means of MS, FTIR,(1)H NMR and (31)P NMR methods. After curing, the products were transparent and stable up to 220 degrees C, while exhibited quick thermal decomposition at the temperature range of 255-280 degrees C. The removal test showed that, after heat-treatment at 260 degrees C in air atmosphere for only 4 min, the residual char on the glass substrate could be easily wiped off. This unique degradation behavior was attributed to the synergistic effect of two factors: the thermally-labile phosphate groups evenly distributed within the three-dimensional network and the in-situ catalyzing of phosphoric acid generated from the cleavage of phosphate bond on the pyrolysis of adjacent other phosphate and ester groups, as evidenced by the results of molecular modeling, isothermal TGA and FTIR spectra. In addition, compared to the commercial cycloaliphatic epoxy resin ERL-4221, the newly synthesized epoxy resins had increased limiting oxygen index (LOI) by 31%. The combination of excellent reworkability, non-halogen flame retardancy, high glass transition temperature of 227 degrees C and high mechanical modulus endows them the potential for environment-friendly microelectronic and optoelectronic packaging applications. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.polymer.2010.08.039
• 作为产物：
  描述：

  3-环己烯-1-甲醇 、 三氯氧磷 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 36.0h， 以89%的产率得到tri(cyclohex-3-enylmethyl) phosphate
  参考文献：
  名称：

  Phosphorus-containing liquid cycloaliphatic epoxy resins for reworkable environment-friendly electronic packaging materials

  摘要：

  Novel thermally reworkable, phosphorus-containing, di- and tri-functional liquid cycloaliphatic epoxy resins were designed and synthesized. Their chemical structures were characterized by means of MS, FTIR,(1)H NMR and (31)P NMR methods. After curing, the products were transparent and stable up to 220 degrees C, while exhibited quick thermal decomposition at the temperature range of 255-280 degrees C. The removal test showed that, after heat-treatment at 260 degrees C in air atmosphere for only 4 min, the residual char on the glass substrate could be easily wiped off. This unique degradation behavior was attributed to the synergistic effect of two factors: the thermally-labile phosphate groups evenly distributed within the three-dimensional network and the in-situ catalyzing of phosphoric acid generated from the cleavage of phosphate bond on the pyrolysis of adjacent other phosphate and ester groups, as evidenced by the results of molecular modeling, isothermal TGA and FTIR spectra. In addition, compared to the commercial cycloaliphatic epoxy resin ERL-4221, the newly synthesized epoxy resins had increased limiting oxygen index (LOI) by 31%. The combination of excellent reworkability, non-halogen flame retardancy, high glass transition temperature of 227 degrees C and high mechanical modulus endows them the potential for environment-friendly microelectronic and optoelectronic packaging applications. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.polymer.2010.08.039

文献信息

• PROCESS FOR THE EPOXIDATION OF OLEFINS
  申请人：Chang Chun Plastics Co., Ltd.

  公开号：US20160083360A1

  公开（公告）日：2016-03-24

  The subject invention is related to a process for the epoxidation of olefin with peroxide, comprising reacting peroxide with olefin in the presence a solvent, wherein the solvent has Hansen Solubility Parameters (HSPs) of δ T,solvent and δ H,solvent and the epoxide product has Hansen Solubility Parameters (HSPs) of δ T,product and δ H,product , and wherein: δ T,product −6≦δ T,solvent ≦δ T,product +6, and δ H,product −6≦δ H,solvent .

  该发明涉及一种过氧化物与烯烃进行环氧化反应的方法，包括在溶剂存在的情况下，将过氧化物与烯烃反应，其中溶剂具有Hansen溶解度参数（HSPs）δT，溶剂和δH，溶剂，环氧产物具有Hansen溶解度参数（HSPs）δT，产物和δH，产物，并且满足以下条件：δT，产物-6≦δT，溶剂≦δT，产物+6，以及δH，产物-6≦δH，溶剂。
• CONTINUOUS PROCESS OF OLEFINIC EPOXIDATION BY SUPPORTED HETEROPOLY ACID
  申请人：Chang Chun Plastics Co., Ltd.

  公开号：US20160177023A1

  公开（公告）日：2016-06-23

  The subject invention is related to a continuous process of epoxidation of an olefin with supported heteropoly acid catalyst, which does not involve the use of an additive(s). The subject invention separates the products and oxides through a continuous process to reduce backmixing, thereby achieving an efficacy equal to that of a process involving the use of an additive. By excluding additives from the process, the subject invention has a lower cost, and avoids the need for additional wastewater treatment since no alkali metal or alkali earth metal compound is formed during the reaction. Moreover, the continuous process of the invention is also beneficial in industrial manufacturing.
• US9499505B2
  申请人：——

  公开号：US9499505B2

  公开（公告）日：2016-11-22