dimethyl N-trichloroacetylamidophosphate, sodium salt | 18183-64-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: dimethyl N-trichloroacetylamidophosphate, sodium salt
• 英文别名: sodium dimethyl trichloroacetamidatophosphate；sodium dimethyl tricholoracetamidophosphonate；trichloroacetyl-amidophosphoric acid dimethyl ester; sodium-compound；Trichloracetyl-amidophosphorsaeure-dimethylester; Natrium-Verbindung；Sodium;dimethoxyphosphoryl-(2,2,2-trichloroacetyl)azanide
• CAS: 18183-64-7
• 化学式: C₄H₆Cl₃NO₄P*Na
• 分子量: 292.418
• InChiKey: ZWGGXROLEIUTHR-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.34
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  53.6
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  四苯基溴化锑 、 dimethyl N-trichloroacetylamidophosphate, sodium salt 以 丙酮 、 乙腈 为溶剂， 生成 tetraphenylstibonium dimethyl trichloroacetamidatophosphate
  参考文献：
  名称：

  Amirkhanov, V. M.; Trush, V. A., Russian Journal of General Chemistry, 1995, vol. 65, p. 1021 - 1024

  摘要：

  DOI：

文献信息

• β-Diketonates and their Analogs: Stabilization of the Dimeric M₂{L}₄(D)₂ (M = Co, Ni) Core in the Complexes with Dimethyl-N-trichloroacetylamidophosphate {Cl₃C(O)NP(O)(OCH₃)₂}^-
  作者：Elizaveta A. Bundya、Vladimir M. Amirkhanov、Vladimir A. Ovchynnikov、Victor A. Trush、Konstantin V. Domasevitch、Joachim Sieler、Victor V. Skopenko

  DOI：10.1515/znb-1999-0810

  日期：1999.8.1

  formula [MX}2(2-propanol)]2 (M = Co(II) (1), Ni(II) (2); X} = Cl3CC(O)NP(O)(OCH3)2) have been prepared and characterized by means of IR, UV-VIS spectroscopy and X-ray analysis. The compounds are isomorphous according to X-ray powder diffraction studies. Crystal data for 1: triclinic, P1̄, with a = 9.510(2), b = 12.053(2), c = 23.594(5) Å ,a = 84.74(3), b = 86.47(3), g = 75.45(3)°, Z = 2, V = 2604.7(9)

  配位化合物通式[MX}2(2-丙醇)]2 (M = Co(II) (1), Ni(II) (2); X} = Cl3CC(O)NP(O) (OCH3)2) 已制备并通过 IR、UV-VIS 光谱和 X 射线分析表征。根据 X 射线粉末衍射研究，这些化合物是同晶的。1的晶体数据：三斜晶系，P1̄，a = 9.510(2), b = 12.053(2), c = 23.594(5) Å ,a = 84.74(3), b = 86.47(3), g = 75.45( 3)°，Z = 2，V = 2604.7(9) Å3，R1 = 0.067，wR2 = 0.143（对于使用的 6299 唯一反射）。该配合物采用二聚体中心对称分子阵列，具有通过磷酰基的氧原子形成的 Co-O-Co 桥。该结构通过 P = O---H 类型的二聚体内氢键与配位的 2-丙醇稳定。金属原子在略微扭曲的八面体 (Co-O
• Spectroscopic and magnetic studies of mixed lanthanide complexes: LnL3α,α′Dipy in solution and in solid
  作者：M Borzechowska、V Trush、I Turowska-Tyrk、W Amirkhanov、J Legendziewicz

  DOI：10.1016/s0925-8388(02)00075-0

  日期：2002.7

  in the triclinic system, space group P 1 . Magnetic susceptibility and magnetization of the crystals were investigated. High resolution absorption, luminescence and excitation spectra were measured for crystals at 293, 77 and 4 K in order to characterize their physical properties. Radiative and nonradiative processes were analyzed. The role of the ligand singlet and triplet states in energy-transfer

  摘要 合成了新的单体配合物LnL3bip(1/2bip)(Ln=Eu3+, Tb3+)；β-二酮的L-磷-偶氮衍生物：CCl3C(O)NP(O)(OCH3)2和bip-α,α'dipyridyl和单晶生长。进行了 X 射线衍射研究。配合物在三斜晶系中结晶，空间群 P 1 。研究了晶体的磁化率和磁化强度。在 293、77 和 4 K 下测量晶体的高分辨率吸收、发光和激发光谱，以表征它们的物理特性。分析了辐射和非辐射过程。研究了配体单重态和三重态在能量转移中的作用以及电荷转移态在发射猝灭中的作用。
• A New Binuclear Lutetium(III) Dimethyl-N-trichloroacetylamidophosphate Complex with a γ, γ'-Dipyridyl Bridge, {Lu[CCl₃C(O)NP(O)(OCH₃)₂]₃}2-μ(γ,γ'-dipy)
  作者：Victor A. Trush、Jolanta Swiatek-Kozlowska、Victor V. Skopenko、Vladimir M. Amyrkhanov

  DOI：10.1515/znb-2001-0306

  日期：2001.3.1

  type of binuclear coordination compound of lutetium, Lu2L6 · μ-(γ,γ '-dipy)} (where L = dimethyl-N-trichloroacetylamidophosphate anion and γ,γ '-dipy = 4,4'-dipyridyl), has been obtained. The IR spectroscopic data reveal that the ambidentate phosphoryl ligand is coordinated to the metal center in a bidentate manner via the phosphoryl and carbonyl oxygen atoms. The crystal and molecular structure of Ln2L6-μ-(γ

  摘要 一种新型的镥双核配位化合物，Lu2L6·μ-(γ,γ'-dipy)}（其中L=二甲基-N-三氯乙酰氨基磷酸根阴离子，γ,γ'-dipy=4,4'-二吡啶基） ，已获得。红外光谱数据表明，双齿磷酰基配体通过磷酰基和羰基氧原子以双齿方式与金属中心配位。Ln2L6-μ-(γ ,γ'-dipy)}的晶体和分子结构已通过X射线衍射（三斜晶系，空间群P i 参数：a = 9.259(2), b = 12.530）确定(3), c = 16.548(3) Å, α = 85.44(3)°, β = 75.64(3)°, γ = 70.56(3)°, Z = 1)。该结构由中心对称双核分子组成，其中中性杂环配体通过其氮原子以双齿桥接方式与金属中心配位。
• Amirkhanov; Trush; Kapshuk, Russian Journal of Inorganic Chemistry, 1996, vol. 41, # 12, p. 1947 - 1952
  作者：Amirkhanov、Trush、Kapshuk、Skopenko

  DOI：——

  日期：——