2-methylacrylic acid 3-(diethoxyphosphoryloxy)propyl ester | 99993-26-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: 2-methylacrylic acid 3-(diethoxyphosphoryloxy)propyl ester
• 英文别名: 2-Methyl-acrylic acid 3-(diethoxy-phosphoryloxy)-propyl ester；3-diethoxyphosphoryloxypropyl 2-methylprop-2-enoate
• CAS: 99993-26-7
• 化学式: C₁₁H₂₁O₆P
• 分子量: 280.258
• InChiKey: HOYGTAOJDVZWGX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  18
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  甲基丙烯酸3-羥丙酯 、 氯磷酸二乙酯 在 吡啶 、 三乙胺 作用下， 以 二氯甲烷 为溶剂， 以71%的产率得到2-methylacrylic acid 3-(diethoxyphosphoryloxy)propyl ester
  参考文献：
  名称：

  具有长烷基链间隔基的甲基丙烯酸酯官能化的膦酸酯和磷酸盐的合成及其在水溶液中的自聚集

  摘要：

  摘要合成了可聚合的两亲有机磷化合物，研究了它们的自聚集行为。所研究的分子包含一个亲水性的磷端基，一个长度可变的3至11 CH 2烷基链间隔基基团和在另一链端的可聚合甲基丙烯酸基团。因此，分子代表一类可聚合表面活性剂。使用了两种不同的反应方法。不饱和醇或含溴的醇都可以用作制备有机磷表面活性剂的起始化合物。通过动态光散射测量研究了在水溶液中制备的化合物的自聚集和胶束形成。在所有情况下，含P两亲物的临界胶束浓度均小于0.040 mol / l，并​​强烈取决于磷头部基团的极性和间隔基的链长。 图形概要 提出了有机磷两亲物作为用于改性金属氧化物表面的表面活性单体的合成。磷头基和甲基丙烯酸酯基之间的间隔物就其长度和组成而言是变化的。研究了这些甲基丙烯酸酯官能化的磷酸盐和膦酸酯表面活性剂的自聚集行为。

  DOI：

  10.1007/s00706-008-0045-y

文献信息

• THERMALLY CONDUCTIVE COMPOSITION
  申请人：3M Innovative Properties Company

  公开号：EP1773925A1

  公开（公告）日：2007-04-18
• THERMALLY CONDUCTIVE SHEET
  申请人：3M Innovative Properties Company

  公开号：EP1791874A1

  公开（公告）日：2007-06-06
• Thermally Conductive Sheet
  申请人：Yoda Masaki

  公开号：US20070224426A1

  公开（公告）日：2007-09-27

  There is provided a thermally conductive sheet containing: a binder component, a modified liquid polyolefin, and at least one thermally conductive filler selected from the group consisting of metal oxide and metal hydroxide. The thermally conductive sheet can have good moldability, and the surface of the sheet is inhibited from being contaminated by bleeding or the like. Further, the sheet can have good flexibility maintained for a long period of time and is inhibited from deteriorating or emitting an offensive odor due to decomposed matter of an organic phosphorous compound even when an organic phosphorous compound is contained.
• Thermally Conductive Composition
  申请人：Hiroshige Yuji

  公开号：US20070249755A1

  公开（公告）日：2007-10-25

  There is provided a thermally conductive composition including: a thermally conductive filler, and a binder component. The thermally conductive filler includes: a particulate central portion comprising metal aluminum, and an electrically-insulated oxide layer having an average thickness of 500 nm or more formed on a surface of said central portion. The thermally conductive composition is capable of giving a thermally conductive sheet which has high thermal conductivity, which may not cause a problem such as a short circuit even if it is disposed in an integrated circuit (IC), or the like, and which has superior reliability.
• US7851534B2
  申请人：——

  公开号：US7851534B2

  公开（公告）日：2010-12-14