N,N',N''-tris(2-aminopropyl)phosphoric triamide | 1163237-67-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: N,N',N''-tris(2-aminopropyl)phosphoric triamide
• CAS: 1163237-67-9
• 化学式: C₉H₂₇N₆OP
• 分子量: 266.327
• InChiKey: WURFWRVMKAMWHP-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  1,3-丙二胺 在 三氯氧磷 、 sodium ethanolate 作用下， 以 乙醇 为溶剂， 反应 2.0h， 生成 N,N',N''-tris(2-aminopropyl)phosphoric triamide
  参考文献：
  名称：

  pH-reversible supramolecular hydrogels based on aminoalkyl phosphoamide compounds

  摘要：

  A series of aminoalkyl phosphoamide compounds of the general formula O=P(NH)(3)(CH2)(n)(NH2)(3) (n = 2, 3, 4, 6) and [O=P(NH)(2)(CH2)(2)(NH2)(2)](2) have been prepared by reacting phosphoryl trichloride with diamines, and their pH-modulated gelation and self-assembly behaviour are reported. pH-reversible hydrogels are formed in neutral water by the physical entanglement oriented by hydrogen bonds. Highly polar nature of these compounds affords multiple sites for supramolecular interactions, leading to the self-assembled nanostructures with different morphologies according to pH conditions.

  DOI：

  10.1080/10610278.2011.638382