(R,S)-bis(1,2-N,N'-dimethylaminomethylferrocenyl)dimethylsilane | 250259-45-1

• 分子结构分类: 有机化合物 - 碳氢化合物 - 芳香烃
• 英文名称: (R,S)-bis(1,2-N,N'-dimethylaminomethylferrocenyl)dimethylsilane
• 英文别名: cyclopenta-1,3-diene;1-[5-[[2-[(dimethylamino)methyl]cyclopenta-2,4-dien-1-yl]-dimethylsilyl]cyclopenta-1,3-dien-1-yl]-N,N-dimethylmethanamine;iron(2+)
• CAS: 250259-45-1；12249-15-9；250259-46-2
• 化学式: C₂₈H₃₈Fe₂N₂Si
• 分子量: 542.403
• InChiKey: IFKYDLUIAAOLFG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  meso-bis(1,2-N,N'-dimethylaminomethylferrocenyl)dichlorosilane 、 甲基氯化镁 以 乙醚 为溶剂， 以81%的产率得到(R,S)-bis(1,2-N,N'-dimethylaminomethylferrocenyl)dimethylsilane
  参考文献：
  名称：

  Bis-(1,2-N,N-dimethylaminomethylferrocenyl)dichlorosilane—structure and reactivity

  摘要：

  The treatment of silicon tetrachloride with two equivalents of 2-dimethyl-aminomethylferrocenyl lithium (1), (FcN)Li, affords (R,S)-(FcN)(2)SiCl2 (3). Complex 3 was used as the starting chlorosilyl compound for reaction with MeMgCl to give (R,S)(FcN)(2)SiMe2 (4). Dimethyldichlorosilane reacts with two equivalents of 1 to form an isomeric mixture of 4 (meso) and (R,R-) and (S, S)-bis-(1, 2-N,N-dimethylaminomethylferrocenyl)dimethylsilane. A detailed characterization of 3 and 4 has been carried out by H-1-, C-13-, Si-29-NMR and Mossbauer spectroscopies. The structures of 3 and 4 have been determined by X-ray diffraction analysis. The redox behaviour of 3 and 4 has been studied by electrochemical techniques. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00244-2