磷酸十六烷基二苯基酯 | 56827-92-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 中文名称: 磷酸十六烷基二苯基酯
• 英文名称: n-hexadecyl diphenyl phosphonate
• 英文别名: phosphoric acid hexadecyl ester-diphenyl ester；Phosphorsaeure-hexadecylester-diphenylester；Phosphoric acid, hexadecyl diphenyl ester；hexadecyl diphenyl phosphate
• CAS: 56827-92-0
• 化学式: C₂₈H₄₃O₄P
• 分子量: 474.621
• InChiKey: FEUQWJRZKZQFAO-UHFFFAOYSA-N

物化性质

• 熔点：
  21-22 °C
• 沸点：
  190-195 °C(Press: 10-13 Torr)
• 密度：
  1.012 g/cm3(Temp: 25 °C)

计算性质

• 辛醇/水分配系数(LogP)：
  10.9
• 重原子数：
  33
• 可旋转键数：
  20
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  磷酸十六烷基二苯基酯 在 platinum(IV) oxide 吡啶 、 氢气 、 sodium phosphate 作用下， 以 乙醇 、 二氯甲烷 为溶剂， 22.0 ℃ 、303.98 kPa 条件下， 反应 0.5h， 生成 Phosphoric acid 4-benzyloxy-cyclohexyl ester hexadecyl ester
  参考文献：
  名称：

  Inhibition of human erythrocyte membrane phosphatidylinositol 4-kinase by phospholipid analogues

  摘要：

  Analogues of phosphatidylinositol (Ptdlns, 1) have been synthesized to investigate the structural requirements for inhibition of a Ptdlns 4-kinase obtained from human erythrocyte membranes. While the presence of either D-1 or D-3 Stereochemistry in the inositol moiety greatly influences the degree of inhibition produced by Ptdlns analogues, the stereochemistry of the glycerol moiety is of little consequence. Neither structural feature, however, makes a significant contribution to binding affinity. Competitive inhibitory activity was found to be retained (or even enhanced) in substantially simpler analogues consisting of 1 or 2 hydrocarbon chains attached to a charged phosphate head group, such as in the phosphatidic acids, 24 and 26. The observation that the phosphatidylinositol 4-phosphate (Ptdlns 4P) and phosphatidic acid analogues (eg, 16 or 17, and 26 respectively) inhibit Ptdlns 4-kinase may suggest that such species have a regulatory role in Ptdlns turnover.

  DOI：

  10.1016/0223-5234(94)90146-5
• 作为产物：
  描述：

  1-十六烷醇 在 三氯氧磷 作用下， 生成 磷酸十六烷基二苯基酯
  参考文献：
  名称：

  烷基芳基磷酸盐的化学和物理性质

  摘要：

  DOI：

  10.1021/ie50529a062

文献信息

• Modification method of resins
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0612797A2

  公开（公告）日：1994-08-31

  Provided for resins by the present invention are flame-retarding, thermal stabilization and compatibilization methods, which make use of specific diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptane and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexane, or derivatives thereof. The novel derivatives, polymeric microspheres and the like are also provided.

  本发明为树脂提供了阻燃、热稳定和相容方法，这些方法利用了特定的二胍胺衍生物，主要是 2,5/2,6-双(4,6-二氨基-1,3,5-三嗪-2-基)-双环[2.2.1]庚烷和 1,3/1,4-双(4,6-二氨基-1,3,5-三嗪-2-基)-环己烷或其衍生物。此外，还提供了新型衍生物、聚合物微球等。
• Flame retardant radiation curable compositions
  申请人：Cytec Surface Specialties, S.A.

  公开号：EP2154191A1

  公开（公告）日：2010-02-17

  The invention relates to a flame retardant composition comprising at least one polymer precursor, at least one flame retardant (A) selected from cyclic phosphonate esters responding to formula (I) and at least one flame retardant (B) selected from phosphorus derivatives different from the cyclic phosphonates of formula (I) and their use to make fire resistant glass laminates.

  本发明涉及一种阻燃剂组合物，该组合物包含至少一种聚合物前体、至少一种选自符合式 (I) 的环状膦酸酯的阻燃剂 (A) 和至少一种选自不同于式（I）环状膦酸酯的磷衍生物的阻燃剂（B），以及它们在制造防火玻璃层压板中的用途。
• Crystalline high modulus thermoplastic polyurethane
  申请人：Lubrizol Advanced Materials, Inc.

  公开号：US10774172B2

  公开（公告）日：2020-09-15

  A crystalline non-reinforced thermoplastic polyurethane composition having a high flexural modulus comprises 5% to 25% of a hydroxyl-functional polyol intermediate having a weight average molecular weight of 250 to 3000 and 75% to 95% hard segment comprising an unbranched, unsubstituted, linear chain diol and an aromatic isocyanate.

  一种具有高弯曲模量的结晶型非增强热塑性聚氨酯组合物包含 5% 至 25% 的羟基官能团多元醇中间体（其重量平均分子量为 250 至 3000）和 75% 至 95% 的硬段（由未支链、未取代的线性链二醇和芳香族异氰酸酯组成）。
• Brown et al., Journal of the Chemical Society, 1955, p. 1584,1585
  作者：Brown et al.

  DOI：——

  日期：——
• Polymer compositions containing hydrated basic magnesium calcium carbonates as smoke-depressant additives
  申请人：MONSANTO EUROPE S.A.

  公开号：EP0012578B1

  公开（公告）日：1983-06-08