磷酸氢(Z,Z)-9-十八烯酯 | 14450-07-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 中文名称: 磷酸氢(Z,Z)-9-十八烯酯
• 英文名称: dioleyl phosphate
• 英文别名: Dioleylphosphat；phosphoric acid di-octadec-9c-enyl ester；Dioleyl hydrogen phosphate；bis[(Z)-octadec-9-enyl] hydrogen phosphate
• CAS: 14450-07-8
• 化学式: C₃₆H₇₁O₄P
• 分子量: 598.931
• InChiKey: WFFZELZOEWLYNK-CLFAGFIQSA-N

物化性质

• 沸点：
  651.4±58.0 °C(Predicted)
• 密度：
  0.929±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  14.8
• 重原子数：
  41
• 可旋转键数：
  34
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  55.8
• 氢给体数：
  1
• 氢受体数：
  4

安全信息

• 海关编码：
  2919900090

反应信息

• 作为产物：
  描述：

  油醇 在 吡啶 、 水 、 三乙胺 、 N,N-二异丙基乙胺 、 三氯化磷 作用下， 以 二氯甲烷 为溶剂， 反应 0.5h， 生成 磷酸氢(Z,Z)-9-十八烯酯
  参考文献：
  名称：

  A Selective and Mild Synthetic Route to Dialkyl Phosphates

  摘要：

  描述了一种非常温和的二烷基磷酸酯的合成路线。将适当的醇与PCl3反应，然后用吡啶和四氯化碳处理，得到相应的三氯甲基酯。随后与醋酸的三乙胺盐反应，再在非常温和的条件下水解生成的混合酸酐，从而高产率地得到二烷基磷酸酯。

  DOI：

  10.1055/s-2003-38074

文献信息

• Molecular compounds having complementary surfaces to targets
  申请人：Alnis, LLC

  公开号：US20030153001A1

  公开（公告）日：2003-08-14

  Synthetic polymer complements (SPCs) are provided, as well as methods for their synthesis and use. The SPCs may have surfaces that include functional groups that are complementary to surface sites of targets such as nanostructures or macromolecular targets, and may be capable of specifically interacting with such targets. The positions of the functional groups in one embodiment are stabilized by a polymer network. The SPCs are formed by contacting the target with a set of monomers which self-assemble on the target, and then are polymerized into a network to form the synthetic polymer complement. At least a portion of the surface of the resulting SPC thus may include an imprint of the target. The complex of the SPC and the target may be the desired product. Alternatively, the target is released, for example, by controllably expanding and contracting the crosslinked network. The SPC is isolated and used in many applications.

  提供了合成聚合物互补体（SPC），以及它们的合成和使用方法。SPC可能具有表面，其中包括与目标（如纳米结构或大分子靶标）表面位点互补的功能基团，并且可能能够与这些目标特异性地相互作用。在一种实施例中，功能基团的位置由聚合物网络稳定。通过将一组单体与目标接触，然后将其聚合成网络来形成合成聚合物互补体SPC。因此，至少部分形成的SPC表面可能包括目标的印迹。SPC和目标的复合物可能是所需的产品。或者，例如通过可控地扩张和收缩交联网络来释放目标。SPC被分离并用于许多应用。
• Creamy cleansing compositions
  申请人：Kao Corporation

  公开号：EP0037161A2

  公开（公告）日：1981-10-07

  A creamy cleansing composition comprises the following four components: (A) one or more phosphoric ester surfactants, (B) an organic or inorganic salt, (C) polyethylene glycol and (D) an ethylene oxide addition type non-ionic surface active agent or a cationic surface active agent. The cleansing composition is gentle to the skin or hair, and stable without separation for a long period of time.

  一种乳状清洁组合物由以下四种成分组成：(A) 一种或多种磷酸酯表面活性剂，(B) 有机或无机盐，(C) 聚乙二醇和 (D) 环氧乙烷加成型非离子表面活性剂或阳离子表面活性剂。该清洁组合物对皮肤或头发温和，长期稳定不分离。
• Crystaline block copolymer and process for producing the same
  申请人：Asahi Kasei Kogyo Kabushiki Kaisha

  公开号：EP0234512A2

  公开（公告）日：1987-09-02

  crystalline block copolymer containing at least a triblock chain represented by the formula A-B-C or containing at least a radial structure represented by the formula (D-EX in the polymer chain is provided. These triblock chains or radial structures comprise blocks of a homopolymer of a vinyl aromatic compound or a copolymer of a vinylaromatic compound with another vinylaromatic compound or a conjugated diene compound having a glass transition temperature of not lower that 50°C and a weight average molecular weight in the range of from 2,000 to 100,000 and blocks of a homopolymer of a conjugated diene compound or a copolymer of a conjugated diene compound with another conjugated diene compound or a copolymer of a conjugated diene compound having less that 20 wt.% of a vinyl aromatic compound having a glass transition temperature of not higher than 10°C and a crystallinity at 25°C and a 1,4-trans-linkage ratio in the conjugated diene portion of 80 % or higher. These crystalline block copolymers are produced by polymerization of the respective monomers in the presence of a composite catalyst comprising the catalyst components (a), (b) and (c), or (a), (b), (c) and (d), wherein (a) is an organic compound of barium or strontium; (b) is an organic compound of lithium; (c) is an organomagnesium compound; and (d) is an organoaluminum or organozinc compound. Further provided are shaped bodies obtainable by injection, extrusion or compression molding comprising such crystalline block copolymer.

  本发明提供了一种结晶嵌段共聚物，其聚合物链中至少含有一个由式 A-B-C 表示的三嵌段链或至少含有一个由式（D-EX）表示的径向结构。这些三嵌段链或径向结构包括乙烯基芳香族化合物均聚物嵌段，或乙烯基芳香族化合物与另一种乙烯基芳香族化合物或共轭二烯化合物的共聚物嵌段，其玻璃化转变温度不低于 50℃，重量平均分子量在 2,000 至 100,000 之间；以及共轭二烯化合物均聚物嵌段，或共轭二烯化合物与另一种共轭二烯化合物的共聚物嵌段，或共轭二烯化合物与乙烯基芳香族化合物或共轭二烯化合物的共聚物嵌段，其玻璃化转变温度不低于 50℃，重量平均分子量在 2,000 至 100,000 之间。乙烯基芳香族化合物的共聚物，其玻璃化转变温度不高于 10°C，结晶度为 25°C，共轭二烯部分的 1,4-反式连接比例为 80% 或更高。 这些结晶嵌段共聚物是在由催化剂组分(a)、(b)和(c)或(a)、(b)、(c)和(d)组成的复合催化剂存在下，通过聚合各单体而制得的，其中 (a) 是钡或锶的有机化合物； (b) 是锂的有机化合物 (c) 是一种有机镁化合物；和 (d) 有机铝或有机锌化合物。 此外，还提供了可通过注塑、挤压或压缩成型获得的由此类结晶嵌段共聚物组成的成型体。
• Lubricant compositions
  申请人：ETHYL PETROLEUM ADDITIVES, INC.

  公开号：EP0459656A1

  公开（公告）日：1991-12-04

  Gear oils and gear oil additive concentrates of enhanced positraction performance are described. They comprise: (i) at least one oil-soluble sulfur-containing extreme pressure or antiwear agent; (ii) at least one oil-soluble amine salt of a partial ester of an acid of phosphorus; and (iii) at least one oil-soluble succinimide of the formula where R₁ is an alkyl or alkenyl group having an average of 8 to 50 carbon atoms, and each of R₂, R₃ and R₄ is a hydrogen atom or an alkyl or alkenyl group having an average of up to about 4 carbon atoms. These compositions preferably contain one, more preferably two, and most preferably all three of the following additional components: (iv) at least one amine salt of a carboxylic acid; (v) at least one nitrogen-containing ashless dispersant; and (vi) at least one trihydrocarbyl ester of a pentavalent acid of phosphorus.

  所述齿轮油和齿轮油添加剂浓缩物具有增强的正曳引性能。它们包括：(i) 至少一种油溶性含硫极压剂或抗磨剂；(ii) 至少一种磷酸部分酯的油溶性胺盐；(iii) 至少一种油溶性琥珀酰亚胺，其式为 其中 R₁ 是平均具有 8 至 50 个碳原子的烷基或烯基，R₂、R₃ 和 R₄ 各为氢原子或平均具有最多约 4 个碳原子的烷基或烯基。这些组合物最好含有一种，更优选两种，最优选全部三种下列附加成分：(iv) 至少一种羧酸胺盐； (v) 至少一种含氮无灰分散剂；以及 (vi) 至少一种五价磷酸三烃基酯。
• Oil additive concentrates and lubricants of enhanced performance capabilities
  申请人：ETHYL PETROLEUM ADDITIVES LIMITED

  公开号：EP0531585A1

  公开（公告）日：1993-03-17

  Additive concentrates, lubricating oil compositions and the use thereof are described. The compositions comprise one or more of each of the following oil-soluble additive components: a) a Mannich base ashless dispersant; b) a metal-free sulphur-containing antiwear and/or extreme pressure agent; c) a metal-free phosphorus-containing and nitrogen-containing antiwear and/or extreme pressure agent; and optionally but preferably, d) an amine salt of a carboxylic acid. Oils containing such additive components exhibit excellent performance under heavy duty service such as in the planetary spur gear test. In addition, such oils exhibit good demulsibility in the ASTM D1401 test procedure and good clean gear performance in the CRC L-60 test.

  本文描述了添加剂浓缩物、润滑油组合物及其用途。这些组合物包含以下每种油溶性添加剂成分中的一种或多种：a) 曼尼希基无灰分散剂；b) 不含金属的含硫抗磨剂和/或极压剂；c) 不含金属的含磷和含氮抗磨剂和/或极压剂；以及可选但最好是 d) 羧酸胺盐。含有此类添加剂成分的机油在重负荷工作（如行星直齿轮试验）中表现出卓越的性能。此外，此类润滑油在 ASTM D1401 试验程序中表现出良好的抗乳化性，在 CRC L-60 试验中表现出良好的清洁齿轮性能。