cyclopenta-1,3-diene;cyclopenta-2,4-dien-1-ylmethyl(triethyl)azanium;iron(2+);iodide | 366795-91-7

• 分子结构分类: 有机化合物 - 碳氢化合物 - 芳香烃
• 英文名称: cyclopenta-1,3-diene;cyclopenta-2,4-dien-1-ylmethyl(triethyl)azanium;iron(2+);iodide
• CAS: 366795-91-7
• 化学式: C₁₇H₂₆FeN*I
• 分子量: 427.152
• InChiKey: DFGCUKAXKRUOON-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  manganese(II) chloride tetrahydrate 、 ammonium tri(oxalato)chromate(III) trihydrate 、 cyclopenta-1,3-diene;cyclopenta-2,4-dien-1-ylmethyl(triethyl)azanium;iron(2+);iodide 以 甲醇 、 水 为溶剂， 以38%的产率得到
  参考文献：
  名称：

  (Ferrocenylmethyl)trialkyl ammoniums as template cations in optically active two-dimensional oxalate bridged [Cr–Mn] and [Cr–Ni] molecule-based magnets: synthesis and magnetic properties

  摘要：

  A series of (ferrocenylmethyl)trialkyl ammoniums: FcCH(2)NR(3)(+) with R = CH3 (1), C2H5 (2), n-C3H7 (3), n-C4H9 (4) (X-ray structure provided), n-C5H11 (5) and the planar chiral 1,2-disubstituted Fc(CH3)CH2NBu3+ (6) have been tentatively used as template cation in order to synthesise bidimensional (2D) oxalate bridged molecule-based magnets of general formula {[(CrMII)-M-III(ox)(3)][FcCH(2)NR(3)]}(n) and {[(CrMII)-M-III(ox)(3)][Fc(CH3)CH2NBu3]}(n) (M = Mn2+, Ni2+, ox = C2O42-). These polymeric compounds were obtained only for reactions performed with 2, 3, 4 and 6. Starting from resolved Cr(ox)'-, the networks were prepared in their two enantiomeric forms in the case of ([(CrNiII)-Ni-III(ox)(3)][FcCH(2)NBu(3)])(n) ([Cr-Delta-Ni-Lambda]-4 and [Cr-Lambda-Ni-Delta]-4) or {[(CrMnII)-Mn-III(ox)(3)][FcCH(2)NBu(3)]}(n) ([Cr-Lambda-Mn-Delta]-4 and [Cr-Lambda-Mn-Delta]-4)) and characterised by circular dichroism measurements. All these compounds are ferromagnets with a Curie temperature close to 6 K when M = Mn and to 17 K for Ni. While the manganese [Cr-Mn] containing compounds are soft magnets, the [Cr-Ni] networks show coercive force up to 2200 Oe far above those previously reported for these networks. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)00902-0
• 作为产物：
  描述：

  N,N,N-(ferrocenylmethyl)trimethylammonium iodide 、 三乙胺 以 乙腈 为溶剂， 以59%的产率得到cyclopenta-1,3-diene;cyclopenta-2,4-dien-1-ylmethyl(triethyl)azanium;iron(2+);iodide
  参考文献：
  名称：

  摘要：

  Trialkyl (ferrocenyl methyl)ammonium salts and their 2-substituted analogs designed for the preparation of molecular ferromagnetics based on bimetallic oxalates were synthesized using classical alkylation of dialkylaminomethylferrocenes by alkyl halides and nucleophilic substitution reaction of 2-substituted dimethylaminomethylferrocene methiodides with trialkylamines. In the case of salts with electron-donating substituents in position 2, only the latter of the two proposed routes is applicable because IV-alkylation with alkyl halides is accompanied by competing ferrocenylmethylation of the starting amine. On the contrary, the salts with electron-withdrawing 2-substituents should be prepared preferably by the reaction of amines with alkyl halides, while nucleophilic trialkylamination of methiodides is complicated by deprotonation. induced by bases.

  DOI：

  10.1023/a:1011377611293