Ru2(CO)6(μ-SCH2CH2CH2S) | 288141-53-7

• 英文名称: Ru2(CO)6(μ-SCH2CH2CH2S)
• 英文别名: [Ru2(CO)6(μ-κ-S(CH2)3S)]；Ru2(1,3-propanedithiolate)(CO)6；Ru2(CO)6(μ-S2C3H6)；[Ru2(CO)6(μ-pdt)]
• CAS: 288141-53-7
• 化学式: C₉H₆O₆Ru₂S₂
• 分子量: 476.415
• InChiKey: VSWDAOVGTCOKDJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Ru2(CO)6(μ-SCH2CH2CH2S) 、 双二苯基膦甲烷 以 四氢呋喃 为溶剂， 以30%的产率得到[diruthenium(carbonyl)₄(μ-dppm)(μ-pdt)]
  参考文献：
  名称：

  含桥接二硫醇盐和dppm配体的双核钌配合物：[Ru2（CO）4（μ-SCH2CH2CH2S）（μ-dppm）]和[Ru2（CO）4 {（μ-SC6H3（CH3）S]（）的X射线结构μ-dppm）]

  摘要：

  摘要[Ru3（CO）10（μ-dppm）]（4）与1,2-乙二硫醇，1,3-丙二硫醇和3,4-甲苯二硫醇在回流的THF中反应，得到双核二硫lato配合物[Ru2（CO） 4（μ-SCH2CH2S）（μ-dppm）]（5），[Ru2（CO）4（μ-SCH2CH2CH2S）（μ-dppm）]（6）和[Ru2（CO）4 {μ-SC6H3（CH3） S}（μ-dppm）]（7）。CD2Cl2中四氟硼酸对复合物5和6的质子化导致形成阳离子氢化物复合物[（μ-H）Ru2（CO）4（μ-SCH2CH2S）（μ-dppm）] +（8）和[Ru2（CO ）4（μ-SCH2CH2CH2S）（μ-dppm）] +（9）作为PF6-盐分离出来。化合物5和6也分别从dppm与[Ru2（CO）6（μ-SCH2CH2S）]（10）和[Ru2（CO）6（μ-SCH2CH2CH2S）]（11）的反应获得。用四氟硼酸对10和

  DOI：

  10.1016/s0277-5387(02)01439-0
• 作为产物：
  描述：

  [(μ-H)Ru3(CO)10]2(μ-SCH2CH2CH2S) 以 四氢呋喃 为溶剂， 以34%的产率得到Ru2(CO)6(μ-SCH2CH2CH2S)
  参考文献：
  名称：

  Dithiolate complexes of ruthenium and osmium: X-ray structures of [Ru2(CO)6(μ-SCH2CH2S)] and [{(μ-H)M3(CO)10)}2(μ-SCH2CH2CH2S)] (M=Ru, Os)

  摘要：

  A comparison between the reactivity of [Ru-3(CO)(12)] and [Os-3(CO)(10)(MeCN)(2)] with 1,2-ethanedithiol (HSCH2CH2SH) and 1,3-propanedithiol (HSCH2CH2CH2SH) is reported. The reaction of [Ru-3(CO)(12)] with 1.2-ethanedithiol at 68 degrees C afforded [Ru-2(CO)(6)(mu-SCH2CH2S)] (1) in 40% yield, whereas the reaction with 1,3-propanedithiol yielded [{(mu-H)Ru-3(CO)(10)}(2)(mu-SCH2CH2CH2S)] (2) and [Ru-2(CO)(6)(mu-SCH2CH2CH2S)] (3) in 30 and 19% yields respectively. Treatment of [Os-3(CO)(10)(MeCN)(2)] with 1,2-ethanedithiol gave [(mu-H) Os-3(CO)(10)(mu-SCH2CH2SH)] (4) in 60% yield and with 1,3-propanedithiol it afforded [{(mu-H)Os-3(CO)(10)}(2)(mu-SCH2CH2CH2S)] (5) in 30% yield. Compounds 1 and 3 both react with equimolar amounts of PPh3 at room temperature to give the monosubstituted products [Ru-2(CO)(5)(mu-SCH2CH2S)(PPh3)] (6) and [Ru-2(CO)(5)(mu-SCH2CH2S)(PPh3)] (7) respectively. When heated to 68 degrees C, compound 2 transformed into 3. The compounds have been characterized by spectroscopic studies, and in the case of 1, 2 and 5 by X-ray crystallography. (C) 2000 Elsevier Science Ltd All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00353-3
• 作为试剂：
  描述：

  甲酸 在 Ru2(CO)6(μ-SCH2CH2CH2S) 、 三乙胺 、 三(邻甲基苯基)磷 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 5.0h， 生成 氢气
  参考文献：
  名称：

  基于钌的仿生氢簇，可有效地从甲酸产生光催化氢

  摘要：

  钌系仿生氢簇，的[Ru 2（CO）6（μ-SCH 2 CH 2 CH 2 S）]（1），已经合成和，在P的存在下配体三（ø甲苯基）膦证明了由甲酸分解产生的有效光催化氢。使用少于50 ppm的催化剂可获得5500 h -1的周转频率（TOF）和超过24 700的周转率（TONs），因此代表了钌配合物的最高TOF以及从甲酸生产光催化制氢的最佳效率酸。而且1 在90°C下长时间光辐照后，显示出高稳定性，光催化剂没有明显降解。

  DOI：

  10.1002/chem.201406381

文献信息

• Diruthenium Dithiolato Cyanides:  Basic Reactivity Studies and a Post Hoc Examination of Nature's Choice of Fe versus Ru for Hydrogenogenesis
  作者：Aaron K. Justice、Rachel C. Linck、Thomas B. Rauchfuss

  DOI：10.1021/ic051989z

  日期：2006.3.1

  Ru2(S2C3H6)(CO)6 (1) with 2 equiv of Et4NCN yielded (Et4N)2[Ru2(S2C3H6)(CN)2(CO)4], (Et4N)2[3], which was shown crystallographically to consist of a face-sharing bioctahedron with the cyanide ligands in the axial positions, trans to the Ru-Ru bond. Competition experiments showed that 1 underwent cyanation >100x more rapidly than the analogous Fe2(S2C3H6)(CO)6. Furthermore, Ru2(S2C3H6)(CO)6 underwent

  Ru2（S2C3H6）（CO）6（1）与2当量的Et4NCN反应生成（Et4N）2 [Ru2（S2 ）（CN）2（CO）4]，（Et4N）2 [3]，如图所示从晶体学上讲是由面共享的生物体二十面体组成，轴向上带有氰化物配体，反过来是Ru-Ru键。竞争实验表明1的氰化速度比类似的Fe2（S2 ）（CO）6快100倍以上。此外，Ru2（S2 ）（CO）6比[Ru2（S2 ）（CN）（CO）5]-进行双氰化的速度更快，这意味着高度亲电的中间体[Ru2（S2 ）（mu-CO）（CN）（CO） 5]-。如[Ru2（S2 ）（mu-H）（CO）6] +，[1H] +的产生所证明，Ru2（S2 ）（CO）6（1）比二铁化合物更碱性。与1相反，复合物[1H] +在MeCN溶液中不稳定，并转化为[Ru2（S2 ）（mu-H）（CO）5（MeCN）] +。（Et4N）2
• Sn–S and Ru–Ru bonds cleavage reactions between [Ph3SnS(CH2)3SSnPh3] and Ru3(CO)12: X-ray crystal structures of [Ph3SnS(CH2)3SSnPh3] and trans-[Ru(CO)4(SnPh3)2]
  作者：Shishir Ghosh、Rehana Pervin、Arun K. Raha、Shariff E. Kabir、Brian K. Nicholson

  DOI：10.1016/j.ica.2009.05.011

  日期：2009.8

  The organotin complex [Ph3SnS(CH2)(3)SSnPh3] (1) was synthesized by PdCl2 catalyzed reaction between Ph3SnCl and disodium-1,3-propanedithiolate which in turn was prepared from 1,2-propanedithiol and sodium in refluxing THF. Reaction of 1 with Ru-3(CO)(12) in refluxing THF affords the mononuclear complex trans-[Ru(CO)(4)(SnPh3)(2)] (2) and the dinuclear complex [Ru-2(CO)(6)(mu-kappa(2)-SCH2CH2CH2S)] (3) in 20 and 11% yields, respectively, formed by cleavage of Sn-S bond of the ligand and Ru-Ru bonds of the cluster. Treatment of pymSSnPPh(3) (pymS = pyrimidine-2-thiolate) with Ru-3(CO)(12) at 55-60 degrees C also gives 2 in 38% yield. Both 1 and 2 have been characterized by a combination of spectroscopic data and single crystal X-ray diffraction analysis. (C) 2009 Elsevier B. V. All rights reserved.
• Diphosphine Mobility at a Binuclear Metal Center: A Concerted Double Trigonal-Twist in Bis(dithiolate) Complexes [M₂(CO)₄(μ-dppm){μ-S(CH₂)_<i>n</i>S}] (M = Fe, Ru; <i>n</i> = 2, 3)
  作者：Graeme Hogarth、Shariff E. Kabir、Idris Richards

  DOI：10.1021/om100894w

  日期：2010.12.13

  Heating [M-2(CO)(6)mu-S(CH2)(n)S}] (M = Fe, Ru; n = 2 (edt), 3 (pdt)) with bis(diphenylphosphino)methane (dppm) in toluene affords the bridged-diphosphine complexes [M-2(CO)(4)(mu-dppm)mu-S(CH2)(n)S}]. At room temperature, all show two separate environments for the methylene protons of the diphosphine ligand, while at higher temperatures these coalesce to a single peak. This behavior, which interconverts the two sulfur atoms, is ascribed to a concerted double trigonal-twist of the M(CO)(2)P moieties. No such fluxional behavior was observed for the nonlinked dithiolate complexes [Fe-2(CO)(4)(mu-dppm)(mu-SR)(2)] (R = Me, Ph, p-tolyl). The X-ray structures of [M-2(CO)(4)(mu-dppm)(mu-edt)] (M = Fe, Ru) and [Fe-2(CO)(4)(mu-dppm)(mu-SMe)(2)] are presented in order to compare them to the previously reported [M-2(CO)(4)(mu-dppm)(mu-pdt)].