[(μ-H)Ru3(CO)10]2(μ-SCH2CH2CH2S) | 288141-51-5

• 英文名称: [(μ-H)Ru3(CO)10]2(μ-SCH2CH2CH2S)
• CAS: 288141-51-5
• 化学式: C₂₃H₈O₂₀Ru₆S₂
• 分子量: 1274.86
• InChiKey: ORFBAPIPEMTBDW-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [(μ-H)Ru3(CO)10]2(μ-SCH2CH2CH2S) 以 四氢呋喃 为溶剂， 以34%的产率得到Ru2(CO)6(μ-SCH2CH2CH2S)
  参考文献：
  名称：

  Dithiolate complexes of ruthenium and osmium: X-ray structures of [Ru2(CO)6(μ-SCH2CH2S)] and [{(μ-H)M3(CO)10)}2(μ-SCH2CH2CH2S)] (M=Ru, Os)

  摘要：

  A comparison between the reactivity of [Ru-3(CO)(12)] and [Os-3(CO)(10)(MeCN)(2)] with 1,2-ethanedithiol (HSCH2CH2SH) and 1,3-propanedithiol (HSCH2CH2CH2SH) is reported. The reaction of [Ru-3(CO)(12)] with 1.2-ethanedithiol at 68 degrees C afforded [Ru-2(CO)(6)(mu-SCH2CH2S)] (1) in 40% yield, whereas the reaction with 1,3-propanedithiol yielded [{(mu-H)Ru-3(CO)(10)}(2)(mu-SCH2CH2CH2S)] (2) and [Ru-2(CO)(6)(mu-SCH2CH2CH2S)] (3) in 30 and 19% yields respectively. Treatment of [Os-3(CO)(10)(MeCN)(2)] with 1,2-ethanedithiol gave [(mu-H) Os-3(CO)(10)(mu-SCH2CH2SH)] (4) in 60% yield and with 1,3-propanedithiol it afforded [{(mu-H)Os-3(CO)(10)}(2)(mu-SCH2CH2CH2S)] (5) in 30% yield. Compounds 1 and 3 both react with equimolar amounts of PPh3 at room temperature to give the monosubstituted products [Ru-2(CO)(5)(mu-SCH2CH2S)(PPh3)] (6) and [Ru-2(CO)(5)(mu-SCH2CH2S)(PPh3)] (7) respectively. When heated to 68 degrees C, compound 2 transformed into 3. The compounds have been characterized by spectroscopic studies, and in the case of 1, 2 and 5 by X-ray crystallography. (C) 2000 Elsevier Science Ltd All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00353-3
• 作为产物：
  描述：

  1,3-丙二硫醇 、 十二羰基三钌 以 四氢呋喃 为溶剂， 以30%的产率得到[(μ-H)Ru3(CO)10]2(μ-SCH2CH2CH2S)
  参考文献：
  名称：

  Dithiolate complexes of ruthenium and osmium: X-ray structures of [Ru2(CO)6(μ-SCH2CH2S)] and [{(μ-H)M3(CO)10)}2(μ-SCH2CH2CH2S)] (M=Ru, Os)

  摘要：

  A comparison between the reactivity of [Ru-3(CO)(12)] and [Os-3(CO)(10)(MeCN)(2)] with 1,2-ethanedithiol (HSCH2CH2SH) and 1,3-propanedithiol (HSCH2CH2CH2SH) is reported. The reaction of [Ru-3(CO)(12)] with 1.2-ethanedithiol at 68 degrees C afforded [Ru-2(CO)(6)(mu-SCH2CH2S)] (1) in 40% yield, whereas the reaction with 1,3-propanedithiol yielded [{(mu-H)Ru-3(CO)(10)}(2)(mu-SCH2CH2CH2S)] (2) and [Ru-2(CO)(6)(mu-SCH2CH2CH2S)] (3) in 30 and 19% yields respectively. Treatment of [Os-3(CO)(10)(MeCN)(2)] with 1,2-ethanedithiol gave [(mu-H) Os-3(CO)(10)(mu-SCH2CH2SH)] (4) in 60% yield and with 1,3-propanedithiol it afforded [{(mu-H)Os-3(CO)(10)}(2)(mu-SCH2CH2CH2S)] (5) in 30% yield. Compounds 1 and 3 both react with equimolar amounts of PPh3 at room temperature to give the monosubstituted products [Ru-2(CO)(5)(mu-SCH2CH2S)(PPh3)] (6) and [Ru-2(CO)(5)(mu-SCH2CH2S)(PPh3)] (7) respectively. When heated to 68 degrees C, compound 2 transformed into 3. The compounds have been characterized by spectroscopic studies, and in the case of 1, 2 and 5 by X-ray crystallography. (C) 2000 Elsevier Science Ltd All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00353-3