(10-Hydroxy-1-methyl-6,9-dioxo-3,4,6,9-tetrahydro-1H-benzo[g]isochromen-3-yl)-acetic acid methyl ester | 54367-53-2

分子结构分类

有机化合物 - 苯丙烷和聚酮 - 异色满醌

中文名称

——

中文别名

——

英文名称

(10-Hydroxy-1-methyl-6,9-dioxo-3,4,6,9-tetrahydro-1H-benzo[g]isochromen-3-yl)-acetic acid methyl ester

英文别名

(1S,3R)-3,4,6,9-Tetrahydro-10-hydroxy-1-methyl-6,9-dioxo-1H-naphtho<2,3-c>pyran-3-essigsaeure-methylester；(1R,3R)-3,4,6,9-Tetrahydro-10-hydroxy-1-methyl-6,9-dioxo-1H-naphtho<2,3-c>pyran-3-essigsaeure-methylester

(10-Hydroxy-1-methyl-6,9-dioxo-3,4,6,9-tetrahydro-1H-benzo[g]isochromen-3-yl)-acetic acid methyl ester化学式

CAS

54367-53-2；55102-34-6；83376-30-1

化学式

C₁₇H₁₆O₆

mdl

——

分子量

316.31

InChiKey

ONZNLSXABURTCK-PSASIEDQSA-N

BEILSTEIN

——

EINECS

——

计算性质

辛醇/水分配系数(LogP)：

1.89
重原子数：

23.0
可旋转键数：

2.0
环数：

3.0
sp3杂化的碳原子比例：

0.35
拓扑面积：

89.9
氢给体数：

1.0
氢受体数：

6.0

反应信息

作为产物：

描述：

Desacetylanhydro-α-naphthocyclinonsaeure-methylester 在重氮甲烷、盐酸作用下，生成 (1S,3R)-3,4,6,9-Tetrahydro-10-hydroxy-1-methyl-6,9-dioxo-1H-naphtho<2,3-c>pyran-3-essigsaeure-methylester 、 (10-Hydroxy-1-methyl-6,9-dioxo-3,4,6,9-tetrahydro-1H-benzo[g]isochromen-3-yl)-acetic acid methyl ester 、 (1S,3R)-3,4,6,7,8,9-Hexahydro-10-hydroxy-1-methyl-6,9-dioxo-1H-naphtho<2,3-c>pyran-3-essigsaeure-methylester 、 (1R,3R)-3,4,6,7,8,9-Hexahydro-10-hydroxy-1-methyl-6,9-dioxo-1H-naphtho<2,3-c>pyran-3-essigsaeure-methylester

参考文献：

名称：

Laatsch, Hartmut, Liebigs Annalen der Chemie, 1987, p. 297 - 304

摘要：

DOI：

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文献信息

Laatsch, Hartmut, Liebigs Annalen der Chemie, 1987, p. 297 - 304

作者：Laatsch, Hartmut

DOI：——

日期：——

同类化合物

黄麦格霉素镰刀菌素甲醚芦替菌素脱氢胆碱红葱醌紫黄素灰色菌素B 异红葱乙素富仑菌素 B 乳醌霉素A 七尾霉素C 七尾霉素 O-乙基镰红菌素 N-(乙酰氧基)-N-((4-甲基苯基)甲氧基)苯酰胺 N-(4,5-二氢-1,3-噻唑-2-基)-2,4-二甲氧基苯酰胺 9-羟基-7-甲氧基-3-甲基-1H-苯并[g]异苯并吡喃-5,10-二酮 7,9-二羟基-3-甲基-1H-苯并[g]异苯并吡喃-5,10-二酮 3-羟基-3,4-二氢-1H-苯并[g]异苯并吡喃-5,10-二酮 3-溴噻吩 3,9-二羟基-7-甲氧基-3-甲基-1,4-二氢苯并[g]异苯并吡喃-5,10-二酮 3,7,9-三羟基-3-甲基-1,4-二氢苯并[g]异苯并吡喃-5,10-二酮 3,4-二氢-3-羟基-7,9-二甲氧基-3-甲基-1H-萘并[2,3-c]吡喃-5,10-二酮 2-甲基溴丁烷 2-[（（1S，3R）-9-hydroxy-1-methyl-5,10-dioxo-3,4-dihydro-1H-benzo[g]isochromen-3-yl]acetate甲基] 1H-萘并[2,3-c]吡喃-6,9-二酮,3,4-二氢-8,10-二羟基-7-甲氧基-1,3-二甲基-,(1R,3S)- 1H-萘并[2,3-c]吡喃-6,9-二酮,3,4-二氢-5,10-二羟基-7-甲氧基-1,3-二甲基-,(1R,3S)- 1H-氮杂卓,2-[(4-乙氧苯基)甲基]六氢- 10-羟基-8-[(2R,4S,5R)-5-羟基-4-(羟基甲基)-1,3-二恶烷-2-基]-3-甲基-7-(2-氧代丙基)-1-丙基-1H-苯并[g]异苯并吡喃-6,9-二酮 1,5,10-三羟基-7-甲氧基-3-甲基-1H-苯并[g]异苯并吡喃-6,9-二酮 (5R,3aR,11bR)-4'alpha-乙酰氧基-3',3a,4',5',6',11b-六氢-3'alpha,7-二羟基-6'beta-甲基螺[5H-呋喃并[3,2-b]萘并[2,3-d]吡喃-5,2'-[2H]吡喃]-2,6,11(3H)-三酮 (3aR-(3aalpha,5alpha,11balpha))-3,3a,5,11b-四氢-8-羟基-7-甲氧基-5-甲基-2H-呋喃并(3,2-b)萘并(2,3-d)吡喃-2,6,11-三酮 cis-3,4-dihydro-4-hydroxy-3-methyl-1H-naphtho<2,3-c>pyran-5,10-dione 10-hydroxy-7-methoxy-3-methylbenzo[g]isochromene-1,6,9-trione (1S,3R,4R)-3,4-dihydro-4,7,9-trihydroxy-1,3-dimethylnaphtho[2,3-c]pyran-5,10-quinone (1S,3R,4S)-3,4-dihydro-4,7,9-trihydroxy-1,3-dimethylnaphtho[2,3-c]pyran-5,10-quinone (1R,3S,4R)-3,4-dihydro-4,7,9-trihydroxy-1,3-dimethylnaphtho[2,3-c]pyran-5,10-quinone (1R,3S,4S)-3,4-dihydro-4,7,9-trihydroxy-1,3-dimethylnaphtho[2,3-c]pyran-5,10-quinone 2,4-dihydro-1-(hydroxymethyl)-1H-naphtho<2,3-c>pyran-3,5,10-trione (+/-)-3,4-dihydro-1-hydroxy-7,9-dimethoxy-1-methyl-3-(1-propyl)-1H-naphtho<2,3-c>pyran-5,10-quinone fusarubin 8-O-methylfusarubin (1'R*,3'R*)-methyl [1'-hydroxy-5',10'-dioxo-3',4',5',10'-tetrahydro-1'H-naphtho[2,3-c]pyran-3'-yl]acetate 3-methyl-1H-naphtho<2,3-c>pyran-5,10-dione Bromomethyl (5,10-dioxo-5,10-dihydronaphtho[2,3-C]pyran-3-yl) Ketone (3aR,5S,11bR)-5-Methyl-3,3a,5,11b-tetrahydro-1,4-dioxa-cyclopenta[a]anthracene-2,6,11-trione 5-epi-frenolicin B (3aS,5S,11bS)-7-hydroxy-5-propyl-3,3a,5,11b-tetrahydro-2H-benzo[g]thro[3,2-c]isochromene-2,6,11-trione (1R,3R)-3-((4-benzyl-1H-1,2,3-triazol-1-yl)methyl)-9-methoxy-1-methyl-3,4-dihydro-1H-benzo[g]isochromene-5,10-dione (1R,3R)-3-((4-(2-hydroxyphenyl)-1H-1,2,3-triazol-1-yl)methyl)-9-methoxy-1-methyl-3,4-dihydro-1H-benzo[g]isochromene-5,10-dione (1R,3R)-3-((4-hexyl-1H-1,2,3-triazol-1-yl)methyl)-9-methoxy-1-methyl-3,4-dihydro-1H-benzo[g]isochromene-5,10-dione