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纳米碳化钨 | 12070-12-1

中文名称
纳米碳化钨
中文别名
碳化钨粉;碳化钨(IV)粉末;碳化钨(IV);碳化钨;纳米碳化钨(IV)粉
英文名称
Tungsten carbide
英文别名
methanidylidynetungsten(1+)
纳米碳化钨化学式
CAS
12070-12-1
化学式
WC
mdl
——
分子量
195.85
InChiKey
UONOETXJSWQNOL-UHFFFAOYSA-N
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

物化性质

  • 熔点:
    2870°C
  • 沸点:
    6000°C
  • 密度:
    15,63 g/cm3
  • 溶解度:
    不溶于水;溶于HNO3/HF
  • 暴露限值:
    ACGIH: TWA 3 mg/m3NIOSH: TWA 5 mg/m3; STEL 10 mg/m3
  • 物理描述:
    Tungsten carbide is a gray powder. (NTP, 1992)
  • 颜色/状态:
    Gray hexagonal crystals
  • 蒸汽压力:
    4 mmHg
  • 稳定性/保质期:

    在常温常压下稳定,避免与氧化物接触。该物质能被硝酸氢氟酸的混酸以及王水溶解,但不溶于冷。其相对密度为1.63,耐酸性强。硬度高,弹性模量大。

    它是一种灰色并带有属光泽的粉末,理论结合碳含量约为6.13%(质量分数)。属于六方晶系,具有a=0.2900nm和c=0.2831nm的晶格参数。密度为15.7g/cm³,微维氏硬度(负荷50g)为2080kg/mm²。非常坚硬且弹性模量大(72700kg/mm²)。熔点虽高,记载范围在2600℃至2870℃之间,但由于熔融时会发生分解,所以实际值可能不太准确。沸点为6000℃,不溶于冷,能溶解于硝酸氢氟酸的混合溶液中。

计算性质

  • 辛醇/水分配系数(LogP):
    0.08
  • 重原子数:
    2
  • 可旋转键数:
    0
  • 环数:
    0.0
  • sp3杂化的碳原子比例:
    0.0
  • 拓扑面积:
    0
  • 氢给体数:
    0
  • 氢受体数:
    1

ADMET

毒理性
  • 致癌物分类
国际癌症研究机构致癌物:属和碳化钨
IARC Carcinogenic Agent:Cobalt metal with tungsten carbide
来源:International Agency for Research on Cancer (IARC)
毒理性
  • 致癌物分类
国际癌症研究机构(IARC)致癌物分类:2A组:可能对人类致癌
IARC Carcinogenic Classes:Group 2A: Probably carcinogenic to humans
来源:International Agency for Research on Cancer (IARC)
毒理性
  • 致癌物分类
国际癌症研究机构专著:第86卷:(2006年)硬属中的硫酸钴砷化镓磷化铟五氧化二钒
IARC Monographs:Volume 86: (2006) Cobalt in Hard Metals and Cobalt Sulfate, Gallium Arsenide, Indium Phosphide and Vanadium Pentoxide
来源:International Agency for Research on Cancer (IARC)
毒理性
  • 暴露途径
该物质可以通过吸入被身体吸收。
The substance can be absorbed into the body by inhalation.
来源:ILO-WHO International Chemical Safety Cards (ICSCs)
毒理性
  • 吸入症状
咳嗽。
Cough.
来源:ILO-WHO International Chemical Safety Cards (ICSCs)

安全信息

  • 职业暴露等级:
    D
  • 职业暴露限值:
    TWA: 0.015 mg/m3
  • TSCA:
    Yes
  • 危险等级:
    4.1
  • 危险品标志:
    T
  • 安全说明:
    S22,S24/25
  • 危险类别码:
    R23
  • 海关编码:
    28499020
  • 危险品运输编号:
    UN3178
  • RTECS号:
    YO7250000
  • 包装等级:
    III
  • 危险类别:
    4.1

SDS

SDS:d27193f153bed6430521e6ab4f84753b
查看
Name: Tungsten Carbide 99% Material Safety Data Sheet
Synonym: Tungsten Monocarbide
CAS: 12070-12-1
Section 1 - Chemical Product MSDS Name:Tungsten Carbide 99% Material Safety Data Sheet
Synonym:Tungsten Monocarbide

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
12070-12-1 Tungsten Carbide 99 235-123-0
Hazard Symbols: T
Risk Phrases: 23

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Toxic by inhalation.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 12070-12-1: United Kingdom, WEL - TWA: (listed as tungsten, insoluble compoun 5 mg/m3 TWA (as W) United Kingdom, WEL - STEL: (listed as tungsten, insoluble compounds): 10 mg/m3 STEL (as W) Belgium - TWA: (listed as tungsten, insoluble compounds): 5 mg/m3 (as W) Belgium - STEL: (listed as tungsten, insoluble compounds): 10 mg/ VLE (as W) Malaysia: (listed as tungsten, insoluble compounds): 5 mg/m3 TWA W) Netherlands: (listed as tungsten, insoluble compounds): 5 mg/m3 M (as W) Russia: 6 mg/m3 TWA (as W) Spain: (listed as tungsten, insoluble compounds): 5 mg/m3 VLA-ED W) Spain: (listed as tungsten, insoluble compounds): 10 mg/m3 VLA-EC W) Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: white to off-white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: CW
Molecular Weight: 195.86

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 12070-12-1: YO7250000 LD50/LC50:
Not available.
Carcinogenicity:
Tungsten Carbide - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23 Toxic by inhalation.
Safety Phrases:
S 22 Do not breathe dust.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 12070-12-1: 0
Canada
CAS# 12070-12-1 is listed on Canada's DSL List.
CAS# 12070-12-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 12070-12-1 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

制备方法与用途

根据提供的信息,以下总结了有关碳化钨的一些关键要点:

  1. 制备方法:

  2. 主要用途:

    • 生产各种硬质合
    • 催化剂
    • 工具材料等
  3. 化学性质:

  4. 物理特性:

    • 高硬度、高熔点、良好的耐磨性
    • 密度大(15-16g/cm3)
  5. 安全注意事项:

    • 粉尘具有刺激性和毒性
    • 作业时需佩戴防护装备,避免吸入粉尘
  6. 生产标准:

    • 最高容许浓度为6 mg/m³
    • 在美国可溶性化合物的最高容许浓度为1 mg/m³,不溶性为5 mg/m³
  7. 研究进展:

    • 制备超细碳化钨粉体的研究不断深入
    • 一维纳米结构碳化钨制备技术取得突破
  8. 应用领域:

    • 切削工具、耐磨件等硬质材料
    • 催化剂、催化剂载体
    • 热喷涂材料
    • 高温部件材料等