| 158198-66-4

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 各种混合金属/非金属
• CAS: 158198-66-4
• 化学式: B*H₂
• 分子量: 12.8269
• InChiKey: AIVXPZVQHDMAOO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.13
• 重原子数：
  1.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  氢气 、 diborane(6) 以 gaseous matrix 为溶剂， 生成
  参考文献：
  名称：

  Observation of the weakly bound B(2s2p^2 2D)–H₂ complex by fluorescence depletion spectroscopy

  摘要：

  The fluorescence depletion method is used to observe electronic transitions in weakly bound complexes involving the B atom in the spectral range near the atomic 2s2p2 2D←2s22p 2P transition. The fluorescence depletion spectrum of the BNe C 2Δ, D 2Π←X 2Π transitions is compared with the previously reported fluorescence excitation spectrum [X. Yang, E. Hwang, and P. J. Dagdigian, J. Chem. Phys. 104, 599 (1996)]. This technique has also been employed to detect the corresponding electronic transitions in the B⋅⋅⋅H2 complex which cannot be detected by laser fluorescence excitation.

  DOI：

  10.1063/1.471493