磷酸二辛酯钠盐 | 1560-42-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 中文名称: 磷酸二辛酯钠盐
• 中文别名: 辛基磷酸钠
• 英文名称: sodium dioctyl phosphate
• 英文别名: Dioctylphosphat；phosphoric acid dioctyl ester; sodium salt；dioctyl sodium phosphate；sodium;dioctyl phosphate
• CAS: 1560-42-5
• 化学式: C₁₆H₃₄O₄P*Na
• 分子量: 344.407
• InChiKey: XCPXWEJIDZSUMF-UHFFFAOYSA-M

物化性质

• 熔点：
  >221°C (dec.)
• 溶解度：
  可溶于氯仿（少许）、甲醇（少许）

计算性质

• 辛醇/水分配系数(LogP)：
  2.21
• 重原子数：
  22
• 可旋转键数：
  16
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  58.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  三丁基氯化锡 、 磷酸二辛酯钠盐 以 苯 为溶剂， 生成
  参考文献：
  名称：

  Organotin phosphate esters

  摘要：

  公开号：

  US02630442A1
• 作为产物：
  描述：

  Sodium octyl hydrogen phosphate 、 水 生成 磷酸二辛酯钠盐
  参考文献：
  名称：

  KUROSAKI, TOMIHIRO;NISHIGAWA, NORIO;MATSUNAGA, AKIRA, YUKAGAKU, 39,(1990) N, S. 346-350

  摘要：

  DOI：

文献信息

• [EN] THE USE OF CARBOXYLIC ACID ESTERS AS LUBRICANTS<br/>[FR] UTILISATION D'ESTERS D'ACIDE CARBOXYLIQUE EN TANT QUE LUBRIFIANTS
  申请人：BASF SE

  公开号：WO2014005932A1

  公开（公告）日：2014-01-09

  The presently claimed invention is directed to the use of carboxylic acid esters which are obtained by reacting aliphatic dicarboxylic acids and a mixture of structurally different monoalcohols having 10 carbon atoms as lubricants and a process for their preparation.

  目前所宣称的发明是针对使用由脂肪族二羧酸和具有10个碳原子的结构不同的单醇混合物反应得到的羧酸酯作为润滑剂的，以及它们的制备方法。
• Maleated vegetable oils and derivatives, as self-emulsifying lubricants in metalworking
  申请人：Lange Richard M.

  公开号：US20090209441A1

  公开（公告）日：2009-08-20

  A succinated triglyceride oil derived from maleating triglyceride oil from a plant or land animal is described for use as an emulsifying agent for metalworking fluids. The metalworking fluid would comprise water; as an emulsifier this succinated triglyceride, optionally further reacted with water, Group IA and IIA metals, ammonium hydroxide, various amines, alkanolamines, alkoxylated alkanolamines, and polyamines to form a modified emulsifier; and optionally an oil and other additives.

  一种从植物或陆地动物中制得的马来化甘油三酯油，用作金属加工液的乳化剂。该金属加工液包括水；作为乳化剂的这种琥珀酸酯化甘油，可选择进一步与水、IA和IIA族金属、氢氧化铵、各种胺、烷基胺、烷氧基化烷基胺和多胺反应，形成改性乳化剂；并可选择添加油和其他添加剂。
• Process for producing benzoyl peroxide crystals of a small size
  申请人：WARNER-LAMBERT COMPANY

  公开号：EP0075442A1

  公开（公告）日：1983-03-30

  There is disclosed a process for producing benzoyl peroxide in crystalline form with crystals having a size of up to approximately 10 microns, comprising: forming a first solution comprising benzoyl peroxide and a precipitate-promoting material selected from sulphur-containing aliphatic ethers, long-chain aliphatic and araliphatic ethers, ethylene oxide derivatives, and mixtures thereof; mixing the first solution with a second solution comprising an aqueous solution of a non-toxic and non-reactive dispersant selected from cellulosic derivatives, anionic surfactants, non-ionic surfactants, inorganic colloidal materials, and mixtures thereof; and recovering the benzoyl peroxide in the desired crystalline form. The process may be performed at room temperature and is therefore safe and energy conservative. The resulting benzoyl peroxide crystals are of desirable small size, and are particularly well suited for incorporation into commercial cosmetic and pharmaceutical preparations.

  本发明公开了一种生产结晶状过氧化苯甲酰的工艺，其结晶的尺寸可达约 10 微米，该工艺包括 形成由过氧化苯甲酰和沉淀促进材料组成的第一溶液，沉淀促进材料选自含硫脂肪族醚、长链脂肪族和芳香族醚、环氧乙烷衍生物及其混合物； 将第一种溶液与第二种溶液混合，第二种溶液包含一种无毒、无反应的分散剂水溶液，该分散剂选自纤维素衍生物、阴离子表面活性剂、非离子表面活性剂、无机胶体材料及其混合物；以及 回收所需晶型的过氧化苯甲酰。 该工艺可在室温下进行，因此既安全又节能。所得到的过氧化苯甲酰晶体具有理想的小尺寸，特别适合加入商业化妆品和药物制剂中。
• Oral composition
  申请人：UNILEVER N.V.

  公开号：EP0371542A2

  公开（公告）日：1990-06-06

  The present invention relates to oral compositions such as dentifrices or mouthwashes. By inclusion therein of a shorter chain mono- and dialkylphosphate as surfactant, a mild product is obtained which also has improved anti-caries properties. Preferred are sodium mono- and di-octyl phosphates for use in these compositions.

  本发明涉及口腔组合物，如牙膏或漱口水。 通过在其中加入较短链的单烷基和二烷基磷酸酯作为表面活性剂，可获得一种温和的产品，同时还具有更好的抗龋齿特性。 在这些组合物中，首选单辛基和二辛基磷酸钠。
• Topical composition
  申请人：UNILEVER PLC

  公开号：EP0371802A1

  公开（公告）日：1990-06-06

  A composition suitable for topical application to the skin or hair, comprises: a. a dialkyl or dialkenyl phosphate salt having the structure (1): and b. a branched or unbranched, monoalkyl or monoalkenyl phosphate salt (or mixtures thereof) having the structure (2): where R⁰¹, R⁰² and R⁰³ and are each chosen from branched or unbranched, alkyl or alkenyl groups having an average of from 7 to 9 carbon atoms; X, Y and Z are each chosen from H, alkali metal, ammonium and substituted ammonium counterions; and a, b and c are each chosen from 0 or a value of from 1 to 4; the weight ratio of the monoalkyl or monoalkenyl phosphate salt to the dialkyl or dialkenyl phosphate salt being from 1:1000 to 1:5.

  一种适用于皮肤或头发局部涂抹的组合物，包括 a. 具有（1）结构的二烷基或二烯基磷酸酯盐： 和 b. 具有结构（2）的支链或非支链、单烷基或单烯基磷酸酯盐（或其混合物）： 其中 R⁰¹、R⁰² 和 R⁰³ 和各自选自支链或未支链、平均具有 7 至 9 个碳原子的烷基或烯基； X、Y 和 Z 各选自 H、碱金属、铵和取代铵反离子；以及 a、b 和 c 各选自 0 或 1 至 4； 单烷基或单烯基磷酸酯盐与二烷基或二烯基磷酸酯盐的重量比为 1:1000 至 1:5。