| 1597616-55-1

• CAS: 1597616-55-1
• 化学式: C₄₄H₂₆Cl₃CoN₄
• 分子量: 776.069
• InChiKey: DKRQFCOSWSXICF-PEZVUUMASA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  盐酸 、 cobalt(II) acetate 、 5,15-bis-(4-chlorophenyl)-10,20-diphenyl-porphyrin 以 N,N-二甲基甲酰胺 、 水 为溶剂， 反应 4.5h， 以98%的产率得到
  参考文献：
  名称：

  Catalytic oxidation of cyclohexane with dioxygen over boehmite supported trans-A2B2 type metalloporphyrins catalyst

  摘要：

  Metalloporphyrin-catalysed direct functionalization of saturated C H bonds is one among the topical and challenging areas within the chemical industry. In this work, three types of unsupported and boehmite supported trans-A(2)B(2)-metalloporphyrin chloride complexes (Co-D(p-Cl)PPCl, Fe-D(p-Cl)PPCl, Mn-D(p-Cl)PPCl) were prepared and characterized. It has been found that these trans-A(2)B(2)-metalloporphyrins have high catalytic activity in cyclohexane oxidation under dioxygen. The boehmite supported metalloporphyrins show better catalytic performance and are more stable than unsupported metalloporphyrins. Among these supported metalloporphyrin catalysts, Co-D(p-Cl)PPCl/BM was better than Fe-D(p-Cl)PPCl/BM and Mn-D(p-CI)PPCl/BM, the cyclohexane conversion and selectivity to KA oil are 6.83% and 83.30%, respectively, and the turnover number is 1.05 Chi 10(7). The Co-D(p-Cl)PPCl/BM catalyst can be facilely recovered and was recycled up to six times without significant decrease in catalytic performance. (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2014.02.002
• 作为试剂：
  描述：

  环己烷 在 C₄₄H₂₆Cl₃CoN₄ 、 氧气 作用下， 以 乙腈 为溶剂， 155.0 ℃ 、2.0 MPa 条件下， 反应 2.0h， 生成 戊二酸 、 己二酸 、 丁二酸 、 环己酮 、 环己醇
  参考文献：
  名称：

  Catalytic oxidation of cyclohexane with dioxygen over boehmite supported trans-A2B2 type metalloporphyrins catalyst

  摘要：

  Metalloporphyrin-catalysed direct functionalization of saturated C H bonds is one among the topical and challenging areas within the chemical industry. In this work, three types of unsupported and boehmite supported trans-A(2)B(2)-metalloporphyrin chloride complexes (Co-D(p-Cl)PPCl, Fe-D(p-Cl)PPCl, Mn-D(p-Cl)PPCl) were prepared and characterized. It has been found that these trans-A(2)B(2)-metalloporphyrins have high catalytic activity in cyclohexane oxidation under dioxygen. The boehmite supported metalloporphyrins show better catalytic performance and are more stable than unsupported metalloporphyrins. Among these supported metalloporphyrin catalysts, Co-D(p-Cl)PPCl/BM was better than Fe-D(p-Cl)PPCl/BM and Mn-D(p-CI)PPCl/BM, the cyclohexane conversion and selectivity to KA oil are 6.83% and 83.30%, respectively, and the turnover number is 1.05 Chi 10(7). The Co-D(p-Cl)PPCl/BM catalyst can be facilely recovered and was recycled up to six times without significant decrease in catalytic performance. (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2014.02.002