[Sm(bis(trifluoromethanesulfonyl)amido)3(H2O)3] | 861436-87-5

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 后过渡金属氧阴离子化合物
• 英文名称: [Sm(bis(trifluoromethanesulfonyl)amido)3(H2O)3]
• CAS: 861436-87-5
• 化学式: C₆H₆F₁₈N₃O₁₅S₆Sm
• 分子量: 1044.85
• InChiKey: HATQPRCPBLPIJO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  samarium(III) oxide 、 水 、 双三氟甲烷磺酰亚胺 以 水 为溶剂， 生成 [Sm(bis(trifluoromethanesulfonyl)amido)3(H2O)3]
  参考文献：
  名称：

  Structural Characterization of a Lanthanum Bistriflimide Complex, La(N(SO₂CF₃)₂)₃(H₂O)₃, and an Investigation of La, Sm, and Eu Electrochemistry in a Room-Temperature Ionic Liquid, [Me₃NⁿBu][N(SO₂CF₃)₂]

  摘要：

  The reduction of selected lanthanide cations to the zerovalent state in the room-temperature ionic liquid [(Me3NBu)-Bu-n][TFSI] is reported (where TFSI = bistriflimide, [N(SO2CF3)(2)](-)). The lanthanide cations were introduced to the melt as the TFSl hydrate complexes [Ln(TFSI)(3)(H2O)(3)] (where Ln = La-III, Sm-II or Eu-III). The lanthanum compound [La(TFSl)(3)(H2O)(3)] has been crystallographically characterized, revealing the first structurally characterized f-element TFSl complex. The lanthanide in all three complexes was shown to be reducible to the metallic state in [(Me3NBu)-Bu-n][TFSI]. For both the Eu and Sm complexes, reduction to the metallic state was achieved via divalent species, and there was an additional observation of the electrodeposition of Eu metal.

  DOI：

  10.1021/ic048199u