(μ-ortho-semidinato)Fe2(CO)6 | 18716-94-4

• 英文名称: (μ-ortho-semidinato)Fe2(CO)6
• CAS: 18716-94-4
• 化学式: C₁₈H₁₀Fe₂N₂O₆
• 分子量: 461.981
• InChiKey: VUHGFUBCZMUQFC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis(N-phenyl-o-semiquinonediimine)platinum(II) 、 iron pentacarbonyl 以 苯 为溶剂， 以40%的产率得到(μ-ortho-semidinato)Fe2(CO)6
  参考文献：
  名称：

  摘要：

  The reactions of o-semiquinonediimine complexes M[o-(NH)(NPh)C6H4]2 (M = Ni (1) or Pt (2)) with carbonyl-containing iron and rhenium compounds were studied. The reactions of complexes 1 or 2 with Fc(CO)(5) afforded the Fe-2(CO)(6)[mu-(NH)(NPh)C6H4] complex (3) containing the bridging N-phenyl-o-phenylenediamide ligand in high yield. The reaction of the Re(CO)(2)(NO)Cl-2(thf) complex with complex 2 gave rise to the unusual mononuclear rhenium(III) complex, viz., Re(Ph)[sigma-eta (1)-o-(NH)(NHPh)C6H4](CO)(NO)Cl-2 (4), no changes in the geometry of N-phenyl-o-phenylenediamine bound to the Re(NO)(CO)(2)Cl-2 fragment being observed. The reaction of complex 2 with the Re(CO)(5)Cl complex, which has been preliminarily treated with silver triflate, afforded the heterometallic complex (CO)Pt[mu -N,N-o-(N)(NPh)C6H4](2)ReCl[(NH)(NPh)C6H4]. The structures of the resulting complexes were established by X-ray diffraction analysis.

  DOI：

  10.1023/a:1009549807222

文献信息

• Cluster chemistry
  作者：Michael I. Bruce、Mark G. Humphrey、Omar bin Shawkataly、Michael R. Snow、Edward R.T. Tiekink

  DOI：10.1016/0022-328x(87)87169-3

  日期：1987.12

  measurements: an Ru3 triangle with a non-bonded Ru…Ru vector is capped on both sides by a μ3-arylimido moiety. Electron transfer-catalysed reactions with isocyanides, tertiary phosphines and phosphites proceed to give CO-substituted products in moderate yields: complexes Ru3(μ3- NPh)2(CO)8(L) (L = CNC6H3Me2-2,6 (15), PPh3 (16), P(OMe)3), Ru3(μ3- NPh)2(CO)8}2(μ-(PPh2)2C2) and Ru3(μ3-NPh)2(μ-LL)(CO)7 (LL = dppm

  Azoarenes，ArNNAr'，与反应的Ru 3（CO）12，得到的Ru 3（μ 3 -NAr）（μ 3 - NAR'）（CO）9（AR = PH，中，Ar'=苯基，C 6 H ^ 4 Me-3，C 6 H 4 CF 3 -3，C 6 H 4 F-3（11），C 6 H 4 F-4； Ar ＝ Ar'＝ C 6 H 4 Me-3）；产率中等。作为Ar =氩'=苯基或C 6 H ^ 4 ME-3，单核环金属化的Ru（C 6 H ^ 3 RNNC 6 ħ 4还以低收率获得R-3）2（CO）2（R ＝ H或Me）。的Fe 3（CO）12和偶氮苯得到的Fe 3（μ 3 -NPh）2（CO）9以非常低的产率。的X射线研究11所确认的结构分配的光谱测量的基础上作出的：的Ru 3三角形与一非粘合茹...孺矢量由μ封端的两侧3 -arylimido部分。与异氰化物，叔膦和亚磷酸酯的电子转移催化的反
• Kisch, Horst; Reisser, Peter; Knoch, Falk, Chemische Berichte, 1991, vol. 124, # 5, p. 1143 - 1148
  作者：Kisch, Horst、Reisser, Peter、Knoch, Falk

  DOI：——

  日期：——