phosphoric acid decyl ester-diphenyl ester | 14167-87-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: phosphoric acid decyl ester-diphenyl ester
• 英文别名: Phosphorsaeure-decylester-diphenylester；Decyl diphenyl phosphate
• CAS: 14167-87-4
• 化学式: C₂₂H₃₁O₄P
• 分子量: 390.459
• InChiKey: UZJUEEROTUVKNS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.6
• 重原子数：
  27
• 可旋转键数：
  14
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  癸醇 在 三氯氧磷 作用下， 生成 phosphoric acid decyl ester-diphenyl ester
  参考文献：
  名称：

  烷基芳基磷酸盐的化学和物理性质

  摘要：

  DOI：

  10.1021/ie50529a062

文献信息

• Transition metal-catalyzed substitution reaction of allylic phosphates with Grignard reagents
  作者：Akira Yanagisawa、Nobuyoshi Nomura、Hisashi Yamamoto

  DOI：10.1016/s0040-4020(01)90454-5

  日期：1994.1

  SN2-selective Grignard coupling with primary allylic diphenylphosphates was successfully achieved using Ni or Fe catalyst. In sharp contrast, a catalytic amount of CuCN·2LiCl promoted a SN2′-selective coupling reaction. In the presence of the copper catalyst, stereochemically homogeneous γ- disubstituted allyl Grignard reagents reacted at the less substituted allylic terminus (α-position) with an allylic diphenylphosphate

  使用Ni或Fe催化剂成功地实现了S N 2-选择性格利雅（Grignard）与伯烯丙基二苯基磷酸酯的偶联。与之形成鲜明对比的是，催化量的CuCN·2LiCl促进了S N 2'-选择性偶联反应。在铜催化剂的存在下，立体化学均一的γ-二取代的烯丙基格氏试剂在较少取代的烯丙基末端（α-位）与烯丙基磷酸二苯酯选择性地反应，而不会失去双键的几何形状。
• Selective Hydrogenation Catalyst and Methods of Making and Using Same
  申请人：Cheung Tin-Tack Peter

  公开号：US20100228065A1

  公开（公告）日：2010-09-09

  A composition comprising a supported hydrogenation catalyst comprising palladium and an organophosphorous compound, the supported hydrogenation catalyst being capable of selectively hydrogenating highly unsaturated hydrocarbons to unsaturated hydrocarbons. A method of making a selective hydrogenation catalyst comprising contacting a support with a palladium-containing compound to form a palladium supported composition, contacting the palladium supported composition with an organophosphorus compound to form a catalyst precursor, and reducing the catalyst precursor to form the catalyst. A method of selectively hydrogenating highly unsaturated hydrocarbons to an unsaturated hydrocarbon enriched composition comprising contacting a supported catalyst comprising palladium and an organophosphorous compound with a feed comprising highly unsaturated hydrocarbon under conditions suitable for hydrogenating at least a portion of the highly unsaturated hydrocarbon feed to form the unsaturated hydrocarbon enriched composition.

  一种包括支持的氢化催化剂的组合物，其中氢化催化剂包括钯和有机磷化合物，支持的氢化催化剂能够选择性地将高度不饱和烃氢化为不饱和烃。一种制备选择性氢化催化剂的方法，包括将支持物与含钯化合物接触以形成支持的钯组合物，将支持的钯组合物与有机磷化合物接触以形成催化剂前体，并还原催化剂前体以形成催化剂。一种将高度不饱和烃选择性氢化为富含不饱和烃的组合物的方法，包括将包括钯和有机磷化合物的支持催化剂与含高度不饱和烃的进料接触，在适宜的氢化条件下至少部分氢化高度不饱和烃进料以形成富含不饱和烃的组合物。
• Mould-release compositions
  申请人：IMPERIAL CHEMICAL INDUSTRIES PLC

  公开号：EP0460858A1

  公开（公告）日：1991-12-11

  Composition comprising a neutral ester of a specific orthophosphoric acid and a mineral wax. The composition may be used as an external mould release agent or may be used together with a polyisocyanate, especially for binding of ligno-cellulosic material.

  由特定正磷酸的中性酯和矿物蜡组成的组合物。该组合物可用作外部脱模剂，也可与聚异氰酸酯一起使用，特别是用于粘合木质纤维素材料。
• Stabilized chlorinated resin composition
  申请人：ASAHI DENKA KOGYO KABUSHIKI KAISHA

  公开号：EP0483400A1

  公开（公告）日：1992-05-06

  A stabilizer for a rigid chlorinated resin comprising a hydrotalcite compound and an inorganic copper compound and a stabilized rigid chlorinated resin composition obtained by adding said stabilizer to a chlorinated resin.

  一种用于硬质氯化树脂的稳定剂，由一种氢铝酸盐化合物和一种无机铜化合物组成，以及一种通过将所述稳定剂添加到氯化树脂中而获得的稳定硬质氯化树脂组合物。
• Plastisol compositions
  申请人：SARTOMER COMPANY, INC.

  公开号：EP0534847A1

  公开（公告）日：1993-03-31

  Free radical-curable compositions comprising a plastisol component and a copolymer containing free anhydride functionality and, optionally, other reactive diluents are provided. In particular, curable compositions employing a plastisol, preferably a polyvinyl chloride - containing plastisol, and a low molecular weight crosslinking copolymer component having free anhydride functionality and which is a partial esterification product of a terminally ethylenically unsaturated compound and a polymerizable maleic anhydride are provided. The compositions of the invention yield improved adhesives, sealants, coatings, and insulators for a wide variety of substrates and may be employed in a variety of coating and castings. Processes for preparing cured plastisol compositions from the disclosed free radical-curable compositions are also provided.

  本发明提供了自由基固化组合物，该组合物由塑溶胶组分和含有游离酸酐官能团的共聚物以及可选的其他反应性稀释剂组成。特别是提供了采用塑溶胶（最好是含有聚氯乙烯的塑溶胶）和具有游离酸酐官能团的低分子量交联共聚物组分的可固化组合物，后者是烷基乙烯基不饱和化合物和可聚合马来酸酐的部分酯化产物。本发明的组合物可改善粘合剂、密封剂、涂层和绝缘体的性能，适用于各种基材，并可用于各种涂层和铸件。本发明还提供了利用所公开的自由基固化组合物制备固化增塑溶胶组合物的工艺。