phosphorofluoridic acid dihexyl ester | 1841-39-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: phosphorofluoridic acid dihexyl ester
• 英文别名: fluorophosphoric acid dihexyl ester；Fluorophosphorsaeure-dihexylester；Dihexylphosphorfluoridat；1-[Fluoro(hexoxy)phosphoryl]oxyhexane
• CAS: 1841-39-0
• 化学式: C₁₂H₂₆FO₃P
• 分子量: 268.309
• InChiKey: YKCQMDXVSXGSMI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  17
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  dihexyl phosphonate 在 1,3-dichlorodimethylhydantoin-KF 作用下， 以 乙腈 为溶剂， 反应 0.58h， 以93%的产率得到phosphorofluoridic acid dihexyl ester
  参考文献：
  名称：

  Dichlorodimethylhydantoin–KF as an efficient reagent for one pot synthesis of dialkylfluorophosphates from dialkylphosphites

  摘要：

  Organic-inorganic hybrid reagent dichlorodimethylhydantoin - KF (DCDMH - KF) mixture was explored as an efficient reagent for the direct conversion of dialkylphosphites to their corresponding dialkylfluorophosphates at room temperature and in shorter reaction times through a facile electrophilic - nucleophilic metathesis. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jfluchem.2007.11.008

文献信息

• Schrader, Angewandte Chemie, 1952, vol. 62, p. 21,24
  作者：Schrader

  DOI：——

  日期：——
• Dichlorodimethylhydantoin–KF as an efficient reagent for one pot synthesis of dialkylfluorophosphates from dialkylphosphites
  作者：A.K. Gupta、J. Acharya、D.K. Dubey、M.P. Kaushik

  DOI：10.1016/j.jfluchem.2007.11.008

  日期：2008.3

  Organic-inorganic hybrid reagent dichlorodimethylhydantoin - KF (DCDMH - KF) mixture was explored as an efficient reagent for the direct conversion of dialkylphosphites to their corresponding dialkylfluorophosphates at room temperature and in shorter reaction times through a facile electrophilic - nucleophilic metathesis. (c) 2007 Elsevier B.V. All rights reserved.