2-hydroxyphenyl diphenyl phosphate | 138079-34-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: 2-hydroxyphenyl diphenyl phosphate
• 英文别名: (2-hydroxyphenyl) diphenyl phosphate
• CAS: 138079-34-2
• 化学式: C₁₈H₁₅O₅P
• 分子量: 342.288
• InChiKey: SGXRTWRRYSEZLP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  24
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  65
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  磷酸三苯酯 在 lithium diisopropyl amide 作用下， 以 四氢呋喃 、 水 为溶剂， 以75%的产率得到2-hydroxyphenyl diphenyl phosphate
  参考文献：
  名称：

  带有（杂-）芳烃和[3]二茂铁基的二茂铁磷酸酯对阴离子磷酸酯重排的反应性

  摘要：

  阴离子磷酸弗里斯重排内的温度依赖行为的P（apFr）（O）（OFC）Ñ（EAR）3- Ñ（FC =铁（η 5 -C 5 H ^ 5）（η 5 -C 5 H ^ 4）; E = O; Ar =苯基，萘基，（R）-BINOL，[3]二茂铁酰基; E = N，1 H-吡咯基，1 H-吲哚基，9 H-咔唑基; n = 1-3） 。当Fc经历一次时，基于Ph的apFr取决于温度。首先，芳基被锂化和重排，然后是Fc和N-杂环。我2 SO 4的加法因此得到甲基化的Fc，这与非有机金属芳族化合物形成HO和MeO衍生物的混合物相反。（R）-BINOL Fc磷酸酯以91％de得到Fc重排的膦酸酯。由于P处的电子密度较高，用N-脂族化合物交换O-阻止了apFr。还观察到1,2-N→C迁移。X射线分析证实了OH和NH衍生物的一维H桥键。通过电化学证实了N-脂族和N-芳族氨基磷酸酯之间反应性的差异。氧化还原电位显示

  DOI：

  10.1021/acs.joc.7b00030

文献信息

• RESIN COMPOSITION, CURED PRODUCT THEREOF, FIBRE-REINFORCED PLASTIC, AND FIBRE-REINFORCED PLASTIC FLAMEPROOFING METHOD
  申请人：ADEKA CORPORATION

  公开号：US20210163733A1

  公开（公告）日：2021-06-03

  Provided is a resin composition that is capable of producing a cured product having excellent environmental suitability, high strength, and excellent flame retardancy, and that is suitably usable as a matrix resin for fiber-reinforced plastics. A resin composition contains (A) an epoxy resin, (B) a cyanate resin, (C) an aromatic amine curing agent that is liquid at 25° C., and (D) a phosphorus-containing compound represented by formula (1). Preferably, in formula (1), R 1 and R 2 each independently represent an alkyl group or an aryl group, and X and Y are an oxygen atom.

  提供的是一种树脂组成物，能够产生具有优良环境适应性、高强度和优异阻燃性的固化产品，适合用作纤维增强塑料的基体树脂。该树脂组成物包含（A）环氧树脂，（B）氰酸酯树脂，（C）在25℃下为液态的芳香胺固化剂，以及（D）由公式（1）表示的含磷化合物。在公式（1）中，最好是R1和R2各自独立地表示烷基或芳基，而X和Y则是氧原子。
• STYRENE-BASED RESIN COMPOSITION, AND RESIN MOLDED ARTICLE COMPRISING SAME
  申请人：Fujisawa Tomoyuki

  公开号：US20130012646A1

  公开（公告）日：2013-01-10

  Disclosed is a styrene-based resin composition that comprises 5-20 parts by mass of (D) a fire retardant per 100 parts by mass of a resin composition (1) that comprises 30-51 mass % of (A) a graft copolymer obtained by graft polymerization of a diene rubber polymer with an aromatic vinyl monomer and an unsaturated nitrile monomer, 10-55 mass % of (B) a copolymer comprising two or more monomers selected from among aromatic vinyl monomers, unsaturated nitrile monomers and unsaturated carboxylic acid alkyl ester monomers, and 15 to 39% by mass of a copolymer (C) comprising one kind of unsaturated carboxylic acid alkyl ester monomers, or two or more unsaturated carboxylic acid alkyl ester monomers, ((A)+(B)+(C)=100 mass %), wherein the diene rubber polymer constitutes 15-25 mass % of the resin composition (1).

  本发明公开了一种苯乙烯基树脂组合物，其中每100份树脂组合物（1）包含5-20份质量份（D）阻燃剂，该树脂组合物（1）包含30-51质量%（A）通过将二烯基橡胶聚合物与芳香族乙烯单体和不饱和腈单体进行接枝聚合得到的接枝共聚物，10-55质量%（B）包含两种或两种以上从芳香族乙烯单体、不饱和腈单体和不饱和羧酸烷基酯单体中选择的单体的共聚物，以及15-39质量%的共聚物（C），其包含一种或两种以上的不饱和羧酸烷基酯单体，（（A）+（B）+（C）=100质量%），其中，二烯基橡胶聚合物占树脂组合物（1）的15-25质量%。
• HIGH-PRECISION MECHANICAL PARTS MADE FROM FLAME-RETARDANT RESIN FOR OFFICE AUTOMATION EQUIPMENT
  申请人：Asahi Kasei Kogyo Kabushiki Kaisha

  公开号：EP0754531A1

  公开（公告）日：1997-01-22

  Disclosed is a flame retardant, high precision resin mechanical part for use in office automation machines required to function with high accuracy and high precision, which is made by injection molding a thermoplastic resin composition comprising: (A) an amorphous thermoplastic resin; (B) an inorganic filler in a scale form; and (C) a specific phosphoric acid ester in which phosphoric acid ester groups are bonded through a bisphenol. The high precision resin mechanical part of the present invention is free from conventionally experienced disadvantages, such as volatilization of a flame retardant contained in the resin, smoking caused by the volatilization of the flame retardant and occurrence of MD (mold deposit) during the production thereof by molding, and bleeding of the flame retardant during the use thereof. Further, the mechanical part of the present invention is unlikely to suffer from warpage, and has advantageously small shrinkage ratio during the production thereof by molding. The mechanical part of the present invention has also not only high precision but also various excellent mechanical properties, such as extremely low anisotropy in linear expansion coefficient, and excellent vibration characteristics. The high precision resin mechanical part of the present invention can be advantageously used as a mechanical part for high precision machines which are required to function with high accuracy and high precision even under various stringent conditions, such as computers, game machines, sound-reproducing systems, audio-visual machines, copiers, printers, facsimile machines, personal computers, word processors, portable communication apparatuses and composite machines composed thereof.

  本发明公开了一种阻燃高精度树脂机械零件，用于要求高精度和高准确度的办公自动化机器，该零件是通过注塑成型热塑性树脂组合物制成的，该组合物包括：(A) 无定形热塑性树脂；(B) 鳞片状无机填料；以及 (C) 特定磷酸酯，其中磷酸酯基通过双酚键合。本发明的高精密树脂机械零件不存在传统的缺点，例如树脂中含有的阻燃剂挥发、阻燃剂挥发导致的冒烟和通过模塑生产过程中出现的 MD（模具沉积物），以及使用过程中阻燃剂的渗出。此外，本发明的机械部件不易发生翘曲，而且在模塑生产过程中具有收缩率小的优势。本发明的机械部件不仅精度高，而且还具有各种优异的机械性能，例如极低的线膨胀系数各向异性和优异的振动特性。本发明的高精度树脂机械零件可作为高精度机器的机械零件使用，这些机器即使在各种苛刻的条件下也要求高精度和高准确度，例如计算机、游戏机、音响系统、视听机器、复印机、打印机、传真机、个人计算机、文字处理机、便携式通信设备以及由它们组成的复合机器。
• MODIFIED CYCLOOLEFIN ADDITION POLYMER AND CURABLE RESIN COMPOSITION CONTAINING THE SAME
  申请人：NIPPON ZEON CO., LTD.

  公开号：EP0997482A1

  公开（公告）日：2000-05-03

  A curable resin composition comprising a modified cycloolefin addition polymer (A) obtained by introducing a functional group into a cycloolefin addition polymer containing a repeating unit (a) derived from a cycloolefin monomer having an organic group having at least 4 carbon atoms at its side chain at a rate of introduction of the functional group of 0.1 to 50 mol% based on the whole repeating unit of the cycloolefin addition polymer, and a hardening agent (B), and a modified cycloolefin addition polymer (A) obtained by introducing a functional group into a cycloolefin addition polymer containing a repeating unit (a) derived from a cycloolefin monomer having an organic group having at least 4 carbon atoms at its side chain at a rate of introduction of the functional group of 0.1 to 50 mol% based on the whole repeating unit of the cycloolefin addition polymer, and having a weight average molecular weight (Mw) of 1,000 to 1,000,000.

  一种可固化的树脂组合物，它包括一种改性环烯烃加成聚合物 (A)，该改性环烯烃加成聚合物是通过向环烯烃加成聚合物中引入官能团而获得的，环烯烃加成聚合物含有一个重复单元 (a)，该重复单元来源于环烯烃单体，该环烯烃单体具有一个有机基团，该有机基团在其侧链上至少有 4 个碳原子，官能团的引入率为 0.1 至 50 摩尔%（以环烯烃加成聚合物的整个重复单元为基数）的环烯烃加成聚合物和硬化剂 (B)，以及一种改性环烯烃加成聚合物 (A)，该改性环烯烃加成聚合物是通过在环烯烃加成聚合物中引入一个官能团而获得的，该环烯烃加成聚合物含有从环烯烃单体衍生而来的重复单元 (a)，该环烯烃单体在其侧链上具有至少 4 个碳原子的有机基团，官能团的引入率为 0.1至50摩尔％，且其重量平均分子量(Mw)为1,000至1,000,000。
• Flame retardant resin composition
  申请人：Asahi Kasei Kabushiki Kaisha

  公开号：EP1302510A1

  公开（公告）日：2003-04-16

  Disclosed is a flame retardant resin composition comprising: 100 parts by weight of a resin component (A) which is a resin mixture of an aromatic polycarbonate and a styrene polymer, wherein the resin mixture has an aromatic polycarbonate content of from 50 to 95 % by weight and a styrene polymer content of from 5 to 50 % by weight; 0.1 to 30 parts by weight of an organopolysiloxane (B) which comprises 0 to 70 mol% of a monofunctional siloxane unit (M unit), 0 to 100 mol% of a bifunctional recurring siloxane unit (D unit), 0 to 100 mol% of a trifunctional recurring siloxane unit (T unit), and 0 to 63 mol% of a tetrafunctional recurring siloxane unit (Q unit); and 0.0005 to 5 parts by weight of at least one inorganic metal salt (C) selected from the group consisting of inorganic alkali metal salts and inorganic alkaline earth metal salts.

  公开了一种阻燃树脂组合物，它包括100 份（重量）的树脂组分 (A)，它是芳香族聚碳酸酯和苯乙烯聚合物的树脂混合物，其中该树脂混合物的芳香族聚碳酸酯含量为 50% 至 95%（重量），苯乙烯聚合物含量为 5%至 50%（重量）； 0.1 至 30 份（重量）的有机聚硅氧烷 (B)，其中包括 0 至 70 摩尔％的单官能度硅氧烷单元 (M单元)、0 至 100 摩尔％的双官能度循环硅氧烷单元 (D单元)、0 至 100 摩尔％的三官能度循环硅氧烷单元 (T单元)和 0 至 63 摩尔％的四官能度循环硅氧烷单元 (Q单元)；以及 0.0005至5份重量的至少一种无机金属盐(C)，选自无机碱金属盐和无机碱土金属盐组成的组。