N-ethyl-N-methylpyrrolidiniumdiethyl phosphate | 1199623-28-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: N-ethyl-N-methylpyrrolidiniumdiethyl phosphate
• 英文别名: 1-ethyl-1-methylpyrrolidinium diethyl phosphate；[C2mpyr][DEP]；N,N-ethylmethylpyrrolidinium diethylphosphate；Diethyl phosphate;1-ethyl-1-methylpyrrolidin-1-ium
• CAS: 1199623-28-3
• 化学式: C₄H₁₀O₄P*C₇H₁₆N
• 分子量: 267.305
• InChiKey: MMXQIIYOECXDFR-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.77
• 重原子数：
  17
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  58.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1-甲基吡咯烷 、 磷酸三乙酯 反应 51.0h， 以76.25%的产率得到N-ethyl-N-methylpyrrolidiniumdiethyl phosphate
  参考文献：
  名称：

  {磷酸二乙酯基离子液体 (1) + 乙醇 (2)} 系统的热力学性质、实验数据和相关性

  摘要：

  在这项工作中，由离子液体和乙醇组成的三种溶液被考虑用于吸收式制冷技术的前瞻性应用。建议使用以下离子液体作为吸收剂：1-乙基-3-甲基咪唑二乙基磷酸盐（缩写为[EMIM][DEP]）、4-乙基-4-甲基吗啉二乙基磷酸盐（[EMMOR][DEP]）、和 1-乙基-1-甲基-吡咯烷鎓磷酸二乙酯 ([EMPYR][DEP])。由于工作流体的热力学和物理化学性质决定了制冷机在寻找替代工作流体时的效率，因此发挥其广泛特性至关重要。因此，在这项工作中，（蒸汽 + 液体）相平衡 (VLE)、液体密度 (ρ)、测定了上述三种磷酸二乙酯基离子液体的乙醇溶液和动态粘度 (η)。等温 VLE 通过沸腾法测量，温度范围为T = (328.15 至 348.15) K，增量为 10 K，压力高达 90 kPa。具有温度相关参数的非随机二液 (NRTL) 方程用于关联实验数据。包括液体密度和动态粘度在内的物理化学性质是在

  DOI：

  10.1021/acs.jced.1c00924

文献信息

• Method of Purifying Olefins Using Pyrrolidinium-Based or Piperidinium-Based Ionic Liquids Comprising Copper (I) Halide
  申请人：AHN Byoung Sung

  公开号：US20110092758A1

  公开（公告）日：2011-04-21

  The present invention relates to a method of purifying olefin, the method comprising removing a small amount of acetylenic compounds contained in olefin by using pyrrolidinium-based or piperidinium-based ionic liquid mixtures comprising copper (I) halide. According to the method of the present invention, copper (I) halide is stabilized by pyrrolidinium-based or piperidinium-based ionic liquids, suppressing the oxidation of Cu(I) into Cu(II), whereby the capacity of removing acetylenic compounds can be maintained for a long time and the selective removal rate of acetylenic compounds to olefin can be significantly improved. In addition, since the ionic liquid mixtures comprising copper (I) halide used in the method of the present invention can be applied to both absorption and extraction processes, it can effectively remove acetylenic compounds from olefin in a more simple and economical way compared to the existing adsorption and membrane separation processes.

  本发明涉及一种精制烯烃的方法，该方法包括使用含有铜（I）卤化物的吡咯烷鎓基或哌啶鎓基离子液体混合物去除烯烃中含有的少量炔烃。根据本发明的方法，铜（I）卤化物通过吡咯烷鎓基或哌啶鎓基离子液体得到稳定，从而抑制Cu(I)氧化成Cu(II)，使得去除炔烃的能力可以长时间维持，并且显著提高烯烃中炔烃的选择性去除率。另外，由于本发明方法中使用的含有铜（I）卤化物的离子液体混合物既适用于吸收过程也适用于提取过程，因此与现有的吸附和膜分离过程相比，可以以更简单和经济的方式有效地从烯烃中去除炔烃。
• Exothermic and thermal runaway behaviour of some ionic liquids at elevated temperatures
  作者：R. Vijayaraghavan、M. Surianarayanan、V. Armel、D. R. MacFarlane、V. P. Sridhar

  DOI：10.1039/b911568d

  日期：——

  The exothermic behaviour and intrinsic safety of a number of ionic liquids being considered for battery and solar cell applications have been investigated at elevated temperatures by analysing data from accelerated rate calorimetric (ARC) studies.

  通过分析加速速率量热法（ARC）研究的数据，研究了电池和太阳能电池应用中考虑使用的一些离子液体在高温下的放热行为和内在安全性。
• Probing the Physical Properties, Synthesis and Cellulose Dissolution Ability of Dialkyl Phosphate Ionic Liquids
  作者：Sharon I. Lall-Ramnarine、Marie F. Thomas、Mariyam Jalees、Firmause Payen、Samanta Boursiquot、Sharon Ramati、Damian Ewko、Nicole V. Zmich、James F. Wishart

  DOI：10.1080/10426507.2014.985824

  日期：2015.6.3

  We report the synthesis, characterization and cellulose dissolution properties of a series of ionic liquids bearing alkyl and hydroxyl-functionalized imidazolium and pyrrolidinium cations, and dialkyl phosphate anions. Ionic liquids that dissolve cellulose have anions that are excellent hydrogen bond acceptors. Based on this study, it is clear that the cation also plays a role. Cellulose dissolution was achieved in the imidazolium ionic liquids but not in the pyrrolidinium ionic liquids. Thermogravimetric analysis results show that most of the ILs are thermally stable up to 240 degrees C and thus are more suitable solvents for high temperature applications than most organic solvents. Imidazolium ILs are less viscous and slightly more thermally stable than the pyrrolidinium ILs of the same chain length.
• VERFAHREN UND VORRICHTUNG ZUM BETRIEB EINES DAMPFKREISPROZESSES MIT GESCHMIERTEM EXPANDER
  申请人：MAN Truck & Bus AG

  公开号：EP2577003A2

  公开（公告）日：2013-04-10
• Method and Apparatus for Operating a Steam Cycle Process with a Lubricated Expander
  申请人：Almbauer Raimund

  公开号：US20130263598A1

  公开（公告）日：2013-10-10

  Embodiments of the invention relate to a method for operating a steam cycle process performed in an apparatus having an evaporator or steam generator for the evaporation of a liquid working medium and an expander, which is lubricated by a lubricant, for the performance of mechanical work. The method comprises a) supplying the liquid working medium to the evaporator, in which it evaporates and is fed to the expander in the form of steam; b) supplying an ionic liquid, which at room temperature forms two liquid phases with the liquid working medium, to the expander as a lubricant; and c) separating the ionic liquid forming the lubricant for the expander from the working medium upstream of the evaporator.