di-n-propyl fluorophosphate | 381-45-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: di-n-propyl fluorophosphate
• 英文别名: Dipropyl-fluorophosphat；phosphorofluoridic acid dipropyl ester；fluorophosphoric acid dipropyl ester；Fluorophosphorsaeure-dipropylester；Phosphorsaeure-dipropylester-fluorid；Phosphorofluoridic acid, dipropyl ester；1-[fluoro(propoxy)phosphoryl]oxypropane
• CAS: 381-45-3
• 化学式: C₆H₁₄FO₃P
• 分子量: 184.148
• InChiKey: CLKGIOYRLWWQNR-UHFFFAOYSA-N

物化性质

• 沸点：
  98-100 °C(Press: 20 Torr)
• 密度：
  1.083 g/cm3(Temp: 18 °C)

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  11
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  氯磷酸二正丙基酯 在 potassium fluoride 、 苯 作用下， 生成 di-n-propyl fluorophosphate
  参考文献：
  名称：

  Bany, Bulletin International de l'Academie Polonaise des Sciences et des Lettres, Classe des Sciences Mathematiques et Naturelles, Serie A: Sciences Mathematiques, 1951, p. 1,10,19

  摘要：

  DOI：

文献信息

• Fluorination of phosphorus(+3) derivatives by xenon difluoride
  作者：S.A. Lermontov、A.V. Popov、S.I. Zavorin、I.I. Sukhojenko、N.V. Kuryleva、I.V. Martynov、N.S. Zefirov、P. Stang

  DOI：10.1016/0022-1139(93)02910-7

  日期：1994.3

  Xenon difluoride, XeF2, effectively fluorinates various phosphorous acid derivatives as well as hydrophosphoryl compounds. Arbuzov rearrangement is followed by i-Bu → t-Bu isomerization in the case of i-Bu OPF2.

  二氟化氙XeF 2有效地氟化了各种亚磷酸衍生物以及氢磷酰基化合物。在i-Bu OPF 2的情况下，Arbuzov重排后是i-Bu→t-Bu异构化。
• [EN] METHOD OF DETECTION<br/>[FR] PROCÉDÉ DE DÉTECTION
  申请人：UNIV QUEENSLAND

  公开号：WO2021189112A1

  公开（公告）日：2021-09-30

  A method for detection of a nerve agent in a sample, which method comprises (a) irradiating an optical sensing element, the optical sensing element comprising a fluorescent sensing compound provided on a substrate, and measuring the luminescence of the optical sensing element; wherein the fluorescent sensing compound comprises a combination of at least one electron acceptor moiety and, optionally, one or more electron donor moieties such that the electronic properties of the sensing compound are sufficient to enable a change in the luminescence of the sensing element in the presence of the nerve agent, and a moiety that influences solubility of the sensing compound in a solvent; (b) contacting the sample with the optical sensing element; (c) measuring the luminescence of the optical sensing element; and (d) determining whether the nerve agent is present in the sample based on the measurements obtained in steps (a) and (c).

  一种检测样品中神经毒剂的方法，该方法包括：（a）照射光学传感元件，光学传感元件包括提供在基底上的荧光感应化合物，并测量光学传感元件的发光度；其中，荧光感应化合物包括至少一个电子受体基团的组合，以及可选地一个或多个电子给体基团，使得感应化合物的电子性质足以在神经毒剂存在时改变感应元件的发光度，并且影响感应化合物在溶剂中的溶解度的基团；（b）将样品与光学传感元件接触；（c）测量光学传感元件的发光度；以及（d）根据步骤（a）和（c）得到的测量结果确定样品中是否存在神经毒剂。
• IMIDIC ACID COMPOUND HAVING DIVALENT ANION AND PROCESS FOR PRODUCING THE SAME
  申请人：Central Glass Co., Ltd.

  公开号：EP3222624A1

  公开（公告）日：2017-09-27

  Provided is a novel imidic acid compound having a divalent anion useful as a pharmaceutical intermediate, an agrochemical intermediate, an acid catalyst, a battery electrolyte or an antistatic agent. The imidic acid compound is a divalent imidic acid compound represented by the following general formula (1) or (2). [In formulae (1) and (2), R1 to R3 represent a fluorine atom or an organic groups selected from a linear or branched C1-10 alkoxy group, a C2-10 alkenyloxy group, a C2-10 alkynyloxy group, a C3-10 cycloalkoxy group, a C3-10 cycloalkenyloxy group and a C6-10 aryloxy group, and wherein a fluorine atom, an oxygen atom or an unsaturated bond may also be present in the organic group. M1 and M2 represent protons, metal cations or onium cations.]

  本文提供了一种具有二价阴离子的新型亚胺酸化合物，可用作医药中间体、农用化学品中间体、酸催化剂、电池电解液或抗静电剂。该亚胺酸化合物是由以下通式（1）或（2）表示的二价亚胺酸化合物。 [在式(1)和(2)中，R1 至 R3 代表一个氟原子或一个有机基团，该有机基团选自直链或支链 C1-10 烷氧基、C2-10 烯氧基、C2-10 烷炔氧基、C3-10 环烷氧基、C3-10 环烯氧基和 C6-10 芳氧基，其中有机基团中还可能存在一个氟原子、一个氧原子或一个不饱和键。M1和M2代表质子、金属阳离子或鎓阳离子]。
• Imidic acid compound having divalent anion and process for producing the same
  申请人：CENTRAL GLASS CO., LTD.

  公开号：US10287165B2

  公开（公告）日：2019-05-14

  Provided is a novel imidic acid compound having a divalent anion useful as a pharmaceutical intermediate, an agrochemical intermediate, an acid catalyst, a battery electrolyte or an antistatic agent. The imidic acid compound is a divalent imidic acid compound represented by the following general formula (1) or (2). [In formulae (1) and (2), R1 to R3 represent a fluorine atom or an organic groups selected from a linear or branched C1-10 alkoxy group, a C2-10 alkenyloxy group, a C2-10 alkynyloxy group, a C3-10 cycloalkoxy group, a C3-10 cycloalkenyloxy group and a C6-10 aryloxy group, and wherein a fluorine atom, an oxygen atom or an unsaturated bond may also be present in the organic group. M1 and M2 represent protons, metal cations or onium cations.]

  本文提供了一种具有二价阴离子的新型亚胺酸化合物，可用作医药中间体、农用化学品中间体、酸催化剂、电池电解液或抗静电剂。该亚胺酸化合物是由以下通式（1）或（2）表示的二价亚胺酸化合物。 [在式 (1) 和 (2) 中，R1 至 R3 代表氟原子或有机基团，这些有机基团选自直链或支链 C1-10 烷氧基、C2-10 烯氧基、C2-10 烷炔氧基、C3-10 环烷氧基、C3-10 环烯氧基和 C6-10 芳氧基，其中有机基团中还可能存在氟原子、氧原子或不饱和键。M1和M2代表质子、金属阳离子或鎓阳离子]。
• Voigt,D. et al., Bulletin de la Societe Chimique de France, 1969, p. 3383 - 3386
  作者：Voigt,D. et al.

  DOI：——

  日期：——