The infrared spectra of the moOCl, moO2Cl2, WOCl, WO2Cl2, MoO2, MoO3 and Mo3O9 gaseous molecules
作者:D.L. Neikirk、J.C. Fagerli、M.L. Smith、D. Mosman、T.C. Devore
DOI:10.1016/0022-2860(91)80154-v
日期:1991.4
Abstract The IR spectra of several gaseous molybdenum and tungsten oxides and oxychlorides which are thought to be transporting agents for these metals in halogen lamps have been obtained. MoO 2 Cl 2 and WO 2 Cl 2 were observed in absorption and emission by heating the solid compound; Mo 3 O 9 was observed in absorption by heating the solid and by observing the products of the reaction between Mo and
摘要 已经获得了几种气态钼和钨的氧化物和氯氧化物的红外光谱,它们被认为是卤素灯中这些金属的传输剂。通过加热固体化合物,观察到MoO 2 Cl 2 和WO 2 Cl 2 的吸收和发射;通过加热固体和观察Mo与N 2 O反应的产物,观察到Mo 3 O 9 的吸收;MoO 2 和MoO 3 作为Mo和N 2 O反应的产物被观察到;金属与POCl 3 反应生成MoOCl和WOCl。所有光谱均以0.5 cm -1 的分辨率获得,这允许分辨谱带形状并进行明确的光谱分配。