tris(4-iodophenyl) phosphate

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: tris(4-iodophenyl) phosphate
• 化学式: C₁₈H₁₂I₃O₄P
• 分子量: 703.978
• InChiKey: VVMFIUJVORFNIH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  26
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  tris(4-iodophenyl) phosphite 在 bis(2,4,6-triisopropylphenyl) telluride 、 氧气 、 rose bengal 作用下， 以 乙腈 为溶剂， 生成 tris(4-iodophenyl) phosphate
  参考文献：
  名称：

  Aerobic Photooxidation of Phosphite Esters Using Diorganotelluride Catalysts

  摘要：

  Diorganotellurides containing bulky aromatic substituents are found to catalyze the photooxidation of phosphite esters using aerobic oxygen as a terminal oxidant. A Hammett plot with substituted triaryl phosphites yielding rho = 2.88 agrees with a nucleophilic oxygen transfer from telluroxide to phosphite.

  DOI：

  10.1021/ol900240s

文献信息

• Chemiluminescent method and compositions
  申请人：LUMIGEN, INC.

  公开号：EP0516948A1

  公开（公告）日：1992-12-09

  A chemiluminescent method using a protected enhancer compound which is triggered by a hydrolytic enzyme and then enhances a chemiluminescent reaction is described. The reaction involves an amino substituted acylhydrazide which is activated to produce light by a peroxide compound and a peroxidase in the presence of the activated enhancer compound. The result is enhanced generation of light from the reaction. The hydrolytic enzyme is present alone or as a label in an immunoassay, DNA probe assay or other assay wherein the hydrolytic enzyme is bound to a reporter molecule.

  描述了一种使用受保护的增强剂化合物的化学发光方法，该增强剂化合物由水解酶引发，然后增强化学发光反应。该反应涉及一种氨基取代的酰肼，在活化的增强剂化合物存在下，酰肼被过氧化物化合物和过氧化物酶活化产生光。反应的结果是增强了光的产生。水解酶可单独存在，也可作为免疫测定、DNA 探针检测或其他检测中的标记，其中水解酶与报告分子结合。
• Metal-free direct arylation of dialkyl phosphonates for the synthesis of mixed alkyl aryl phosphonates
  申请人：The Board of Regents of the Nevada System of Higher Education on Behalf of the University of Nevada, Las Vegas

  公开号：US10927135B2

  公开（公告）日：2021-02-23

  Provided herein are phosphates, thiophosphates, phosphonates, and phosphinates, methods of making same, and methods of using these compounds and methods for the generation of pharmaceutically relevant phosphate, phosphonate, and phosphinate analogs. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.

  本发明提供了磷酸盐、硫代磷酸盐、膦酸盐和膦酸盐、其制造方法、使用这些化合物的方法以及生成药用磷酸盐、膦酸盐和膦酸盐类似物的方法。本摘要旨在作为在特定技术领域进行搜索的扫描工具，并非对本发明的限制。
• EP1385997A2
  申请人：——

  公开号：EP1385997A2

  公开（公告）日：2004-02-04
• ACTIVATED ENZYME-LINKED DETECTION SYSTEMS FOR DETECTING AND QUANTIFYING NUCLEID ACIDS, ANTIGENS, ANTIBODIES AND OTHER ANALYTES
  申请人：FRAUNHOFER-GESELLSCHAFT ZUR FÖRDERUNG DERANGEWANDTEN FORSCHUNG E.V.

  公开号：EP1448991A2

  公开（公告）日：2004-08-25
• METAL-FREE DIRECT ARYLATION OF DIALKYL PHOSPHONATES FOR THE SYNTHESIS OF MIXED ALKYL ARYL PHOSPHONATES
  申请人：The Board of Regents of the Nevada System of Higher Education on Behalf of the University of Nevada,

  公开号：US20200255461A1

  公开（公告）日：2020-08-13

  Provided herein are phosphates, thiophosphates, phosphonates, and phosphinates, methods of making same, and methods of using these compounds and methods for the generation of pharmaceutically relevant phosphate, phosphonate, and phosphinate analogs. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.