Hexaallylphosphorsaeuretriamid | 23029-47-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: Hexaallylphosphorsaeuretriamid
• 英文别名: Hexallylphosphoramide；N-bis[bis(prop-2-enyl)amino]phosphoryl-N-prop-2-enylprop-2-en-1-amine
• CAS: 23029-47-2
• 化学式: C₁₈H₃₀N₃OP
• 分子量: 335.429
• InChiKey: QUPFZBHBJFUGBC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  23
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  26.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  三(二烯丙基氨基)膦 在 双氧水 作用下， 以 丙酮 为溶剂， 生成 Hexaallylphosphorsaeuretriamid
  参考文献：
  名称：

  Sosnovsky; Lukszo, European Journal of Medicinal Chemistry, 1984, vol. 19, # 4, p. 331 - 340

  摘要：

  DOI：

文献信息

• Peroxide-curable bromin-containing fluoroelastomers containing a sulfone
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0155639A2

  公开（公告）日：1985-09-25

  @ A peroxide-curable fluoroelastomer composition comprising an elastomeric copolymer containing units derived from vinylidene fluoride, units derived from at least one other fluorine-containing monomer copolymerizable with vinylidene fluoride, said monomer being a compound which contains 2-7 carbon atoms, contains no bromine atom and contains at least as many fluorine atoms as carbon atoms, up to 3 mole percent, based on the total moles of copolymer, of a bromine-containing olefin with the proviso that enough of such olefin is present to provide at least about 0.05 weight percent bromine in the copolymer and about 0.5-5 parts per hundred parts elastomeric copolymer of tetramethylene sulfone.

  一种过氧化物固化型氟橡胶组合物，它包含一种弹性共聚物，该共聚物含有从偏氟乙烯衍生的单元、从至少一种可与偏氟乙烯共聚的其他含氟单体衍生的单元，所述单体是一种含有 2-7 个碳原子的化合物、不含溴原子，且氟原子的数目至少与碳原子的数目相同； 含溴烯烃，以共聚物的总摩尔数为基准，其含量不超过 3 摩尔%，但这种烯烃的含量必须足以在共聚物中提供至少约 0.05 重量百分比的溴。05 重量百分数的溴，以及每百份弹性共聚物中约 0.5-5 份的四亚甲基砜。
• Curable compositions of fluoroelastomers containing bromine
  申请人：AUSIMONT S.p.A.

  公开号：EP0761735A1

  公开（公告）日：1997-03-12

  Peroxide-curable fluoroelastomeric compositions, consisting of a fluoroelastomer containing bromine, an organic peroxide and a metal-organic hydride having the formula: wherein M is selected from Sn, Si, Ge, Pb; x is an integer from 1 to 3; y, z are zero or integers from 1 to 3, with the proviso y + z = 4 - x; w is an integer from 1 to 3; the R groups, equal to or different from each other, are selected from: alkyls C1-C4, aryls C6-C12, arylalkyls and alkylaryls C7-C14, optionally containing nitrile and/or hydroxyl groups. The hydride addition allows to increase the curing rate, obtaining at the same time a high crosslinking degree.

  过氧化物固化型氟橡胶组合物，由含溴的氟橡胶、有机过氧化物和金属有机氢化物组成，其化学式为 其中，M 选自 Sn、Si、Ge、Pb；x 为 1 至 3 的整数；y、z 为零或 1 至 3 的整数，但 y + z = 4 - x；w 为 1 至 3 的整数；R 基团彼此相同或不同，选自：C1-C4 烷基、C6-C12 芳基、C7-C14 芳烷基和 C7-C14 芳烷基，可选择含有腈基和/或羟基。添加氢化物可以提高固化速度，同时获得较高的交联度。
• METHOD FOR PRODUCING VULCANIZABLE FLUORINE-CONTAINING ELASTOMER
  申请人：DAIKIN INDUSTRIES, LTD.

  公开号：EP1589047A1

  公开（公告）日：2005-10-26

  The present invention provides a process for preparing a fluorine-containing elastomer in a high productivity comparable to that of non-iodine transfer polymerization process by carrying out an iodine transfer polymerization at high pressure. The present invention also provides a fluorine-containing elastomer prepared by this process, and fluorine-containing molded articles. The process is a batch copolymerization process conducted under conditions that the reduced temperature of the critical constant is at least 0.95 and the reduced pressure of the critical constant is at least 0.80 wherein the reduced temperature and the reduced pressure are calculated using the Peng-Robinson formula from the critical temperature, the critical pressure and the composition ratio of each of the monomers in the gaseous phase in a reaction vessel, in which ethylenically unsaturated compounds containing at least one fluoroolefine are copolymerized in the presence of a compound having the formula: Rf1·Ix wherein Rf1 is a saturated or unsaturated fluorohydrocarbon or chlorofluorohydrocarbon group having 1 to 16 carbon atoms, and x is the number of bonds of Rf1 and an integer of 1 to 4.

  本发明提供了一种通过在高压下进行碘转移聚合制备含氟弹性体的工艺，其生产率与非碘转移聚合工艺相当。本发明还提供了一种通过该工艺制备的含氟弹性体和含氟模塑制品。该工艺是在临界常数的降低温度至少为 0.95 和临界常数的降低压力至少为 0.80 的条件下进行的批量共聚工艺，其中降低温度和降低压力是根据临界温度、临界压力和反应容器中气相中每种单体的组成比例，用彭-罗宾逊公式计算得出的、 其中，含有至少一种氟烯烃的乙烯基不饱和化合物在具有以下式子的化合物存在下共聚：Rf1-Ix 其中 Rf1 是具有 1 至 16 个碳原子的饱和或不饱和氟烃或氯氟烃基团，x 是 Rf1 的键数和 1 至 4 的整数。
• FLUORINE-CONTAINING GRAFT OR BLOCK POLYMER
  申请人：DAIKIN INDUSTRIES, LTD.

  公开号：EP1632518A1

  公开（公告）日：2006-03-08

  The present invention provides a graft or a block polymer in which a fluorine rubber and a silicone rubber are chemically bonded. The present invention is a graft or a block polymer comprising at least one kind of a silicone rubber segment and at least one kind of a fluorine elastomer segment. Furthermore, it is preferable that a fluoirne containing elastomer segment is an elastomer segment comprising vinylidene fluoride or an elastomer segment comprising tetrafluoroethylene and that a silicone rubber segment has a unit of dimethylsiloxane and /or methyl-3,3,3-trifluoropropylsiloxane.

  本发明提供了一种接枝或嵌段聚合物，其中氟橡胶和硅橡胶通过化学键合。本发明是一种接枝聚合物或嵌段聚合物，包括至少一种硅橡胶段和至少一种含氟弹性体段。此外，含氟弹性体段最好是由偏氟乙烯组成的弹性体段或由四氟乙烯组成的弹性体段，硅橡胶段的单元最好是二甲基硅氧烷和/或甲基-3,3,3-三氟丙基硅氧烷。
• PERFLUOROELASTOMER SEALING MATERIAL
  申请人：DAIKIN INDUSTRIES, LTD.

  公开号：EP1666524A1

  公开（公告）日：2006-06-07

  The present invention provides a perfluoroelastomer seal material in which adhesive strength, contamination, corrosion and color change of a contacted surface with a seal material are improved, and an amount of an uncrosslinked polymer component is at most 1 % by weight, measured under specific conditions, and a process for preparing the same. The present invention relates to a perfluoroelastomer seal material, wherein a rate of weight decrease is at most 1 % by weight when the seal material is immersed into perfluoro(tri-n-butyl) amine at 60°C for 70 hours and is dried at 90°C for 5 hours, 125°C for 5 hours and 200°C for 10 hours after taken out of the emersion. And, the present invention also relates to a process for preparing a perfluoroelastomer seal material comprising a step of treating with a solvent having at least 50 % of a swelling rate based on said molded article, when said molded article is immersed at 60°C for 70 hours.

  本发明提供了一种全氟弹性体密封材料，在该密封材料中，与密封材料接触面的粘合强度、污染、腐蚀和颜色变化都得到了改善，而且在特定条件下测得的未交联聚合物成分的量最多为 1%（按重量计），本发明还提供了制备该密封材料的工艺。本发明涉及一种全氟弹性体密封材料，当密封材料在 60°C 的温度下浸入全氟（三正丁基）胺中 70 小时，取出后在 90°C 下干燥 5 小时、125°C 下干燥 5 小时和 200°C 下干燥 10 小时时，重量减少率最多为 1%（按重量计）。此外，本发明还涉及一种制备全氟弹性体密封材料的工艺，该工艺包括以下步骤：当所述模制件在 60°C 下浸泡 70 小时时，用溶胀率至少为所述模制件的 50%的溶剂进行处理。